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Epoxy resin matrix complex additive and preparation method thereof and modified polypropylene material

A polypropylene material and epoxy resin technology, which is applied in the field of compounding additives and preparation, can solve the problems of sticking equipment, mucus leakage, and sticky mucus, etc., and achieves the effects of high production efficiency, convenient operation and fast precipitation speed.

Inactive Publication Date: 2013-07-03
SHAANXI UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Chinese patent CN 02155007.7 reports that the material prepared by adding epoxy resin to polypropylene has good rigidity and strength, but when adding viscous liquid epoxy resin to the equipment and mixing with polypropylene, the mucus is easy to stick to hands, sticky Inconvenience in operation such as equipment and mucus leakage
So far, it has not been found that epoxy resin is added to nylon 6 by solution method to make powder compound additives and then used to modify polypropylene.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0013] A preparation method of epoxy resin-based composite auxiliary agent, comprising the following steps:

[0014] (1) According to the mass ratio, weigh the raw materials of the following components: nylon 6: epoxy resin: formic acid=1: 3.5-4.5: 3-6; see Table 1 for the specific formula.

[0015] Table 1 The mass ratio of each composition of epoxy resin-based composite additives

[0016] Example code

Nylon 6

epoxy resin

formic acid

A

1

4

4

B

1

3.5

5

C

1

4.5

6

D

1

3

3

Remark

Grade: 1022B

Grade: E-44

industrial grade

[0017] (2) Add nylon 6 to formic acid to dissolve it, add epoxy resin to the formic acid solution in which nylon 6 is dissolved, and stir to obtain a uniform mixing system;

[0018] (3) Add water dropwise to the mixing system under stirring, epoxy resin and nylon 6 are precipitated together to form a white prec...

Embodiment 1

[0021] Mix the white powder of the prepared Example A formula with polypropylene at a ratio of 5% of the mass of the white powder to the polypropylene mass, and then add it to the twin-screw extruder at 210°C-220°C-230°C- Melt blending at an extrusion temperature of 225° C. (from the feed port to the discharge port) to obtain a modified polypropylene material. The modified polypropylene material and the pure polypropylene material were respectively tested according to the ASTM D790 standard for bending properties, ASTM D638 for tensile properties, and ASTM D256 for impact properties. The test results are shown in Table 2.

Embodiment 2

[0023] The white powder of the prepared Example A formula is mixed with polypropylene at a ratio of 10% of the mass of the white powder to the polypropylene mass, and then added to the twin-screw extruder at 210°C-220°C-230°C- Melt blending at an extrusion temperature of 225° C. (from the feed port to the discharge port) to obtain a modified polypropylene material. The modified polypropylene material and the pure polypropylene material were respectively tested according to the ASTM D790 standard for bending properties, ASTM D638 for tensile properties, and ASTM D256 for impact properties. The test results are shown in Table 2.

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PUM

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Abstract

The invention discloses an epoxy resin matrix complex additive and a preparation method of the additive and a modified polypropylene material. The preparaiton method comprises the steps of weighing epoxy resin, nylon 6, methanoic acid according to certain mass percentages, dissolving nylon 6 by adding into methanoic acid, and then adding epoxy resin to mix uniformly, dropwisely adding excess water into the mixture till no more white precipitate is generated, filtering and drying the white precipitate to obtain a white lump, and smashing the lump into white powder. The white powdery epoxy resin-nylon 6 complex additive prepared with the method of the invention has a good reinforcement effect on polypropylene, and the modified polypropylene obtained has good rigidity and strength and can beprocessed into automobile spare parts, electronic and electrical parts and the like. Furthermore, the preparation process of the epoxy resin matrix complex additive and the modified polypropylene material provided in the invention is simple and easy to operate, and is suitable for large-scale industrial production.

Description

technical field [0001] The invention relates to a compounding auxiliary agent and a preparation method, and a modified polypropylene material obtained by using the compounding auxiliary agent. Background technique [0002] Polypropylene is a widely used resin with good mechanical properties, but its rigidity and strength are not high enough to meet the requirements of engineering materials. In order to improve the rigidity and modulus of polypropylene, inorganic fillers and glass fibers are usually added to it. Inorganic fillers and glass fibers are inorganic materials, and they are not easy to combine with organic materials such as polypropylene. Epoxy resin is an organic material and has excellent adhesion, high rigidity and strength. Chinese patent CN 02155007.7 reports that the material prepared by adding epoxy resin to polypropylene has good rigidity and strength, but when adding viscous liquid epoxy resin to the equipment and mixing with polypropylene, the mucus is e...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L63/00C08L77/02C08K5/09C08L23/12B29C47/92B29C48/92
CPCB29C48/40B29C48/92B29C2948/92704B29C2948/92895
Inventor 杨晓明冯小明
Owner SHAANXI UNIV OF TECH
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