Coloring composition, coloring immobilizing membrane and display element
A coloring composition and coloring agent technology, applied in chemical instruments and methods, organic chemistry, instruments, etc., can solve the problems of heat resistance and solvent resistance, etc., and achieve the purpose of inhibiting dye migration and heat resistance and solvent resistance effects
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[0334] Hereinafter, an Example is given and the embodiment of this invention is demonstrated more concretely. However, the present invention is not limited to the following examples.
[0335]
Synthetic example 1
[0337] (Synthesis of Polymer (1))
[0338] Add 5.46g p-(vinylphenyl)trifluoromethanesulfonylimide acid triethylamine salt, 4.51g methyl methacrylate, 0.130g α-thioglycerol to the reaction vessel equipped with condenser, and make They are dissolved in 20 g of cyclohexanone. The solution was heated to 100°C while stirring under nitrogen flow. A solution obtained by dissolving 98.0 mg of α,α'-azobisisobutyronitrile in 10.4 g of cyclohexanone was added dropwise over 30 minutes while stirring at the same temperature, and stirring was continued at the same temperature for 3 hours after the completion of the dropwise addition. Then, after cooling the reaction solution to room temperature, 60 g of acetone was added to make a uniform solution, which was added dropwise to 1.1 L of hexane. The resulting precipitate was collected by filtration and washed with hexane. The obtained solid was dried under reduced pressure at 50° C. to obtain 8.14 g of a polymer represented by the following...
Synthetic example 2
[0344] (Synthesis of Polymer (2))
[0345] In the synthesis of polymer (1), tetraethylammonium p-styrenesulfonate was used instead of triethylamine p-(vinylphenyl)trifluoromethanesulfonimidate, and the synthesis example 1 Similarly, 8.29 g of a polymer (2) represented by the following structural formula was obtained. The Mw of the obtained polymer (2) is 8800, and the Mn is 4300, by 1 H-NMR analysis confirmed that the ratio of p to r was 1 / 2.8 in molar ratio (p / r).
[0346]
[0347] (Synthesis of Polymer B)
[0348] In the synthesis of polymer A, 2.50 g of a polymer represented by the following structural formula was obtained in the same manner as in Synthesis Example 1, except that polymer (2) was used instead of polymer (1) as shown in the following flow diagram b. Polymer B is not the present colorant.
[0349]
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