Dication quaternary ammonium complex iodine disinfectant, preparation method thereof and application thereof

A dual-cation, quaternary ammonium salt technology, applied in the directions of disinfectants, botanical equipment and methods, applications, etc., can solve the problems of unsatisfactory killing effect of bacterial spores and non-membrane viruses, short duration of drugs, and large doses. , to achieve the effect of overcoming poor disinfection effect, strong resistance to organic interference, and long effective time

Inactive Publication Date: 2012-01-04
BEIJING FANBO CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although they have played a good role in the disinfection process, their shortcomings are increasingly prominent, mainly reflected in the unsatisfactory killing effect on bacterial spores and non-membrane viruses, the duration of the agent is short, and bacteria are prone to develop resistance to it. , the dosage is large, the cost is high, and there is a lot of foam when used, it is not easy to remove, etc.

Method used

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  • Dication quaternary ammonium complex iodine disinfectant, preparation method thereof and application thereof
  • Dication quaternary ammonium complex iodine disinfectant, preparation method thereof and application thereof
  • Dication quaternary ammonium complex iodine disinfectant, preparation method thereof and application thereof

Examples

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Effect test

Embodiment 1

[0019] The preparation of dicationic quaternary ammonium salt complexed iodine disinfectant comprises steps:

[0020] (1) Put 50 parts of deionized water in an enamel reaction kettle with a reflux condenser, stir, and control the temperature at about 30-40°C, then add 30 parts of trimethylamine hydrochloride, 60 parts of epichlorohydrin, 10 parts of dodecyl dimethyl amine oxide were put into the reaction kettle, and the reaction was refluxed until the reaction liquid was transparent. Add 50 parts of dodecyl / tetradecyl dimethyl tertiary amine, raise the temperature to 55-65°C, react for 1-2 hours, then raise the temperature to 75-85°C, react for 2-3 hours until the reaction liquid is transparent.

[0021] (2) Cool down to 50-68°C, mix 20 parts of ethylene glycol and 30 parts of refined iodine into the reaction kettle, and react until the reaction liquid is transparent. Cool down to 40-45°C, add 2 parts of 2 g / L sodium dihydrogen phosphate and disodium hydrogen phosphate 1:1 (w...

Embodiment 2

[0023] The preparation of dicationic quaternary ammonium salt complexed iodine disinfectant comprises steps:

[0024] (1) Put 100 parts of deionized water in a reactor with a reflux condenser, stir, and control the temperature at about 30-40°C, then add 40 parts of trimethylamine hydrochloride, 80 parts of epichlorohydrin, and 20 parts of dialkyl dimethyl amine oxide were put into the reactor, and the reaction was refluxed until the reaction liquid was in a transparent state. Add 80 parts of dodecyl / tetradecyl dimethyl tertiary amine, raise the temperature to 55-65°C, react for 1-2 hours, then raise the temperature to 75-85°C, and react for 2-3 hours until the reaction liquid is transparent.

[0025] (2) Cool down to 50-68°C, mix 30 parts of 1.2-propanediol and 40 parts of refined iodine into the reactor, and react until the reaction liquid is transparent. Cool down to 40-45°C, add 3 parts of 2 g / L sodium dihydrogen phosphate and disodium hydrogen phosphate 1:1 (weight ratio)...

Embodiment 3

[0027] The preparation of dicationic quaternary ammonium salt complexed iodine disinfectant comprises steps:

[0028] (1) Put 150 parts of deionized water in a reactor with a reflux condenser, stir, and control the temperature at about 30-40°C, then add 50 parts of trimethylamine hydrochloride, 100 parts of epichlorohydrin, coconut 20 parts of oleamidopropyl amine oxide were put into the reactor, and refluxed until the reaction solution was transparent. Add 100 parts of dodecyl / tetradecyl dimethyl tertiary amine, raise the temperature to 55-65°C, react for 1-2 hours, then raise the temperature to 75-85°C, and react for 2-3 hours until the reaction liquid is transparent.

[0029] (2) Cool down to 50-68°C, mix 30 parts of 1.2-propanediol and 30 parts of refined iodine into the reactor, and react until the reaction liquid is transparent. Cool down to 40-45°C, add 2 parts of 2 g / L sodium dihydrogen phosphate and disodium hydrogen phosphate 1:1 (weight ratio) aqueous solution mixt...

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Abstract

The invention provides a dication quaternary ammonium complex iodine disinfectant. The dication quaternary ammonium complex iodine disinfectant comprises the following ingredients in parts by weight: 10-200 parts of organic amine, 5-100 parts of trimethylamine hydrochloride, 5-150 parts of epoxy chloropropane, 1-50 parts of catalyst, 1-10 parts of buffering agent, 10-100 parts of leveling agent, 10-100 parts of iodine and 10-200 parts of de-ionized water. The preparation process of the disinfectant provided by the invention is simple and convenient; and the prepared disinfectant has the advantages of high efficiency, low toxicity, broad spectrum and less residue. The disinfectant provided by the invention can be widely applied to water disinfection of aquaculture and disease prevention of aquatic animals.

Description

technical field [0001] The invention relates to a novel dication quaternary ammonium salt complexed iodine disinfectant, its preparation method and application. Background technique [0002] Since Domagk discovered the bactericidal effect of cationic surfactants in 1935, the research work on quaternary ammonium salt disinfectants has made significant progress, and has been increasingly widely used in fields such as medical and health care, oil field exploitation, civil and aquaculture disinfection. So far, four generations of quaternary ammonium salt disinfectants have been developed internationally. The first-generation product is alkyl dimethyl benzyl ammonium chloride, in which the product with an alkyl chain length of 12 to 16 carbons has the best bactericidal effect, and the second-generation disinfectant is a derivative of the first-generation product, which is produced through The third generation product is dialkyl dimethyl ammonium chloride. Compared with the previ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): A01N59/12A01P1/00C02F1/50
Inventor 郑超斌郑红超张小文
Owner BEIJING FANBO CHEM
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