Preparation of wc-ni micro parts, cutting tools and their preparation methods based on multi-physics field activation sintering

A technology of micro-parts and activated sintering, applied in other manufacturing equipment/tools, mechanical equipment, engine components, etc., can solve the problems of low product purity, serious product pollution, long sintering time, etc., and achieve simplified process flow and mechanical properties Excellent, short holding time effect

Active Publication Date: 2017-07-04
SICHUAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This method also needs to add grain inhibitors due to the long sintering time and high sintering temperature, which leads to large energy consumption and serious product pollution.
[0007] The inventor of the present invention intends to aim at the current situation that there are few reports on the preparation method of WC-Ni micro parts; Due to defects such as low product purity, a method for preparing WC-Ni micro parts based on multi-physics field activation sintering is provided

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] The sample used in the experiment is a Φ4*4mm cylinder and the theoretical density of the corresponding powder is used to calculate the powder mass. WC powder and Ni powder are mixed by wet grinding method according to the weight ratio of 94:6. After weighing, put the mixed powder into the mold chuck and fix it. Under the condition of vacuum degree ≤ 0.01Pa, adjust the heating rate to 50°C / s, and simultaneously apply a force of 85MPa to both ends of the mold. When the temperature reaches 300°C, keep it warm for 80s, then adjust the heating rate to 60°C / s, heat it to 1150°C and keep it warm for 10 minutes, the powder is formed in the mold and sintered, and finally cooled to room temperature at a cooling rate of 15°C / s , turn off the power and take out the parts. The relative density of the sample is 98.3%, the fracture toughness Kic is 10MPa·m1 / 2, and the product has no obvious Ni pool.

Embodiment 2

[0034] The sample used in the experiment is a Φ4*4mm cylinder and the theoretical density of the corresponding powder is used to calculate the powder mass. WC powder and Ni powder are mixed by wet grinding method according to the weight ratio of 90:10. After weighing, put the mixed powder into the mold chuck and fix it. Under the condition of vacuum degree ≤ 0.01Pa, adjust the heating rate to 25°C / s, and simultaneously apply a force of 65MPa to both ends of the mold. When the temperature reaches 180°C, keep it warm for 50s, then adjust the heating rate to 50°C / s, when heated to 1350°C, keep it warm for 8 minutes, the powder is formed in the mold and sintered, and finally cooled to room temperature at a cooling rate of 10°C / s , turn off the power and take out the parts. The relative density of the sample is 99.3%, and the HV30 is 2121kgf / mm 2 , the fracture toughness Kic is 10.1MPa m1 / 2, and the product has no obvious Ni pool.

Embodiment 3

[0036] The sample used in the experiment is a Φ4*4mm cylinder and the theoretical density of the corresponding powder is used to calculate the powder mass. Mix WC powder and Ni powder by wet grinding method according to the weight ratio of 88:12. After weighing, put the mixed powder into the mold chuck and fix it. Under the condition of vacuum degree ≤ 0.01Pa, adjust the heating rate to 40°C / s, and simultaneously apply a force of 95MPa to both ends of the mold. When the temperature reaches 270°C, keep it warm for 100s, and then adjust the heating rate to 65°C / s. After heating to 1400°C, it is sintered 13 times in the range of 1400°C-800°C. The powder is formed in the mold and sintered, and finally Cool to room temperature at a cooling rate of 10°C / s, then turn off the power and take out the parts. The relative density of the sample is 99.5%, and the HV30 is 2096kgf / mm 2 , the fracture toughness Kic is 12.1MPa m1 / 2, and the product has no obvious Ni pool.

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Abstract

The invention discloses a WC-Ni mini-type component prepared based on multi-physics field activated sintering and a preparing method of the WC-Ni mini-type component. The method comprises the steps that WC powder and Ni powder with the corresponding mass are mixed through a wet grinding method, the mixed powder is arranged in a die after weighing, the die filled with the WC-Ni mixed powder is electrified with alternating current to be rapidly heated under the conditions that the vacuum degree is smaller than or equal to 0.01 Pa and 20-100 MPa acting force exerted on the two ends of the die; the electric field constant-temperature sintering method or the electric heating fluctuation method can be adopted in the heating technology; the WC-Ni mixed powder is cooled to the room temperature after being formed in the die, and finally the component is taken out after outage. According to the WC-Ni mini-type component and the preparing method, the technological process is simplified, the forming process is easy to control, a grain inhibitor does not need to be added in the sintering process, products are free of pollution, the sintering time is shortened, the sintering temperature is reduced, and the product quality is improved.

Description

technical field [0001] The invention relates to a preparation of WC-Ni micro parts based on multi-physics field activation sintering and a preparation method thereof, belonging to the technical field of rapid sintering preparation of WC-Ni micro parts. Background technique [0002] WC–Co cemented carbide is widely used in various cutting tools, impact-resistant abrasives and wear-resistant parts due to its excellent hardness, wear resistance, good fracture strength and toughness. However, as an expensive and scarce metal, Co has extremely limited global reserves, is expensive, and has poor corrosion resistance and oxidation resistance in acidic environments. Therefore, the use of cobalt as a binder is limited to a certain extent. [0003] Ni shows good wettability to WC, and has better oxidation resistance and corrosion resistance than Co, especially after alloying, it can make the cemented carbide more excellent, and it also has no carbon content at low carbon content. Adv...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B22F3/14B22F5/00C22C29/08B22F3/105
Inventor 杨屹杨刚周宇尹德强刘剑
Owner SICHUAN UNIV
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