Method for activating persulphate by OMS (Octahedral Molecular Sieve)-2 to degrade organic wastewater

A technology for activating persulfate and OMS-2, which is applied in chemical instruments and methods, oxidized water/sewage treatment, multi-stage water/sewage treatment, etc., and can solve problems such as difficult reuse, complicated preparation process, and secondary pollution , to achieve the effect of broad practical application prospects, simple process flow and strong operability

Active Publication Date: 2014-08-13
WUHAN TEXTILE UNIV
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

The main technical problems to be solved are: the use of water-soluble transition metal ions as catalysts in the prior art is likely to cause secondary pollution and is difficult to reuse; Large, high cost of wastewater treatment

Method used

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  • Method for activating persulphate by OMS (Octahedral Molecular Sieve)-2 to degrade organic wastewater

Examples

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Comparison scheme
Effect test

Embodiment 1

[0024] 1) Add potassium peroxomonosulfate to 20mg / L acid orange II dye wastewater, the concentration of potassium monopersulfate in wastewater is 250mg / L, and the pH value of the solution is 3.9 at this time; 2) Add to the wastewater solution OMS-2, the concentration of OMS-2 in wastewater is 250mg / L; the decolorization rate of dyestuff after 10 minutes is 97%. In comparative experiment 1, only potassium peroxymonosulfate was added to the dye wastewater, and the decolorization rate was only 1.5% within the same time period. In contrast experiment 2, the decolorization rate was 60% when only OMS-2 was added to the dye wastewater and the pH was 3.9.

Embodiment 2

[0026] 1) Add potassium monopersulfate to 200mg / L acid orange II dye wastewater, the concentration is 500mg / L, and the pH value of the solution is 3.1; 2) Add OMS-2 to the wastewater solution, the concentration is 500mg / L ; After 30 minutes, the decolorization rate of the dye was 94%.

Embodiment 3

[0028] 1) Add potassium monopersulfate to 20mg / L acid orange II dye wastewater, the concentration is 10mg / L, adjust the pH value of the wastewater solution to 1.0 with sulfuric acid; 2) add OMS-2 to the wastewater solution, the concentration is 250mg / L; the decolorization rate of the dye was 90% after 5 minutes.

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Abstract

The invention discloses a method of activating persulphate by an OMS (Octahedral Molecular Sieve)-2 to degrade organic wastewater and relates to the field of catalytic systems and water treatment. The method comprises the following steps: adding a persulphate and OMS-2 into a wastewater solution; stirring for reacting, wherein persulphate generates sulfate radicals and hydroxyl radicals with strong oxidizing properties under the action of the OMS-2; and the radicals further oxidize persistent organic pollutants in the wastewater to finally degrade the organic wastewater. The OMS-2 added can persistently and efficiently catalyze and activate persulphate to degrade the organic wastewater and can be recycled and reused after reaction, so that the method is wide in application pH range, high in treatment efficiency at normal temperature and simple to operate and has a huge application prospect in the field of treatment of persistent organic wastewater.

Description

technical field [0001] The invention belongs to the field of organic wastewater treatment, and in particular relates to a method for degrading organic wastewater by activating persulfate with OMS-2. Background technique [0002] Advanced oxidation technology has attracted extensive attention from scholars at home and abroad because of its high efficiency in degrading organic pollutants. This oxidation technology uses strong oxidizing free radicals such as hydroxyl radicals ( OH) and hydroperoxyl ( OOH), etc., degrade organic pollutants into small molecules, and finally mineralize them into CO 2 、H 2 O and the corresponding inorganic ions. Among various catalytic systems, the catalytic system to form highly active OH to degrade pollutants has received great attention, such as H 2 o 2 / Fe 2+ , UV / H 2 o 2 , O 3 / H 2 o 2 , O 3 / UV etc. [0003] Sulfate radical (SO 4 — ) has an oxidation-reduction potential of 2.6V, which is slightly lower than that of OH (2.7V), bu...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F1/72C02F9/04
Inventor 李晓霞徐爱华段炼程强施薇罗诗露
Owner WUHAN TEXTILE UNIV
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