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Ecological functional wallpaper base paper mixed with dihydrate phosphogypsum whiskers and preparation method thereof

A dihydrate phosphogypsum, functional technology, applied in the field of interior decoration materials, can solve the problems of few research reports on dihydrate phosphogypsum whiskers, crystal structure and performance damage, and reduced paper machine running performance, etc., to achieve good heat preservation effect, Improve the mechanical strength performance and the effect of improving the pore structure

Active Publication Date: 2017-03-15
HUBEI UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, most of the phosphogypsum whiskers on the market are hemihydrate phosphogypsum whiskers with high production cost. Because the hemihydrate and anhydrous phosphogypsum whiskers are prone to hydration reaction after contacting with water, the crystal structure and performance will be destroyed and lose In addition, its high solubility will generate a large amount of calcium ions and sulfate ions in the white water system of the paper machine, which will easily lead to a series of problems such as an increase in the amount of chemicals in the wet end of the paper machine and a decrease in the running performance of the paper machine. Various modifications are required to make paper-making fillers, which greatly increases the cost
Although there have been many reports on the technology of using phosphogypsum hemihydrate whiskers as paper-making fillers, there are still few research reports on phosphogypsum dihydrate whiskers, and no related patents have been seen in China so far.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] The raw material components are calculated by weight percentage as:

[0033] Pulp 60%, dihydrate phosphogypsum whiskers 17%, humidity control agent (modified diatomite) 15%, starch (cationic starch, substitution degree 0.01—0.03) 3%, sizing agent (cationic dispersion rosin gum) 2%, wet strength agent (polyacrylamide resin) 1%, inorganic auxiliary agent (solid aluminum sulfate) 2%.

[0034]The pulp (100% by weight) is composed of 65% bleached chemical thermomechanical pulp and 35% bleached softwood pulp. The bleaching chemical thermomechanical pulp has a beating degree of 38-45°SR and a wet weight of 8.0 —10.0g, the beating degree of bleached softwood pulp is 30-35°SR, and the wet weight is 14.0-16.0g.

[0035] The preparation method of the above-mentioned ecological functional wallpaper base paper mixed with phosphogypsum whiskers comprises the following steps:

[0036] (1) Sizing: Add pulp, starch, phosphogypsum dihydrate whiskers, humidity control agent, wet strengt...

Embodiment 2

[0041] The raw material components are calculated by weight percentage as:

[0042] 65% of pulp, 17% of dihydrate phosphogypsum whiskers, 10% of humidity conditioner (modified diatomaceous earth: modified sepiolite weight ratio is 1:1), 3% of starch (cationic starch, substitution degree is 0.01- 0.03), sizing agent (alkyl ketene dimer) 2%, wet strength agent (polyamine resin) 1%, inorganic additives (solid aluminum sulfate) 2%.

[0043] The pulp (100% by weight) is composed of 75% bleached chemical thermomechanical pulp and 25% bleached softwood pulp. The bleaching chemical thermomechanical pulp has a beating degree of 38-45°SR and a wet weight of 8.0 —10.0g, the beating degree of bleached softwood pulp is 30-35°SR, and the wet weight is 14.0-16.0g.

[0044] The preparation method of the above-mentioned ecological functional wallpaper base paper mixed with phosphogypsum whiskers comprises the following steps:

[0045] (1) Sizing: Add pulp, starch, phosphogypsum whiskers, hum...

Embodiment 3

[0050] The raw material components are calculated by weight percentage as:

[0051] 70% of paper pulp, 15% of dihydrate phosphogypsum whiskers, 10% of humidity-conditioning agent (modified sepiolite), 1% of starch (natural starch), 2% of sizing agent (cation-dispersed rosin gum), wet strength agent 1% (epichlorohydrin resin), inorganic additives (solid aluminum sulfate) 2%.

[0052] In addition, 1% of the antibacterial agent by the total weight of the above-mentioned raw materials was added.

[0053] The pulp (100% by weight) is composed of 70% bleached chemical thermomechanical pulp and 30% bleached softwood wood pulp. The bleaching chemical thermomechanical pulp has a beating degree of 38-45°SR and a wet weight of 8.0- 10.0g, the beating degree of bleached softwood pulp is 30-35°SR, and the wet weight is 14.0-16.0g.

[0054] The preparation method of the above-mentioned ecological functional wallpaper base paper mixed with phosphogypsum whiskers comprises the following ste...

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Abstract

The invention provides ecological functional type wallpaper raw paper doped with dihydrate phosgypsum crystal whiskers and a preparation method thereof. The ecological functional type wallpaper raw paper is prepared from the following raw materials in weight percent: 60%-80% of paper pulp, 9%-17% of the dihydrate phosgypsum crystal whiskers, 8%-15% of a humidifying agent, 1%-3% of starch, 1%-2% of a sizing agent, 0.1%-1% of a wet strength agent and 1%-2% of an inorganic auxiliary agent, wherein the humidifying agent is modified diatomite and / or modified sepiolite, and the whiteness is more than or equal to 95%; the sum of the raw materials is 100%. The prepared wallpaper raw paper is ecological and environmentally friendly, has the effects of humidifying and absorbing sounds, and preserving and insulating heat, and also has the characteristics of high strength, wear resistance, bacterium resistance, fire resistance and the like.

Description

technical field [0001] The invention relates to the technical field of interior decoration materials, in particular to an ecological functional wallpaper base paper mixed with dihydrate phosphogypsum whiskers. Background technique [0002] With the continuous improvement of modern people's living standards, wallpaper is more and more valued as an interior wall decoration material. Bleached chemical wood pulp is usually used to produce wallpaper base paper, and then processed by different processes, such as coating, printing, embossing or surface coating, and finally cut and packaged before leaving the factory. There are many types of wallpaper, such as non-woven wallpaper, resin wallpaper, pure paper wallpaper, fabric wallpaper and so on. [0003] In recent years, the concept of "green environmental protection" has been put forward, and the use of resin wallpaper has been restricted. Pure paper wallpaper is one of the widely used indoor wall decoration wallpapers. It is bas...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D21H27/20D21H21/16D21H21/20D21H21/06D21H17/28D21H17/63
Inventor 贺行洋代飞苏英曾三海李颜娟王迎斌孙艺恒储劲松秦景燕江波王传辉
Owner HUBEI UNIV OF TECH