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Matt composition for wire cladding and matt shell for wires

A composition and electric wire technology, applied in the field of matte composition, can solve problems such as uneven matting, uneven dispersion of elastomer or copolymer, and reduction of mechanical properties of thermoplastic elastomers

Active Publication Date: 2013-09-11
POLYOL MACROMOLECULE POLYMER FUJIAN
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, since additives are included in the materials for manufacturing wire sheaths (or called "compositions for manufacturing wire sheaths"), when one of the mechanical, physical and chemical properties is adjusted, other properties often change, such as adding When used as a flame retardant, it will reduce the mechanical properties of thermoplastic elastomers, etc.
[0004] Furthermore, methods for general elastomers to become matte elastomers, such as adding fillers to materials, grafting (grafting) rubber-like elastomers in resins, and resins containing cross-linkable ethylene copolymers (reference country The prior art of patent US5,508,347, Japanese Patent Laid-Open No. 59-089346), but the surface of the molded body of these materials has problems such as uneven extinction caused by uneven dispersion of these fillers, elastomers or copolymers

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] Example 1: Preparation of Matte Composition 1 for Wire Coating

[0032] Preparation of TPU: Use MDI, 1,4-butanediol (1,4-BG) and adipic acid polyol polyester (molecular weight is about 2000) to carry out a synthesis reaction to obtain TPU.

[0033] 15 parts by weight of TPEE with a hardness of 38D and 48.4 parts by weight of TPU were blended and kneaded, and then granulated with a single screw to obtain material A. Mix material A with 10 parts by weight of EVA, 1.2 parts by weight of SEBS (styrene-ethylene-butadiene block copolymer), 2.5 parts by weight of black pigment, 1.3 parts by weight of silicone (wearing agent), and 1.6 parts by weight of TPU. After mixing and kneading, the pellets were pumped by a single screw to obtain a matte composition 1 for coating electric wires.

Embodiment 2

[0034] Example 2: Preparation of Matte Composition 2 for Wire Coating

[0035] Preparation of TPU: TPU is prepared in the same way as the preparation of TPU in Example 1 above.

[0036] 13 parts by weight of TPEE with a hardness of 38D and 50.4 parts by weight of TPU were blended and kneaded, and then granulated with a single screw to obtain material A. Blend and knead material A with 10 parts by weight of EVA, 1.2 parts by weight of SBS, 2.5 parts by weight of black pigment, 1.3 parts by weight of silicone (abrasion resistant agent), and 21.6 parts by weight of TPU, and then granulate with a single screw to obtain electric wires Matte composition for coverage2.

Embodiment 3

[0037] Example 3: Preparation of Matte Composition 3 for Wire Coating

[0038] Preparation of TPU: TPU is prepared in the same way as the preparation of TPU in Example 1 above.

[0039] Mix and knead 20 parts by weight of TPEE with a hardness of 38D and 43.4 parts by weight of TPU, and then granulate with a single screw to obtain material A. After mixing and kneading material A with 10 parts by weight of EVA, 0.6 parts by weight of SBS, 0.6 parts by weight of SEBS, 2.5 parts by weight of black pigment, 1.3 parts by weight of silicone (wearing agent), and 21.6 parts by weight of TPU, The screw was pumped to obtain the matte composition 3 for covering electric wires.

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PUM

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Abstract

The invention provides a matt composition for wire cladding and a matt shell for wires. The matt composition for wire cladding comprises a first thermoplastic resin and a second thermoplastic resin, wherein the second thermoplastic resin is different from the first thermoplastic resin, an absolute value of a difference between a linear expansion coefficient of the second thermoplastic resin and a linear expansion coefficient of the first thermoplastic resin is 10%-30% of the linear expansion coefficient of the first thermoplastic resin.

Description

technical field [0001] The invention relates to a matte composition, in particular to a matte composition for covering electric wires and a matte shell layer for electric wires. Background technique [0002] The sheath (or "skin") of the wire is now widely used thermoplastic polyurethane (TPU) elastomer, and flame retardant is added to replace the commonly used polyvinyl chloride (PVC) material in the past. However, when thermoplastic polyurethane resins are used in wires and cables, they need to have desired mechanical, physical and chemical properties, such as abrasion resistance, transparency, chemical resistance, flame retardancy, matting (or matte), backlash elasticity, etc. [0003] However, since additives are included in the materials for manufacturing wire sheaths (or called "compositions for manufacturing wire sheaths"), when one of the mechanical, physical and chemical properties is adjusted, other properties often change, such as adding When used as a flame ret...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L75/04C08L23/08C08L53/02
Inventor 张淑美张聪贤
Owner POLYOL MACROMOLECULE POLYMER FUJIAN
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