Antistatic agent composition, antistatic thermoplastic synthetic resin composition, and molded article
A technology of antistatic agent and synthetic resin, which is applied in the field of antistatic agent composition, can solve the problems of adverse effects on the surface and mechanical properties of products, poor antistatic durability, loss of antistatic property, etc., and achieve lasting effective humidity dependence and improve Antistatic performance, excellent effect of antistatic performance
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Embodiment A~J
[0031] Embodiment A~J (antistatic agent composition)
[0032] The above-mentioned homopolymer (A) and the hygroscopic inorganic salt (B) were compounded according to the ratio shown in Table 2 to prepare the antistatic agent compositions of Examples A~J of the present invention.
[0033] Table 2
[0034]
Embodiment 1~10 and comparative Embodiment 1~4
[0042] Embodiment 1~10 and comparative example 1~4 (PVC resin composition)
[0043] Using various antistatic agent compositions of Examples A~J of the present invention or Comparative Examples A~D, mixed in PVC resin according to the ratio shown below, using an extruder at 170°C and 55rpm to prepare Granular resin composition. The obtained pellets were formed into disk-shaped (100 mm in diameter x 1.6 mm in thickness) test pieces at a drum temperature of 175° C. using an injection molding machine.
[0044] The formula of polyvinyl chloride resin composition consists of (unit: part):
[0045]
[0046] The surface resistance values of these test pieces were measured by the following method, and the antistatic performance and appearance were evaluated. The evaluation results are shown in Table 4.
[0047] (1) Antistatic performance evaluation method:
[0048]A. Store various test pieces in the environment of temperature 23°C, humidity 15% and temperature 23°C, humidity 53...
Embodiment 11~20 and comparative Embodiment 5~8
[0057] Embodiment 11~20 and comparative example 5~8 (EVA resin composition)
[0058] Use various antistatic agent compositions of Examples A~J of the present invention or Comparative Examples A~D, mix them in EVA resin according to the ratio shown below, and use an extruder to make a granular resin composition. The pellets were formed into disk-shaped (diameter 100 mm×thickness 1.6 mm) test pieces using an injection molding machine.
[0059] The formula of EVA resin composition consists of (unit: part):
[0060]
[0061] The test pieces prepared above were subjected to the same evaluation test as in Examples 1-10, and the evaluation results are shown in Table 5.
[0062] table 5
[0063]
[0064] In Table 5, the blank is an EVA resin test piece to which no antistatic agent composition has been added. The test pieces of Examples 11-20 correspond to adding the antistatic agent compositions of Examples A-J respectively, and the test pieces of Comparative Examples 5-8 cor...
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