Preparation method of traditional Chinese medicine manyflower tickclove herb extract and application in anti-senile dementia medicaments
A technology of hungry leeches and extracts, which is applied in the field of medicine, can solve the problems of large molecular weight, inability to pass through the blood-brain barrier, and difficulty in large-scale preparation, and achieve the effects of convenient material selection, significant neuromimetic growth factor activity, and wide sources
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Embodiment 1
[0038] Example 1 Preparation of Hungry Leech Extract and its Active Components and Active Compounds
[0039] 1. Crushing and extraction:
[0040] After crushing 1000g of traditional Chinese medicine leeches, extract with 3L of ethanol at room temperature (occasionally shake). After suction filtration, concentration and drying, 50 g of the crude ethanol extract was obtained, which was alternately extracted and separated with water and ethyl acetate several times to obtain 10 g of the active component (A) of the ester layer.
[0041] 2. Separation and purification:
[0042] The active component (A) is first separated by a silica gel open column (200-300 mesh, the following solvent systems are all in volume ratio, and the first separation is chloroform:ethyl acetate=100:0,90:10,80:20 , 70:30, 50:50, 0:10), combined chloroform:ethyl acetate 90:10 to 50:50 eluted fractions to obtain active component (B) 1g; then, the active component was further Separation with ODS open column (...
Embodiment 1
[0044] Qualitative identification of physical and chemical characteristics and chemical structure of the compound obtained in embodiment 1:
[0045] The structures of compounds (1), (2) and (3) were confirmed by MS, 1 H NMR, 13 C NMR test, and confirmed after comparison with literature data.
[0046] Compound 1: white solid; (c1.0,MeOH);C 39 h 56 o 6 (HR ESI-TOF-MS m / z(M+Na) + Calcd.for C 39 h 56 o 6 Na: 643.3969, Found: 643.3981); 1 H NMR (500MHz, CD 3 OD)δ7.51(1H,d,J=15.8Hz),7.03(1H,d,J=2.0Hz),6.94(1H,dd,J=8.2,2.0Hz),6.78(1H,d,J= 8.2Hz),6.23(1H,d,J=15.8Hz),5.20(1H,brt),4.97(1H,dd,J=9.1,7.6Hz),3.52(2H,d,J=10.0Hz),3.35 (d,10Hz,1H),3.16(1H,d,J=12.7Hz),3.11(1H,d,J=11.8Hz),1.23(3H,s),1.07(3H,s),1.02(3H, s), 0.89(6H,s), 0.83(3H,s).
[0047] 13 C NMR (125MHz, CD 3 OD)δ169.2,149.5,146.7,146.6,145.8,127.7,123.4,122.9,116.5,115.6,115.1,75.8,69.8,64.7,49.1,47.9,47.8,43.8,43,43,41,39.2,38.1,37 35.3, 33.7, 33.1, 32.3, 31.8, 26.6, 26.6, 24.6, 24.1, 24, 22.9, 18.8, 17.3, ...
Embodiment 3
[0052] Biological activity of the extract of the traditional Chinese medicine Lelicus chinensis and its active components and active compounds.
[0053] In animal models of neurodegenerative diseases, studies have found that NGF can prevent or reduce the degeneration of neurons, prevent the progression of AD to a certain extent, and have the effects of promoting nerve growth and neuroprotection. Because PC12 cells have the general characteristics of nerve cells, PC12 cells will stop dividing under the action of NGF, grow protrusions, and transform into neuron-like cells. Therefore, using PC 12 cells as an effective activity identification system to screen active active ingredients will become an effective drug for the treatment of senile dementia.
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