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Method for preparing honeycomb ceramic heat accumulator by using andalusite tailings

A technology of honeycomb ceramics and andalusite, which is applied in the field of environmental protection, energy saving and new materials, can solve the problems of high production costs, achieve the effects of reduced production costs, reduced production energy consumption, and reduced production costs

Inactive Publication Date: 2013-03-20
WUHAN UNIV OF TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For example, Zhu Peizhi's Chinese invention patent "mullite honeycomb ceramic carrier" (CN1111093C) first calcines bauxite, then uses bauxite clinker and kaolin as the main raw materials, and burns mullite honeycomb ceramics at 1200 ℃ ~ 1450 ℃; Kevin R.Brundage's US patent "Production of Porous Mullite Bodies" (US 6,254,822B1) uses synthetic mullite as the main raw material, and burns porous ceramics at 1400°C to 1550°C; in order to reduce the amount of synthetic materials and improve honeycomb ceramics Performance, Liu Guangwen's Chinese invention patent "andalusite honeycomb heat storage body and preparation method" (CN101857447A) directly uses andalusite concentrate as the main raw material, and burns the honeycomb ceramic heat storage body at 1350 ℃ ~ 1700 ℃; Jean-Andre Alar The US patent "Ceramic Honeycomb Structures" (US2010 / 0300053A1) also uses andalusite concentrate as the main raw material, and the honeycomb ceramics are made by firing in the temperature range of 1450 ° C to 1500 ° C. However, the production cost of using andalusite concentrate is also high. higher

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] A method for preparing a honeycomb ceramic regenerator by utilizing andalusite tailings, comprising the steps of:

[0021] 1) Raw material processing: ball mill the andalusite tailings, shale and high-temperature flux with a ball mill for 16 hours respectively, and pass through a 200-mesh sieve to obtain andalusite tailings powder, shale powder and high-temperature flux powder for subsequent use; the high-temperature flux is stone;

[0022] 2) Ingredients: according to the mass percentage of each raw material: 60wt% of andalusite tailings powder, 20wt% of shale powder, and 20wt% of high-temperature flux powder. Mix andalusite tailings powder, shale powder and high-temperature flux powder to obtain Mixed material; add plasticizer to the mixed material, and mix in a kneader for 10 minutes to obtain plastic clay;

[0023] Described plasticizer is made up of binder, lubricant and water, and the add-on of binder is 3wt% of the mixture quality, and the add-on of lubricant is...

Embodiment 2

[0032] A method for preparing a honeycomb ceramic regenerator by utilizing andalusite tailings, comprising the steps of:

[0033] 1) Raw material processing: ball mill the andalusite tailings, shale and high-temperature flux with a ball mill for 20 hours respectively, and pass through a 250-mesh sieve to obtain andalusite tailings powder, shale powder and high-temperature flux powder for subsequent use; stone;

[0034] 2) Ingredients: according to the mass percentage of each raw material: andalusite tailings powder 80wt%, shale powder 10wt%, high-temperature flux powder 10wt%, select andalusite tailings powder, shale powder and high-temperature flux powder and mix to obtain Mixed material; add plasticizer to the mixed material, and mix in a kneader for 20 minutes to obtain plastic clay;

[0035] Described plasticizer is made up of binder, lubricant and water, and the add-on of binder is 5wt% of the mixture quality, and the add-on of lubricant is the 5wt% of mixture quality, a...

Embodiment 3

[0043] A method for preparing a honeycomb ceramic regenerator by utilizing andalusite tailings, comprising the steps of:

[0044]1) Raw material treatment: mill the andalusite tailings, shale and high-temperature flux with a ball mill for 24 hours respectively, and pass through a 320-mesh sieve to obtain andalusite tailings powder, shale powder and high-temperature flux powder for subsequent use; the high-temperature flux is lithium porcelain stone;

[0045] 2) Ingredients: according to the mass percentage of each raw material: andalusite tailings powder 70wt%, shale powder 15wt%, high-temperature flux powder 15wt%, select andalusite tailings powder, shale powder and high-temperature flux powder and mix to obtain Mixed material; add plasticizer to the mixed material, and mix in a kneader for 15 minutes to obtain plastic clay;

[0046] Described plasticizer is made up of binder, lubricant and water, and the add-on of binder is 4wt% of the mixture quality, and the add-on of lub...

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Abstract

The invention relates to a method for preparing honeycomb ceramic by using andalusite tailings as a main raw material. The honeycomb ceramic is mainly applied in devices such as a regenerative thermal oxidizer (RTO) and the like. A method for preparing a honeycomb ceramic heat accumulator by using andalusite tailings is characterized by comprising the following steps of 1) raw material treatment:performing ball milling on the andalusite tailings, shale and high-temperature flux for 16 to 24 hours by using a ball mill respectively, and sieving the powder with a sieve of 200 to 320 meshes; 2) proportioning: mixing 60 to 80 weight percent of andalusite tailing powder, 10 to 20 weight percent of shale powder and 10 to 20 weight percent of high-temperature flux powder to obtain a mixture, adding a plasticizing agent into the mixture, and mixing for 10 to 20 minutes in a kneading machine to obtain plastic pug; 3) pug milling and ageing; 4) honeycomb blank preparation; 5) shaping and drying; and 6) sintering to obtain the honeycomb ceramic heat accumulator. The method has the characteristics of low cost and environment friendliness.

Description

technical field [0001] The invention relates to a method for preparing honeycomb ceramics with andalusite tailings as the main raw material, which is mainly used as a heat storage body in RTO regenerative incinerators and other devices, and belongs to the field of environmental protection, energy saving and new materials. Background technique [0002] Andalusite tailings are the product of andalusite concentrate separation operations. For every ton of andalusite concentrate selected, 9 to 12 tons of andalusite tailings will be produced. In the andalusite mining areas in Xinjiang, Henan and other places, a large number of andalusite tailings have been piled up, occupying valuable land resources, and producing a large amount of dust at the same time, polluting the environment. People try to effectively utilize andalusite tailings, such as the invention patent: "Method for preparing sintered bricks with andalusite, sillimanite, and feldspar ore waste as raw materials" (patent ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B38/00C04B35/66B09B3/00
CPCY02W30/82
Inventor 徐晓虹冷光辉马小虎吴建锋郑胜利方斌正
Owner WUHAN UNIV OF TECH