Application of fixed Lentinus edodes prosthecae to heavy metal cadmium pollution
A technology of mushroom stem and heavy metal, which is applied in water/sewage treatment, adsorbed water/sewage treatment, water/sludge/sewage treatment, etc. The problem of high cost, to achieve the effect of wide use, avoid secondary pollution, good stability
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Embodiment 1
[0037] Laboratory test:
[0038] Preparation of the biological components of the adsorption material: cut off and wash the non-edible part of the stipe of the mature fruiting body of the mushroom attached to the culture medium, dry it in a constant temperature drying oven at 50±2°C to constant weight, take it out and cool it, and crush it with a pulverizer Finally, as the biological component of the adsorption material, put it into a jar and set aside.
[0039] Cd 2+ Preparation of adsorbent: Use polyvinyl alcohol-sodium alginate (PVA-SA) to fix the stipe of Lentinus edodes as an adsorbent, weigh 5 g PVA and 1 g SA, pour them into a beaker with 100 mL of distilled water, heat and stir to dissolve, Cool to 50°C, add 3 g of shiitake mushroom powder to make the bacterial powder concentration 3% (w / v), mix well to form a mycoalgal alcohol mixture. Use a syringe equipped with a 7-9 gauge needle to squeeze the bacteriophyll mixture into the 2% CaCl 2 Saturated H 3 BO 3 In the...
Embodiment 2
[0070] In sewage containing heavy metal cadmium, the measured Cd of sewage 2+ The concentration was 25 mg / L, and polyvinyl alcohol-sodium alginate (PVA-SA) was used to immobilize the mushroom stipe as the adsorbent 35 g to prepare a fixed-bed reactor. The fixed-bed reactor was a cylinder with a column length of 20 cm. The diameter is 5.1 cm, and the bed height is 80 mm. The fixed bed reactor is used to adsorb the heavy metal cadmium in the sewage. The speed of the sewage passing through the fixed bed reactor is 10 mL / min to remove the heavy metal cadmium in the wastewater. 2+ The adsorption capacity is 1.21 mg / kg, and the Cd in the sewage after adsorption 2+ The concentration reaches the emission standard required by the state.
[0071] Then, 0.01 mol / L HCl is used to analyze the adsorbed heavy metals. After the fixed mushroom stipe is resolved in the treated sewage, the sewage containing heavy metal cadmium can be adsorbed again.
Embodiment 3
[0073] In sewage containing heavy metal cadmium, the measured Cd of sewage 2+ The concentration is 45 mg / L, using polyvinyl alcohol-sodium alginate (PVA-SA) to immobilize the mushroom stipe as the adsorbent 35 g to prepare a fixed-bed reactor, the fixed-bed reactor is a cylinder with a column length of 20 cm, The diameter is 5.1 cm, and the bed height is 80 mm. The fixed bed reactor is used to adsorb the heavy metal cadmium in the sewage. The speed of the sewage passing through the fixed bed reactor is 10 mL / min to remove the heavy metal cadmium in the wastewater. 2+ The adsorption capacity is 1.65 mg / kg, and the Cd in the sewage after adsorption 2+ The concentration reaches the emission standard required by the state.
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