A kind of low carbon olefin hydration process
A technology of carbon olefin hydration and low carbon olefin, which is applied in the field of low carbon olefin hydration process, and can solve the problem that stability has not been fundamentally solved.
Active Publication Date: 2016-08-17
CHINA PETROLEUM & CHEM CORP +1
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AI Technical Summary
Problems solved by technology
However, the stability of the long-term operation of the low-carbon olefin hydration to low-carbon alcohol process has not been fundamentally resolved.
Method used
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Examples
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Embodiment 1
[0021] In Example 1, the unmodified catalyst DNW-II strong acidic cation exchange resin (produced by Dandong Mingzhu Special Resin Co., Ltd.) was directly used. Embodiment 2 adopts the SO that zinc mass content is 2% 4 2- / ZnO modified DNW-Ⅱ strong acidic cation exchange resin catalyst. Embodiment 3 adopts the SO that zinc mass content is 8% 4 2- / ZnO modified DNW-Ⅱ strong acidic cation exchange resin catalyst. The feeding methods of Examples 1-3 are all extrusion feeding by water, and n-butene and propylene are respectively used as raw materials. The reaction conditions are shown in Table 1, and the analysis results are shown in Table 2.
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A low carbon olefin hydration technology comprises the following steps: injecting water to a raw material tank full of liquid low carbon olefin, conveying the liquid low carbon olefin to water and a reactor under the extrusion of water, and carrying out a hydration reaction under the action of a catalyst under a liquid-volume hourly space velocity of the liquid low carbon olefin of 0.5-2.5h<-1> under a water / olefin mole ratio of 0.8-2.5 at a temperature of 135-170DEG C under a pressure of 5.0-10.0MPa. The technology is simple to operate, and can obviously improve the long period running stability of a method for preparing low carbon alcohol through hydration of the low carbon olefin.
Description
technical field [0001] The invention relates to a low-carbon olefin hydration process, in particular to a low-carbon olefin hydration process for producing low-carbon alcohol capable of long-term and high-stability operation. technical background [0002] The hydration reaction of light olefins is an important catalytic process. In the hydration reaction, the most representative and practical value is the preparation of alcohols through the hydration reaction of low-carbon olefins, such as ethanol, isopropanol, sec-butanol and other low-carbon alcohols. As important organic chemical raw materials and solvents, low-carbon alcohols have a very wide range of uses. Ethanol can be used to make dyes, paints, drugs, synthetic rubber, and detergents. Isopropanol can be used in the synthesis of glycerin and acetone, and can also be used in the synthesis of fine products such as pesticides and spices. Second-butanol is widely used in the synthesis of methyl ethyl ketone, or as a ra...
Claims
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IPC IPC(8): C07C29/04C07C31/12C07C31/10
CPCC07C29/04C07C31/12C07C31/10
Inventor 霍稳周魏晓霞田丹刘野李花伊
Owner CHINA PETROLEUM & CHEM CORP

