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Nylon optical fiber tight sleeve material and preparation method thereof

An optical fiber tight sleeve and nylon technology, which is applied in the field of nylon optical fiber tight sleeve material and its preparation, can solve the problems of increased optical fiber attenuation, high thermal expansion coefficient, material opacity, etc., and achieves the effects of reducing thermal expansion coefficient, improving transparency, and reducing thermal expansion coefficient.

Active Publication Date: 2018-06-08
中广核三角洲(江苏)塑化有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although nylon has the above excellent properties, ordinary grades of nylon 12 and nylon 610 cannot be directly used as optical fiber tight sleeve materials, mainly because the crystallinity of nylon often makes the material opaque, and the thermal expansion coefficient is high, resulting in optical fiber coating nylon tightness. The increase of attenuation after the sleeve cannot meet the requirements, and the commonly used low-smoke halogen-free polyethylene or PVC optical fiber tight sleeve can meet the requirements of optical fiber attenuation resistance, but its low strength, low temperature resistance, and opacity cannot meet the requirements of high temperature and high requirements. place

Method used

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  • Nylon optical fiber tight sleeve material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1~4

[0028] Embodiments 1 to 4: a nylon optical fiber tight sleeve, the nylon optical optical tight sleeve is composed of the following components, as shown in Table 1:

[0029]

Example 1

Example 2

Example 3

Example 4

Aliphatic Nylon 12

68 copies

60 copies

70 copies

62 copies

Nylon 610

22 copies

27 copies

15 copies

18 copies

Cycloolefin copolymer 5-15 parts

6 servings

7 copies

10 copies

13 copies

Maleic anhydride grafted amorphous polyolefin

2.5 servings

3.5 servings

3 copies

3 copies

0.4-1 part of hindered phenolic antioxidant

0.5 parts

0.8 parts

0.6 parts

0.6 parts

Phosphite antioxidant 0.2~0.5 parts

0.5 parts

0.2 parts

0.4 parts

0.4 parts

0.1-3 parts of plasticizer

0.5 parts

1.5 servings

1 copy

3 copies

[0030] The above-mentioned cyclic olefin copolymers are selected from 3 ethylene and norb...

Embodiment 1

[0033] The cyclic olefin copolymer of embodiment 1 is selected from 6013F produced by German TAP company, the cyclic olefin copolymer of embodiment 2 is selected from Japan Polyplastics 6013, and the cycloolefin copolymer of embodiment 3 is selected from Japan Polyplastics The company's 5013, the cyclic olefin copolymer of embodiment 4 is selected from the 6017 of Polyplastics Corporation of Japan.

[0034] A preparation method for the above-mentioned nylon optical fiber tight sleeve material, comprising the following steps:

[0035] Step 1. Put amorphous polyolefin, maleic anhydride, initiator and lubricant into the twin-screw extruder at a ratio of 100:0.4~3:0.03~1:0.1~0.3 for graft polymerization to obtain maleic anhydride 0.5-5 parts of grafted amorphous polyolefin;

[0036] Step 2: 60-70 parts of aliphatic nylon 12, 15-30 parts of nylon 610, 5-15 parts of cycloolefin copolymer, 0.5-5 parts of maleic anhydride grafted amorphous polyolefin, and 0.1 parts of plasticizer ~3...

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Abstract

The invention discloses a nylon optical tight buffered material and a preparation method thereof. The nylon optical tight buffered material comprises the following components: 60-70 parts of aliphatic nylon 12, 15-30 parts of nylon 610, 5-15 parts of a cycloolefin copolymer, 0.5-5 parts of maleic anhydride grafted amorphous polyolefin, 0.4-1 part of a hindered phenol antioxidant, 0.2-0.5 part of a phosphite ester antioxidant and 0.1-3 parts of a plasticizer, wherein the relative viscosities of the aliphatic nylon 12 and the nylon 610 are blow 2.7; the cycloolefin copolymer is selected from ethylene with density of 1.01+ / -0.01 g / cm<3> and a norbornene copolymer TOPAS resin; the plasticizer is selected from N-butylbenzene sulfonamide and N,N-dimethyl-p-toluenesulfonamide. The nylon optical tight buffered material is not easy to crystallize, high in transparency and low in coefficient of thermal expansion, and has the advantage of greatly reducing the optical attenuation loss.

Description

technical field [0001] The invention relates to an optical fiber tight sleeve material, in particular to a nylon optical fiber tight sleeve material and a preparation method thereof. Background technique [0002] The scientific name of nylon is polyamide resin, its amide group is polar, and there are strong hydrogen bonds in its structure, which makes nylon have a high melting point, excellent mechanical properties, good wear resistance and self-lubrication And good corrosion resistance, so nylon is widely used in automobiles, machinery, electronic appliances, chemicals and other fields. [0003] In the prior art, optical fiber is an important tool for information transmission, and is used for long-distance information transmission. The tiny optical fiber is encased in a plastic sheath that allows it to be bent without breaking. Although nylon has the above excellent properties, ordinary grades of nylon 12 and nylon 610 cannot be directly used as optical fiber tight sleeve...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L77/02C08L77/06C08L45/00C08L51/06C08K5/435
CPCC08F255/00C08L77/02C08L2201/10C08L2205/02C08L2205/035C08L77/06C08L45/00C08L51/06C08K5/435C08F222/06
Inventor 金蕊
Owner 中广核三角洲(江苏)塑化有限公司
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