Methods for enhancing p-type doping in III-V semiconductor films
A III-V, semiconductor technology, applied in the field of doped III-V semiconductor film, can solve problems such as lack of understanding
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[0022]First-principles calculations for the incorporation of Zn, Mg, Be, and Cd into GaP films (001) under the influence of surface Sb and H. Sb alone was found to have little effect on the film doping energy of all dopants in the GaP film, and the film doping energy was significantly reduced by Sb only in the presence of H also. Also, surface H alone would not function effectively without Sb. Without intending to be bound by any particular theory of the invention, the inventors believe that it is the combined effect of Sb and H (dual surfactant effect) that makes the p-type doping process thermodynamically favorable. The role of Sb in generating the dual surfactant effect is to serve as an electron pool to accommodate the redistribution of electrons, similar to the concept of ECR summarized in semiconductor surfaces with metallic elements [14]. The role of H is to replenish an electron lost from the p-type dopant, so that the system can meet the ECR[15]. It is experimenta...
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