Photo-post-curing resin composition

A resin composition and post-curing technology, applied in the field of light post-curable resin compositions, can solve the problems of component deterioration, shortened life, and deterioration of luminous properties.

Active Publication Date: 2015-11-04
SEKISUI CHEM CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] However, such an organic EL display element has a problem that if the organic light-emitting material layer and electrodes are exposed to outdoor air, the light-emitting characteristics will deteriorate rapidly and the life will be shortened.
However, there is a problem that when a photocurable adhesive is used in this way, degassing occurs when light is irradiated and the inside of the device is filled, which accelerates the deterioration of the device.

Method used

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  • Photo-post-curing resin composition
  • Photo-post-curing resin composition
  • Photo-post-curing resin composition

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0084] 50 parts by weight of bisphenol F type epoxy resin (manufactured by DIC Corporation, "EPICLON EXA-830LVP"), 25 parts by weight of hydrogenated bisphenol A type epoxy resin (manufactured by Mitsubishi Chemical Corporation, "jER YL8034") Parts by weight, and 25 parts by weight of hydrogenated bisphenol F-type epoxy resin (manufactured by Mitsubishi Chemical Corporation, "jER YL6753"), aromatic sulfonium salt as a photocationic polymerization initiator (manufactured by Midori Kagaku, "DTS-200") 1.0 parts by weight, 5 parts by weight of triglycidyl isocyanurate (manufactured by Nissan Chemical Co., Ltd., "TEPIC") as a compound having a tertiary amino group and a cationic polymerizable functional group, 2,4-diethylene glycol as a sensitizer 0.01 part by weight of thioxanthone (manufactured by Nippon Kayaku Co., Ltd., "DETX-S"), γ-glycidoxypropyltrimethoxysilane (manufactured by Shin-Etsu Silicone Co., Ltd., "KBM-403") as a silane coupling agent ") and 1 part by weight of a f...

Embodiment 2~6、 comparative example 1~3

[0086] According to the compounding ratio of Table 1, each material described in Table 1 was stirred and mixed similarly to Example 1, and the photopost-curable resin composition was produced.

[0087]

[0088] The following evaluations were performed about each photopost-curable resin composition obtained in the Example and the comparative example. The results are shown in Table 1.

[0089] (1) Viscosity

[0090] About each photopost-curable resin composition obtained by the Example and the comparative example, the viscosity in 25 degreeC and conditions of 100 rpm was measured using the E-type viscometer (made by Toki Sangyo Co., Ltd., "VISCOMETER TV-22").

[0091] (2) Curing delay

[0092] Using an ultraviolet irradiation device (manufactured by Oak Corporation, "JL-4300-3S"), 1500 mJ / cm was irradiated to the test pieces of each photo-post-curable resin composition obtained in Examples and Comparative Examples 2 of ultraviolet light. Curability was confirmed after 10 m...

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Abstract

The purpose of the present invention is to provide a photo-post-curing resin composition that makes it possible to suppress the generation of outgas and has exceptional transparency and reliability. The present invention is a photo-post-curing resin composition containing a cationically curable resin, a photo-cationic polymerization initiator, and a compound having amino groups and cationically polymerizable functional groups.

Description

technical field [0001] The present invention relates to a photopost-curable resin composition capable of suppressing the occurrence of outgassing and excellent in transparency and reliability. Background technique [0002] In recent years, research on organic light-emitting devices using organic thin-film elements such as organic electroluminescence (organic EL) display elements and organic thin-film solar cell elements is ongoing. An organic thin film element can be easily produced by vacuum deposition, solution coating, etc., and thus is also excellent in productivity. [0003] An organic EL display element has a thin-film structure in which an organic light-emitting material layer is sandwiched between a pair of electrodes facing each other. In this organic light-emitting material layer, electrons are injected from one electrode and holes are injected from the other electrode, whereby electrons and holes are combined in the organic light-emitting material layer to perfor...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G59/20C08G59/68C08L63/00
CPCC08G59/20C08G59/68C08L63/00C08G2650/24
Inventor 渡边康雄七里德重
Owner SEKISUI CHEM CO LTD
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