Silicic acid fertilizer and preparation technology thereof

A technology of silicic acid and chemical fertilizer, which is applied in the field of agricultural chemical fertilizers, can solve the problems that phosphate fertilizers cannot be used in combination, the effective utilization rate is not enough, calcium silicate agglomerates and hardens, etc., and achieves the effects of small investment, low production cost and moderate solubility

Inactive Publication Date: 2016-02-17
宋淑芹
View PDF0 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The current silicon fertilizers are all made of calcium silicate as an active ingredient, but the hydrolysis reaction of calcium silicate is a reversible reaction with a small equilibrium constant. The amount of silicic acid released by calcium silicate to the surrounding water body is very limited, and silicon Calcium silicate itself has strong hydraulic coagulation, and calcium silicate molecules will form a solid three-dimensional network structure after reacting with water molecules, so calcium silicate will gradually agglomerate and harden in water, losing its original hydrolytic activity. For this reason, the real effective utilization rate of the so-called "effective silicon dioxide" contained in calcium silicate is less than 10% of its actual content, which causes a lot of waste
Moreover, the existing silicon fertilizers with calcium silicate as active ingredients are alkaline and cannot be mixed with nitrogen fertilizers and phosphate fertilizers. Generally, they can only be used alone as base fertilizers.
And take silicic acid as the chemical fertilizer of active ingredient, there is no report yet

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] Embodiment 1 prepares silicic acid fertilizer with sodium silicate

[0029] a, take solid sodium silicate (Na 2 Si0 3 9H2 0) as the raw material to obtain product A;

[0030] b. Make product A into a sodium silicate solution with a concentration of 25%, add hydrochloric acid for neutralization reaction, so that the pH value of the sodium silicate solution does not exceed 6.5, and the obtained silicic acid colloid solution is used as product B: the chemical reaction formula is : Na 2 Si0 3 +2HC→2NaCl+H 2 Si0 3

[0031] c. Use the heating gelation precipitation method to transfer product B into a sedimentation tank, heat to 80-100°C, and keep the temperature for 3 hours. After the silicic acid in product B is completely precipitated, the obtained product is used as product C;

[0032] d. Send product C to a vacuum filter for filtration, wash the sediment with mixed water to remove soluble salt impurities, and then continue to wash the sediment with 8% dilute ammoni...

Embodiment 2

[0034] Embodiment 2 uses sodium silicate to make each silicic acid fertilizer

[0035] a. Take solid sodium silicate as raw material to obtain product A:

[0036] b. Make product A into a sodium silicate solution with a concentration of 25%, add sulfuric acid to carry out neutralization reaction, so that the pH value of the sodium silicate solution does not exceed 6.5, and the obtained silicic acid colloid solution is used as product B; the chemical reaction formula is : CaSi03+C02+H20→CaC03↓+H2Si03:

[0037] c. Using the animal gel coagulation precipitation method, add sulfuric acid to product B to make the acidity of the silicic acid colloidal solution reach 0-1 mol / liter, then add the animal gelatin solution with a concentration of 2% and a volume of the silicic acid colloidal solution of 10%, and then Heat to 60-800°C and keep the temperature for 1 hour, until the silicic acid in product B is completely precipitated, and the obtained product is product C: animal glue is p...

Embodiment 4

[0046] Embodiment 4 makes each silicic acid chemical fertilizer (carbon dioxide neutralization method) with the block containing calcium silicate

[0047] a, take ironmaking slag (also can be yellow phosphorus slag or ferromanganese slag, also can be the block that burns with limestone and clay) as raw material, get A product;

[0048] b. Crush product A and put it into a reaction container, add water 10 times the weight of product A, and pass in carbon dioxide gas while stirring until the pH value of the solution is ≤ 6.5, stop the ventilation, filter, and the obtained filter residue is silicon-rich Calcium carbonate precipitation of acid, as B slag, the obtained filtrate is a colloidal solution of silicic acid, called B liquid;

[0049] c. Using the gelation precipitation method, heat liquid B to 80-100°C and keep it warm for 3 hours. After the silicic acid in liquid B is completely precipitated, add B slag and stir evenly to make the silicic acid precipitate adsorb on the c...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention relates to a silicic acid fertilizer and a preparation technology thereof. The content of silicic acid in the silicify fertilizer is higher than 10%, and the pH value of a saturation extract is lower than 6.5. The silicic acid fertilizer is prepared by the following steps: sodium silicate or material blocks containing calcium silicate are used as raw materials, raw materials are neutralized with acid, a silicic acid colloidal solution is prepared, a deposition treatment is carried out, after filtering, washing, neutralization, drying and crushing, a finished product is obtained. The prepared silicic acid fertilizer has the following characteristics: the silicic acid content is high; after the fertilizer is applied to fields, the soil does not cake and deteriorate; the fertilizer is long-term effective, wherein utilization rate of silica is 100%; the solubility is moderate and the fertilizer efficiency is high, and the fertilizer can be used as a base fertilizer and an additional fertilizer; outputs of crops can be greatly increased; the fertilizer can be prepared into a complex fertilizer with a nitrogenous fertilizer, a phosphate fertilizer, a potash fertilizer and other common fertilizers, and usage of the fertilizer is convenient; the preparation technology is simple, investment is low and production cost is low.

Description

technical field [0001] The invention belongs to the field of agricultural chemical fertilizers, and in particular relates to a silicic acid fertilizer and a preparation process thereof. Background technique [0002] As we all know, the body of plants contains a certain amount of silica, which is an important component of plant bodies. Plants need to continuously absorb silica from the surrounding environment during their growth. The silica absorbed by plants comes from silicic acid dissolved in soil moisture. Studies have shown that silica dissolved in natural water bodies actually exists in the form of silicic acid. The content of silicon dioxide in the soil is very high, but the silicon dioxide in the soil cannot be dissolved in water directly. The silicon dioxide can only be dissolved in water after hydration reaction with water to form silicic acid. The hydration reaction of silicon oxide is extremely slow, and the released silicic acid is very rare, so that the conten...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): C05D9/00
Inventor 宋淑芹
Owner 宋淑芹
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products