Coal-fired flue gas desulphurization denitration process and desulphurization denitration device thereof

A technology for desulfurization and denitrification and coal-fired flue gas is applied in the field of desulfurization and denitrification, which can solve the problems of slow progress of ammonia wet denitrification, low removal rate of ammonia wet denitrification, and low solubility of reaction activity, achieving high absorption rate and easy management. , the effect of convenient operation

Inactive Publication Date: 2012-06-20
SOUTHEAST UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At the same time, the ammonia-based wet denitrification has progressed slowly and has few industrial applications. The reason is that 90% to 95% of NO in coal-fired flue gas x However, the reactivity of NO and the solubility in water are low, which makes the removal rate of ammonia wet denitrification low and consumes a lot of energy. It is difficult to realize the promotion and application of this technology.

Method used

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  • Coal-fired flue gas desulphurization denitration process and desulphurization denitration device thereof
  • Coal-fired flue gas desulphurization denitration process and desulphurization denitration device thereof
  • Coal-fired flue gas desulphurization denitration process and desulphurization denitration device thereof

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Embodiment 1

[0027] This embodiment provides a coal-fired flue gas desulfurization and denitrification process and its desulfurization and denitrification device, and its device structure is as follows figure 1 As shown, it mainly includes low-temperature plasma reactor 1, simultaneous desulfurization and denitration spray tower 2, process water tank 3, ammonia tank 4, pulse power supply 5, absorption liquid circulation pump 6, mother liquor transfer pump 7, ammonia water pump 8 and process water pump 9 , The outlet of the low-temperature plasma reactor 1 is connected with the inlet of the simultaneous desulfurization and denitration spray tower 2, and the absorption liquid at the bottom of the desulfurization and denitration spray tower 2 is re-sent into the spray device through the absorption liquid circulation pump 6. Part of it is discharged through the mother liquor transfer pump 7 installed at the bottom of the simultaneous desulfurization and denitration spray tower. The process water ...

Embodiment 2

[0031] The device structure of this embodiment is the same as that of embodiment 1, the difference is that the process flow of this embodiment is: the coal-fired flue gas at 180°C from the dust collector enters the low-temperature plasma reactor 1 through the flue, and SO in the coal-fired flue gas 2 The concentration is 2000mg / Nm 3 , NO x The concentration is 800mg / N m 3 , The discharge processing power in the low-temperature plasma reactor is 4W / m 3 , The residence time of flue gas is 3.5 seconds. In the reactor, 40%-50% of NO in coal-fired flue gas is oxidized to NO 2 , Making NO and NO in the flue gas 2 The number of molecules is close to 1:1. The conditioned flue gas enters the simultaneous desulfurization and denitrification spray tower 2, the empty tower gas velocity of the flue gas is 3.5m / s, the absorption liquid used is ammonia with a concentration of 10%, the liquid-gas ratio is 6L / m3, and the ammonia is sprayed The atomizing nozzle of the shower system sprays out and ...

Embodiment 3

[0033] The device structure of this embodiment is the same as that of embodiment 1, the difference is that the process flow of this embodiment is: the coal-fired flue gas at 200°C from the dust collector enters the low-temperature plasma reactor 1 through the flue, and SO in the coal-fired flue gas 2 The concentration is 2600mg / N m 3 , NO x The concentration is 700mg / N m 3 , The discharge processing power in the low-temperature plasma reactor is 4W / m 3 , The residence time of the flue gas is 4 seconds. In the reactor, 40%-50% of the NO in the coal-fired flue gas is oxidized to NO 2 , Making NO and NO in the flue gas 2 The number of molecules is close to 1:1. The conditioned flue gas enters the simultaneous desulfurization and denitrification spray tower 2, the empty tower gas velocity of the flue gas is 3.5m / s, the absorption liquid used is ammonia with a concentration of 10%, and the liquid-gas ratio is 6.5L / m3. The atomizing nozzle of the spray system sprays out, and it comes i...

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Abstract

The invention discloses a coal-fired flue gas simultaneous desulphurization denitration process by low temperature plasma oxidation combined with ammonia-method wet absorption; the process comprises two processes of low temperature plasma oxidation and ammonia-method wet absorption; coal-fired flue gas to be treated is firstly introduced into a low temperature plasma reactor through a flue, and thus 40%-50% of NO in the flue gas is oxidized into NO2; the conditioned flue gas is introduced into a simultaneous desulphurization denitration spray tower, and fully contacts ammonia water absorption liquid so as to remove SO2 and NOx in the flue gas and discharge the flue gas; the absorption liquid at the bottom of the simultaneous desulphurization denitration spray tower is delivered into a spray layer again for recycle through an absorption liquid circulating pump; ammonia water in an ammonia water groove is supplied continuously to the spray tower through an ammonia water pump; and a part of mother liquor is discharged through a mother liquor transfer pump. The process of the invention is applicable to the simultaneous desulphurization denitration treatment of coal-fired flue gas, and the device of the invention has the advantages of good pollutant removing effect, simple equipment, less land occupation, convenient operation, and convenience for management.

Description

Technical field [0001] The invention relates to a coal-fired flue gas desulfurization and denitrification process and a desulfurization and denitrification device, in particular to a process and a device for simultaneous desulfurization and denitrification of coal-fired flue gas using low-temperature plasma oxidation combined with ammonia wet absorption, belonging to The technical field of comprehensive purification of pollutants in environmental protection. Background technique [0002] As my country's main primary energy, coal accounts for about 64% of primary energy consumption. Power plants, as a large coal-burning company, consume about 47% of my country's coal production. Many pollutants are produced in the process of burning coal, of which sulfur dioxide (SO 2 ) And nitrogen oxides (NO x ). With the rapid economic development, the coal-based energy structure has greatly increased my country’s coal-fired flue gas emissions, and SO 2 And NO x The pollution is getting more a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D53/75B01D53/60C01C1/18C01C1/24C05C1/00C05C3/00
CPCY02A50/20
Inventor 仲兆平张波钟道旭付宗明周莹
Owner SOUTHEAST UNIV
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