High-precision printing circular screen photographic emulsion and preparation method thereof

A technology for printing rotary screen and photosensitive adhesive, applied in the field of photosensitive adhesive, can solve the problems such as difficulty in improving printing and dyeing enterprises, defects in exposure time and printing durability, poor exposure precision, etc., so as to reduce high-temperature baking time, Good chemical resistance and solvent resistance, less environmental pollution

Active Publication Date: 2012-05-02
山东同大镍网有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] In order to improve production efficiency, the printing and dyeing industry now mostly adopts the rotary screen printing process. The rotary screen photosensitive adhesive is a necessary raw material in the process of making patterns by wax spraying, inkjet and laser exposure. The quality of its quality is the key to the printing quality. However, the rotary screen photosensitive adhesive produced under the current technical conditions generally has the disadvantages of poor exposure fineness, long exposure time and low printing durability, which makes it difficult for printing and dyeing enterprises to print high-definition patterns. Larger improvement, low printing and dyeing grades, and the defects of exposure time and printing durability have caused high printing and dyeing costs and low profits for printing and dyeing companies, and most of the commercially available rotary screen photosensitive adhesives now add organic solvents. The volatilization of organic solvents during the process and the generation of irritating smoke during the baking process not only pollute the environment, but also cause certain harm to the human body.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041]A high-precision printing rotary screen photosensitive adhesive, which is composed of the following components by weight: 100 parts of bisphenol A epoxy resin of type E-35 adhesive, 6 parts of dicyandiamide as a crosslinking agent, and PVA-0588 type of photosensitive agent 30 parts of polyvinyl alcohol, 8 parts of toughening agent hydroxyl-terminated nitrile rubber, 2 parts of catalyst N-phenyl-N,N-dimethylurea, 15 parts of diluent 1,4-butanediol diglycidyl ether, Stabilizer sodium hydroxymethylcellulose 1 part, sensitizer glycerol and trimethylolethane 1 part each, emulsifier 1 part sorbitan oleate, sorbitan monooleate polyoxyethylene 1 part of ether, 0.5 part of ethanol as defoaming agent, 0.5 part of flame retardant tris(1-chloro-2propyl) phosphate, buffer substance is a mixture of 4.5 parts of anhydrous acetic acid and 1 part of sodium acetate, 200 parts of diluting solvent water , The photosensitizer is a mixture of 3 parts of ammonium dichromate and 12 parts of wat...

Embodiment 2

[0044] A high-precision printing rotary screen photosensitive adhesive, consisting of the following components by weight: 100 parts of adhesive E-14 type bisphenol A epoxy resin, 6 parts of crosslinking agent dicyandiamide, photosensitive agent PVA2488 type polyethylene 20 parts of alcohol, 15 parts of toughening agent dimethyl phthalate, 2 parts of catalyst N-(3-chloro-4-methylphenyl)-N,N-dimethylurea, diluent phenyl glycidol 30 parts of ether, 2 parts of stabilizer fumed silica, 3 parts of sensitizer PEG-800 type polyethylene glycol, 2 parts of emulsifier polyoxyethylene sorbitan monolaurate, 1 part of defoamer ethanol, 1 part of flame retardant dimethyl methylphosphonate, the buffer substance is a mixture of 4.5 parts of anhydrous acetic acid and 1 part of formic acid, 300 parts of diluting solvent water, and the photosensitizer is a mixture of 4 parts of ammonium dichromate and 16 parts of water.

[0045] Results: The volume of 500mL photosensitive adhesive for high-defini...

Embodiment 3

[0047] A high-precision printing rotary screen photosensitive adhesive, which is composed of the following components by weight: 100 parts of bisphenol A epoxy resin of type E-20 adhesive, 15 parts of butylated phenolic resin of crosslinking agent, and PVA1788 type of photosensitive agent 25 parts of polyvinyl alcohol, 12 parts of toughening agent dimethyl phthalate, 1 part of catalyst benzyl dimethylamine, 22 parts of diluent neopentyl glycol diglycidyl ether, stabilizer sodium hydroxymethyl cellulose 1.5 parts, 2.5 parts of sensitizer trimethylolethane, 1 part of emulsifier sorbitan monolaurate, 0.7 part of defoaming agent ethanol, 0.7 part of flame retardant dimethyl methylphosphonate, buffer substance is The mixture of 1 part of formic acid and 1 part of sodium hydroxide, 250 parts of diluting solvent water, and the photosensitizer is a mixture of 3.5 parts of ammonium dichromate and 14 parts of water.

[0048] Results: The obtained photosensitive adhesive for high-definit...

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Abstract

The invention discloses a high-precision printing circular screen photographic emulsion and a preparation method thereof; the photographic emulsion comprises binder, cross-linking agent, photosensitizer, flexibilizer, catalyst, diluent, stabilizing agent, sensitizer, emulsifying agent, antifoaming agent, fire retardant, buffering material, diluent solution and light sensitive agent; the photographic emulsion is prepared by steps of diluting, stirring, uniformly mixing and standing; the high-precision printing circular screen photographic emulsion has the following advantages that: the granulegrain diameter of the high-precision printing circular screen photographic emulsion is less than 2 microns and the granule has strong bonding force with the printing circular screen, strong chemical corrosion resistance and friction resistance and high printing resistance; the circular screen platemaking is capable of being developed clearly without blocking the screen holes; therefore, the stretching performance of the printing circular screen in printing process is improved; the service life of the printing circular screen is prolonged, the exposing time of the circular screen is shortened and bonding firmness of the emulsion layer and the printing circular screen is improved; in addition, the washing resistance firmness and resolution of the emulsion layer are high; volatilize organic compound is not produced in the preparation process, so the emulsion and the preparation method have less pollution on the environment and low harm on human body.

Description

technical field [0001] The invention relates to a photosensitive glue, in particular to a high-precision printing cylinder photosensitive glue and a preparation method thereof, belonging to the field of photosensitive glue. Background technique [0002] In order to improve production efficiency, the printing and dyeing industry now mostly adopts the rotary screen printing process. The rotary screen photosensitive adhesive is a necessary raw material in the process of making patterns by wax spraying, inkjet and laser exposure. The quality of its quality is the key to the printing quality. However, the rotary screen photosensitive adhesive produced under the current technical conditions generally has the disadvantages of poor exposure fineness, long exposure time and low printing durability, which makes it difficult for printing and dyeing enterprises to print high-definition patterns. Larger improvement, low printing and dyeing grades, and the defects of exposure time and pri...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G03F7/004G03F7/04
Inventor 孙俊成魏福彬苏窈徐莉
Owner 山东同大镍网有限公司
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