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Method for manufacturing metal nanoparticles for solar cell, ink composition comprising metal nanoparticles, and method for forming thin film using same

一种金属纳米粒子、油墨组合物的技术,应用在金属加工设备、纳米结构制造、油墨等方向,能够解决难以形成光吸收层等问题

Inactive Publication Date: 2015-08-05
LG CHEM LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, when forming nanoparticles of metal elements and Group XVI elements, it is difficult to form a light-absorbing layer with a higher density

Method used

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  • Method for manufacturing metal nanoparticles for solar cell, ink composition comprising metal nanoparticles, and method for forming thin film using same
  • Method for manufacturing metal nanoparticles for solar cell, ink composition comprising metal nanoparticles, and method for forming thin film using same
  • Method for manufacturing metal nanoparticles for solar cell, ink composition comprising metal nanoparticles, and method for forming thin film using same

Examples

Experimental program
Comparison scheme
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Embodiment 1

[0098] Synthesis of Cu-Sn Particles

[0099] will contain 12 mmol of CuCl 2 and 10mmol of SnCl 2 The mixed aqueous solution was slowly added dropwise to the NaBH containing 60mmol 4 , the resulting solution was stirred for 1 hour to induce a reaction between them, and the formed particles were purified by centrifugation to obtain Cu 6 sn 5 bimetallic nanoparticles.

Embodiment 2

[0101] Synthesis of Cu-Sn Particles

[0102] will contain 10 mmol of CuCl 2 and 10mmol of SnCl 2 The mixed aqueous solution was slowly added dropwise to the NaBH containing 100mmol 4 In an aqueous solution of , the resulting solution was stirred for 10 hours to induce a reaction between them, and the formed particles were purified by centrifugation to obtain Cu 6 sn 5 bimetallic nanoparticles.

Embodiment 3

[0104] Synthesis of Cu-Sn Particles

[0105] will contain 12 mmol of CuCl 2 , 10mmol of SnCl 2 And 50mmol of trisodium citrate mixed aqueous solution was added dropwise to the NaBH containing 60mmol within 1 hour 4 in an aqueous solution, the resulting solution was stirred for 24 hours to induce a reaction between them, and the formed particles were purified by centrifugation to obtain Cu 6 sn 5 bimetallic nanoparticles. exist figure 2 with image 3 are shown in Cu 6 sn 5 SEM images and XRD patterns of bimetallic nanoparticles.

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Abstract

The present invention relates to a method for manufacturing metal nanoparticles for a solar cell, an ink composition comprising the metal nanoparticles, and a method for forming a thin film using the same. More specifically, the present invention relates to a method for manufacturing metal nanoparticles, an ink composition comprising the metal nanoparticles, and a method for forming a thin film using the same, wherein the method for manufacturing metal nanoparticles, as a method for manufacturing metal nanoparticles forming a light absorbing layer, comprises the steps of: preparing a first solution containing a reducing agent; preparing a second solution containing at least two salts selected from the group consisting of a copper (Cu) salt, a zinc (Zn) salt, and a tin (Sn) salt; preparing a mixture by mixing the first solution and the second solution; and synthesizing at least one kind of metal nanoparticles through a reaction of the mixture, followed by purification.

Description

technical field [0001] The invention relates to a method for preparing metal nanoparticles used in solar cells, an ink composition containing the metal nanoparticles, and a method for preparing thin films using the ink composition. More specifically, the present invention relates to a method for preparing metal nanoparticles for forming a light absorbing layer of a solar cell, an ink composition containing the metal nanoparticles, and a method for preparing a thin film using the ink composition method, the preparation method of the metal nanoparticles includes: preparing a first solution containing a reducing agent; preparing a second solution containing at least two salts selected from copper (Cu) salts, zinc (Zn) salts, and tin (Sn) salts. two solutions; preparing a mixture by mixing the first and second solutions; and synthesizing nanoparticles of at least one metal by reacting the mixture, and purifying the synthesized nanoparticles. Background technique [0002] Since ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B22F9/24B82B3/00H01L31/032B22F1/054
CPCB22F1/0018C09D11/52B22F9/24H01L31/0326Y02E10/50H01L21/02557H01L21/0256H01L21/02568H01L21/02601H01L21/02628B22F1/054C08K3/08C09D11/00H01L31/1868H01L31/18C08K2003/085C08K2003/0893
Inventor 朴银珠尹锡喜尹锡炫尹泰勋李豪燮
Owner LG CHEM LTD