Green expansive cementing material based on salt chemical industry solid waste and building garbage, preparation method and applications thereof

A technology for cementitious materials and construction waste, which is used in fillings, mining equipment, earth-moving drilling, etc., can solve the problems of poor topping and high production costs, and achieve strong consolidation, high early strength, and good expansion. Effect

Inactive Publication Date: 2015-12-16
胡相明
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] In order to realize the resource reuse of salt chemical solid waste (calcium carbide slag, salt mud, Glauber’s salt) and construction waste (gravel, broken brick, concrete block), solve the problems of poor topping performance and high production cost of existing mine filling materials , the present invention creatively proposes a green expansive gelling material based on salt chemical solid waste and construction waste. The green expansive gelling material has good expansion, fluidity, consolidation and early strength, and can actively top, effectively control surface subsidence, while realizing the resource utilization of salt chemical solid waste (carbide slag, salt mud, Glauber's salt) and construction waste (gravel, broken brick, concrete block), etc., overcome the mine filling in the existing technology Poor topping of materials, high production costs and other technical problems, have high economic benefits and social significance

Method used

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  • Green expansive cementing material based on salt chemical industry solid waste and building garbage, preparation method and applications thereof
  • Green expansive cementing material based on salt chemical industry solid waste and building garbage, preparation method and applications thereof
  • Green expansive cementing material based on salt chemical industry solid waste and building garbage, preparation method and applications thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0040] 1-3 parts of calcium carbide slag, 0.5-3 parts of salt mud, 0.5-3 parts of Glauber's salt, 40 parts of crushed stone, 20 parts of blast furnace slag, 10 parts of desulfurized gypsum, 1 part of water reducing agent, 0.02 parts of expansion agent, soluble calcium Mix 2 parts of salt and 1 part of grinding aid (triethanolamine or triisopropanolamine) evenly, and grind to obtain a green expansive gelling material. Mix the above-mentioned green expansive cementitious material with water, fly ash, and sand in a mass ratio of 1:2.3:4:15 to prepare cementitious material sample 1.

Embodiment 2

[0042] 0.8-1 part of calcium carbide slag, 1 part of salt mud, 1.5 parts of Glauber's salt, 40-45 parts of crushed stone, 30-35 parts of blast furnace slag, 10-20 parts of desulfurized gypsum, 0.8 part of water reducing agent, 0.03 part of aluminum powder, soluble 2 parts of calcium salt, 1 part of grinding aid (triethanolamine or triisopropanolamine), mixed evenly, and ground to obtain green expansive gelling material. Mix the above-mentioned green expansive cementitious material with water, sand, and fly ash at a mass ratio of 1:2.1:4:15 to prepare cementitious material sample 2.

Embodiment 3

[0044] 1.2 parts of calcium carbide slag, 2 parts of salt mud, 1.5 parts of Glauber's salt, 30-40 parts of crushed stone, 20-30 parts of blast furnace slag, 10-15 parts of desulfurized gypsum, 0.05-0.1 parts of water reducing agent, and 0.01-0.03 parts of expansion agent , 2 parts of soluble calcium salt, 0.5-1.5 parts of grinding aid (triethanolamine or triisopropanolamine), mix evenly, and grind to obtain green expansive gelling material. Mix the above-mentioned green expansive cementitious material with water, fly ash, and sand according to the mass ratio of cementitious material: water: fly ash: sand in a specific ratio of 1:2:4:13, and prepare cementitious material sample 3 .

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Abstract

The present invention discloses a green expansive cementing material based on salt chemical industry solid waste and building garbage, and a preparation method thereof, wherein salt-containing chemical industry waste (salt mud, carbide slag and mirabilite), building garbage (gravel, broken bricks and concrete blocks), steelmaking plant waste residue (water residue and steel residue) and power plant desulfuration gypsum are matched with an expander, a water reducer, a soluble calcium salt and other components, and fine grinding and uniform mixing are performed to prepare the green expansive cementing material. According to the present invention, the salt mud, the carbide slag, the mirabilite and other solid waste produced by the salt chemical industry enterprise are digested while the building garbage, the desulfuration gypsum, the water residue and other solid water are subjected to the resource utilization, such that the green expansive cementing material is the green environmental protection cementing material; and the green expansive cementing material has characteristics of good expansion property, good fluidity, good consolidation property, good early strength, active tightening and effective earth's surface sinking control, is the cementing material for mine, and is particularly suitable for the filling mining of coal mines or non-coal mines.

Description

technical field [0001] The invention relates to the field of resource utilization of salt chemical waste, construction waste and mine filling cementing material, in particular to a green expansive cementing material based on industrial waste. Background technique [0002] The solid waste produced by salt chemical enterprises, such as salt mud, calcium carbide slag, and thenardite, has complex recycling processes and poor economic benefits, resulting in a large amount of solid waste accumulated and left idle. On the one hand, the stacking of solid waste occupies a large amount of land resources, on the other hand, it seriously pollutes the soil, water bodies and the atmosphere, and destroys the local ecological environment. Therefore, how to realize the recycling of solid waste such as salt mud, carbide slag and Glauber's salt is an urgent problem for salt chemical enterprises. [0003] At the same time, with the continuous acceleration of my country's urbanization process, ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B7/24C04B7/38C04B22/06C04B22/10C04B22/14C04B22/00E21F15/00
CPCY02P40/10Y02P40/121
Inventor 胡相明程卫民李贻久张宝阳李高鲁
Owner 胡相明
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