Preparation method of green petrochemical natural gas
A natural gas and petrochemical technology, applied in the field of green petrochemical natural gas preparation, can solve problems such as environmental pollution
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Embodiment 1
[0050] a. Preparation of carbon dioxide: Using oxygen and water vapor as gasification agents, react limestone at high temperature to obtain carbon dioxide; the temperature of the high temperature reaction is 1300°C.
[0051] b. Preparation of carbon monoxide: use oxygen and water vapor as gasification agents to reduce the above carbon dioxide to carbon monoxide; wherein, the reduction temperature is 1200° C., and the reduction pressure is 9 MPa.
[0052] c, synthetic natural gas: with above-mentioned carbon monoxide and hydrogen under the catalytic reaction of metal nickel, the temperature of catalytic reaction is 1400 ℃, and reaction pressure is 8MPa, and the consumption of catalyzer is 30% of carbon monoxide weight, to obtain final product.
Embodiment 2
[0054] a. Preparation of carbon dioxide: Using oxygen and water vapor as gasification agents, react limestone at high temperature to obtain carbon dioxide; the temperature of the high temperature reaction is 1600°C.
[0055] b. Preparation of carbon monoxide: use oxygen and water vapor as gasification agents to reduce the above carbon dioxide to carbon monoxide; wherein, the reduction temperature is 1000° C., and the reduction pressure is 4 MPa.
[0056] c. Synthetic natural gas: the above-mentioned carbon monoxide is desulfurized through the tannin extraction process, decarburized by the pressure swing adsorption method and purified through the conversion process to obtain purified carbon monoxide.
[0057] Then the purified carbon monoxide and hydrogen are catalyzed by metal nickel, the temperature of the catalytic reaction is 1100° C., the reaction pressure is 5 MPa, and the consumption of the catalyst is 25% of the weight of carbon monoxide to obtain final product.
Embodiment 3
[0059] a. Preparation of carbon dioxide: Using oxygen and water vapor as gasification agents, react limestone at high temperature to obtain carbon dioxide; the temperature of the high temperature reaction is 1100°C.
[0060] b. Preparation of carbon monoxide: use oxygen and water vapor as gasification agents to reduce the above carbon dioxide to carbon monoxide; wherein, the reduction temperature is 1600° C., and the reduction pressure is 9 MPa.
[0061] c. Synthetic natural gas: the above-mentioned carbon monoxide is desulfurized through the tannin extraction process, decarburized by the pressure swing adsorption method and purified through the conversion process to obtain purified carbon monoxide.
[0062] The conversion process is divided into two procedures:
[0063] The first procedure is to send the carbon monoxide gas output after desulfurization and decarbonization to the shift reactor device, and then add water vapor to make CO and water vapor (replace water to react)...
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