Polyurethane elastomer fibers and processing agent and method therefor
一种聚氨酯类、弹性纤维的技术,应用在聚氨酯类弹性纤维用处理剂、聚氨酯类弹性纤维的处理以及聚氨酯类弹性纤维领域,能够解决得不到稳定操作性、卷装解舒性不好、平滑性或抗静电性不充分等问题
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Embodiment 1
[0102] Example 1 {Preparation of treating agent (T-1) for polyurethane elastic fibers}
[0103] The viscosity at 25°C as the dispersion medium is 20×10 -6 m 2 99 parts of mineral oil (a-1) per s, and 1 part of urethane compound (UT-1) shown in Table 1 as a dispersant, mixed until uniform at a temperature of 20 to 35°C, and used A horizontal bead mill was used for wet pulverization to form a uniform dispersion, and the polyurethane-based elastic fiber treatment agent (T-1) corresponding to Example 1 having an average particle diameter of 5 μm obtained by the above average particle diameter measurement method was prepared.
[0104] ・Examples 2 to 15, 22 to 27 and Comparative Examples 2, 7, 9 to 12 {treatment agents for polyurethane elastic fibers (T-2) to (T-15), (T-22) to (T-27 ) and preparation of treatment agents for polyurethane elastic fibers (t-2), (t-7), (t-9) to (t-12) for comparison}
[0105] In the same manner as the treating agent for polyurethane elastic fibers (T...
Embodiment 16
[0106] Example 16 {Preparation of treating agent (T-16) for polyurethane elastic fibers}
[0107] The viscosity at 25°C as the dispersion medium is 20×10 -6 m 2 The viscosity of 90 parts of mineral oil (a-1) per s and 25°C is 20×10 -6 m 2 / s of 98 parts of a mixture of 10 parts of polydimethylsiloxane (b-1) and 2 parts of urethane compound (UT-6) shown in Table 1 as a dispersoid at 20 to 35°C After mixing at a uniform temperature, use a horizontal bead mill to perform wet pulverization to form a uniform dispersion, and prepare a polyurethane elastic fiber equivalent to Example 16 with an average particle diameter of 10 μm obtained by the above-mentioned method for measuring the average particle diameter. Treatment agent (T-16).
[0108] ・Examples 18, 19, 21, 28, 30 to 35, 43 and Comparative Examples 1, 3, 4 {Treatment agent for polyurethane elastic fibers (T-18), (T-19), (T-21), (T-28), (T-30) to (T-35), (T-43) and the treatment agents for polyurethane elastic fibers (t-1...
Embodiment 17
[0110] Example 17 {Preparation of treating agent (T-17) for polyurethane elastic fibers}
[0111] The viscosity at 25°C as the dispersion medium is 10×10 -6 m 2 The viscosity of 90 parts of mineral oil (a-2) per s at 25°C is 10×10 -6 m 2 / s 98 parts of a mixture of 5 parts of polydimethylsiloxane (b-2) and 5 parts of isotridecyl stearate (c-1), and the amino group shown in Table 1 as a dispersoid After mixing 2 parts of formate compound (UT-7) at a temperature of 20 to 35°C until uniform, wet pulverization was carried out using a horizontal bead mill to form a uniform dispersion, and prepared by the above-mentioned method for measuring the average particle size. The processing agent (T-17) for polyurethane elastic fibers corresponding to Example 17 whose average particle diameter is 10 micrometers.
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