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Anti-separation and anti-corrosion environment-friendly polyaniline coating

An environmentally friendly polyaniline technology, applied in anti-corrosion coatings, epoxy resin coatings, coatings, etc., can solve the problems of poor resin compatibility in machining performance, affecting polyaniline anti-corrosion performance, consuming a lot of energy and time, etc., to achieve Good metal adhesion, high hardness, and the effect of reducing corrosion current

Inactive Publication Date: 2015-02-11
QINGDAO YIQUN PANT GRP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Although polyaniline has excellent anti-corrosion properties, its mechanical processing properties and compatibility with resins are poor, which limits its use.
The conventional methods for combining polyaniline with resin mainly include: Dissolution method: use a special solvent to dissolve and add it to the resin. This method will cause environmental pollution, poor construction conditions, and the expensive solvent will increase the cost sharply; Physical blending method: such as ball milling method, consumes a lot of energy and time, and its dispersion and stability in the resin are poor, which ultimately affects the performance of polyaniline's anti-corrosion performance; (3) first dissolve polyaniline in the amine curing agent , and then compounded with epoxy resin, this method has insurmountable defects: the content of polyaniline is low, and the content with the best anti-corrosion effect cannot be achieved

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] Embodiment 1: prepare a kind of anticorrosion coating, step is as follows:

[0028] (1) Preparation of component A: The number of raw materials used in the preparation of component A is as follows:

[0029] Liquid epoxy resin E44 73 grams;

[0030] Dioctyl phthalate 13 grams;

[0031] OP-10 2.5g;

[0032] 8 grams of n-butanol;

[0033] Ammonium persulfate 4 grams;

[0034] 2 grams of distilled water;

[0035] 0.5 gram of the aqueous solution of camphorsulfonic acid of 0.8mol / L;

[0036] 6 grams of aniline;

[0037] 0.8 grams of methyl silicone oil;

[0038] Neopentyl Glycol Diglycidyl Ether 9g.

[0039] Under the protection of nitrogen, add liquid epoxy resin E44, plasticizer dioctyl phthalate, emulsifier OP-10, 1.2g n-butanol (as a co-emulsifier), distilled water, Ammonium sulfate was stirred rapidly for 3 hours to form a stable microemulsion system with epoxy resin and plasticizer as the oil phase and oxidant aqueous solution as the nucleu...

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PUM

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Abstract

The invention discloses an anti-separation and anti-corrosion environment-friendly polyaniline coating comprising a component A and a component B, and the weight ratio of the component A to the component B is 10:1 to 20:1. The component A is prepared from the following components: 1, 73 g of liquid epoxy resin E44; 2, 13 g of dioctyl phthalate; 3, 2.5 g of OP-10; 4, 8 g of n-butyl alcohol; 5, 4 g of ammonium persulfate; 6, 2 g of distilled water; 7, 0.5 g of a 0.8 mol / L camphorsulfonic acid aqueous solution; 8, 6 g of phenylamine; 9, 0.8 g of methyl silicone oil; and 10, 9 g of neopentyl glycol diglycidyl ether. The component B is composed of the following components: 140 g of liquid aliphatic polyamine, 10 g of polyaniline, 10 g of quartz sand, 7 g of ethylene glycol monophenyl ether, 12 g of a talcum powder, and 3 g of ester gum. The coating has the advantages of high polyaniline content, good anti-corrosion property, no pollution, low cost and the like.

Description

technical field [0001] The invention relates to an anti-shedding, anti-corrosion and environment-friendly polyaniline coating. Background technique [0002] The loss caused by metal corrosion to human beings is staggering. According to statistics, the global annual metal loss due to corrosion is as high as 20%-40% of global metal production, and the economic loss is about 1 trillion US dollars. Practice has proved that the use of coatings for corrosion protection of metals is the most economical, practical and effective method. However, the current commonly used anti-corrosion coatings contain a large amount of organic solvents, which cause great pollution to the environment during the construction process and pose a huge threat to the health of workers; at the same time, commonly used anti-corrosion coatings are also rich in zinc, which not only consumes a lot of zinc resources, but also affects the health of workers. The environment is seriously polluted by heavy meta...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D163/02C09D179/02C09D5/08C08G73/02
CPCC09D163/00C08G73/0266C08L2205/025C08L2205/035C09D5/08
Inventor 董善刚刘永屏祝洒虎王伯凤张喆李春波殷晓燕潘金婷
Owner QINGDAO YIQUN PANT GRP
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