Unlock instant, AI-driven research and patent intelligence for your innovation.

A method of using iron tailings to solidify copper tailings to make mine filling materials

A technology of filling materials and copper tailings, which is applied in the direction of cement production, etc., can solve problems such as shackles, achieve the effects of simple operation, increase value, and reduce filling costs

Active Publication Date: 2016-08-24
沃德费默循环经济科技发展(北京)有限公司
View PDF3 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in the current tailings filling technology, problems such as filling cost, filling material strength, and heavy metal leaching of the filling in the local environment of the goaf have constrained the development of the process. Finding an effective way to solve these problems is to promote the scale of the tailings backfilling process. the key to the application

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • A method of using iron tailings to solidify copper tailings to make mine filling materials
  • A method of using iron tailings to solidify copper tailings to make mine filling materials
  • A method of using iron tailings to solidify copper tailings to make mine filling materials

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] Example 1 Determination of strength and leaching toxicity of test pieces made of different mass parts mixing ratios

[0022] Dry the iron tailings, copper tailings and bauxite at a constant temperature until the moisture is less than 2%, mechanically grind the dried tailings for 2 hours and sieve them, and remove the Na 2 CO 3 Mix with KOH powder at a mass ratio of 1:2 to make a mixed activator, and grind the mixed activator to less than 200 mesh, and take iron tailings, copper tailings, mixed activator and bauxite in parts by mass (20, 70, 2, 8), (30, 60, 8, 2), (25, 65, 5, 5), (23, 67, 4 5 parts, 6 parts), (27 parts, 63 parts, 6 parts, 4 parts) 5 groups and stirred evenly, put the mixed sample of each group in the furnace and calcined at a high temperature of 500 ° C for 60 minutes, after the calcination was completed, the temperature in the furnace was After cooling down to room temperature, take out the activated mixture, add water to the mixture at a liquid-solid...

Embodiment 2

[0026] Example 2 Determination of strength and leaching toxicity of specimens prepared with mixed activators prepared in different mass ratios

[0027] Dry the iron tailings, copper tailings and bauxite at a constant temperature until the moisture is less than 2%, mechanically grind the dried tailings for 2 hours and sieve them, and remove the Na 2 CO 3 Mix with KOH powder at a mass ratio of 1:2, 1:3, and 1:4 to make mixed activators respectively, and grind the mixed activators to less than 200 meshes to prepare 3 mixed activators, and then in parts by mass Take 20 parts, 70 parts, 2 parts, and 8 parts of iron tailings, copper tailings, mixed activator and bauxite respectively and stir them evenly. Put the mixed samples of each group in the furnace and calcinate at a high temperature at 500 ° C. 60min, after the calcination is completed, after the temperature in the furnace drops to room temperature, take out the activated mixture, add water to the mixture at a liquid-solid m...

Embodiment 3

[0031] Example 3 Orthogonal experiment of preparing specimens under different process conditions

[0032]In this example, the effects of tailings grinding time, calcination temperature and liquid-solid ratio on the uniaxial compressive strength and heavy metal leaching toxicity of the prepared test piece are discussed through orthogonal experiments. Dry the iron tailings, copper sulfide tailings and bauxite at a constant temperature until the moisture content is less than 2%, mechanically grind and screen the dried tailings, and set the grinding time to 1h, 2h and 3h respectively. Mix Na2CO3 and KOH powders at a mass ratio of 1:4 to make a mixed activator, and grind the mixed activator to less than 200 mesh. In terms of parts by mass, 20 parts, 70 parts, 2 parts and 8 parts of iron tailings, copper tailings, mixed activator and bauxite were respectively taken and stirred evenly, and the mixed samples were placed in the furnace for calcination. The settings are 350°C, 500°C an...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
particle sizeaaaaaaaaaa
compressive strengthaaaaaaaaaa
compressive strengthaaaaaaaaaa
Login to View More

Abstract

The invention relates to a method for manufacturing a mine filling material by curing copper tailing using iron tailing. The method comprises the following steps: firstly selecting the iron tailing, the copper tailing and bauxite and drying and fining; preparing Na2CO3 and KOH powder into a mixed activator according to a mass ratio of 1:2-4 and grinding to be smaller than 200 meshes; mixing 20-30 parts by mass of fined iron tailing, 60-70 parts by mass of copper tailing, 2-8 parts by mass of bauxite and 2-8 parts by mass of mixed activator and uniformly stirring, placing the mixture in a furnace to calcine for 50-80 minutes under the condition of high temperature of 350-650 DEG C, cooling the mixture and then taking out at room temperature, adding water according to the liquid-solid mass ratio of 0.3-0.5:1 and uniformly stirring the mixture into slurry, and pouring into a mold to manufacture the filling material. Through the method, the compressive strength of a prepared test piece can reach 40.2 MPa, the heavy metal leaching toxicity meets the national standard GB5085.3-2007 'Identification standards for hazardous wastes-Identification for extraction toxicity'. By using the method, the comprehensive utilization added value of the iron tailing and the copper tailing is improved, the goaf filling cost is effectively reduced, and the mining region environment is improved.

Description

technical field [0001] The invention belongs to the field of comprehensive utilization of tailings resources and harmless treatment of waste, and in particular relates to a method for making mine filling materials by using iron tailings to solidify copper tailings. Background technique [0002] According to statistics, during the period from 1949 to 2007, the total discharge of copper tailings in my country was 2.4 billion tons. During 2007-2011, the total discharge of copper tailings was 1.355 billion tons. After 2011, the annual discharge of copper tailings has exceeded 200 million tons, and it has increased year by year. A large amount of copper tailings are discharged every year, which brings many environmental problems. The most serious problem is heavy metal pollution, followed by the chemical agents used in the beneficiation process remaining in the tailings and chemically reacting with certain components to produce new pollution sources, and the surface water flowi...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): C04B7/14
CPCY02P40/10
Inventor 李东伟黄涛黄萧周雯
Owner 沃德费默循环经济科技发展(北京)有限公司