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96 results about "Equilibrium constant" patented technology

The equilibrium constant of a chemical reaction is the value of its reaction quotient at chemical equilibrium, a state approached by a dynamic chemical system after sufficient time has elapsed at which its composition has no measurable tendency towards further change. For a given set of reaction conditions, the equilibrium constant is independent of the initial analytical concentrations of the reactant and product species in the mixture. Thus, given the initial composition of a system, known equilibrium constant values can be used to determine the composition of the system at equilibrium. However, reaction parameters like temperature, solvent, and ionic strength may all influence the value of the equilibrium constant.

Determination apparatus and determination method for concrete impact flexural-tensile injury based on non-equilibrium state

InactiveCN104913985AOvercoming the difficulty of measuring the transmitted wave in the testReduce mistakesMaterial strength using single impulsive forceData acquisitionEquilibrium constant
The present invention discloses a determination apparatus for concrete impact flexural-tensile injury based on non-equilibrium state. The determination apparatus is characterized by comprising a gas gun, a bullet, an incident rod, a transmission rod, a strain sheet, a bridge box and a data acquisition system connected with a computer, wherein the strain sheet is adhered on the middle portion of the incident rod and is connected with the data acquisition system through the bridge box, the incident rod and the transmission rod are respectively provided with a sleeve head, the sleeve heads are respectively provided with a pad block, and a concrete specimen is sandwiched between the pad blocks on the two rods. With the determination apparatus and the determination method of the present invention, the concrete injury theory is introduced into the flexural concrete determination under impact load, such that the difficulty that the flexural concrete injury time is short under the impact load is overcome, and the relationship curve between the tensile strength and the injury time during the concrete flexibility is obtained; and the difficult problem that the transmitted wave is difficult to determine through the test is overcome, and the error is substantially reduced during the wave superimposing.
Owner:POWERCHINA XIBEI ENG +1

Treatment method for rare earth phosphate rock and enrichment method for rare earth

The invention discloses a treatment method for a rare earth phosphate rock and an enrichment method for rare earth. The treatment method comprises the following steps: mixing the rare earth phosphate rock and phosphoric acid to form mixed slurry; adding concentrated sulfuric acid into the mixed slurry in such a manner that the concentration of Ca<2+> in the mixed slurry is decreased from at least 1 wt% to the equilibrium concentration of Ca<2+> and SO4<2->, then the concentration of SO4<2-> in the mixed slurry is increased from the equilibrium concentration of Ca<2+> and SO4<2-> to at least 2 wt% and the mixed slurry is added during addition of the concentrated sulfuric acid to allow the rare earth phosphate rock to be dissolved so as to obtain hemihydrate gypsum; and subjecting the obtained hemihydrate gypsum to recrystallization to obtain dihydrate gypsum. The enrichment method for rare earth comprises a step of recovering rare earth elements from liquid obtained after recrystallization of the hemihydrate gypsum and/or liquid obtained after heating of the mixed slurry. In the process of generation of the hemihydrate gypsum, the addition speed of the concentrated sulfuric acid is controlled, and SO4<2-> in the mixed slurry is allowed to be insufficient at first and then controlled to be excess, which aids rare earth in entering into the phosphoric acid.
Owner:GRIREM ADVANCED MATERIALS CO LTD

Material mixing method of graphite negative electrode slurry

The invention provides a material mixing method of graphite negative electrode slurry. The graphite negative electrode slurry comprises a first graphite material, a second graphite material and a third graphite material, wherein the average grain diameter of the first graphite material is d1, the average grain diameter of the second graphite material is d2, and the average grain diameter of the third graphite material is d3, wherein d1 is smaller than d2 which is smaller than d3, and d2 is equal to k*(d1+d3); k is equal to a*(c1+c3)/(c2+0.5), wherein a is an equilibrium constant, and a is greater than or equal to 1.1 and less than or equal to 1.3; c1, c2 and c3 represent percentages of the first graphite material, the second graphite material and the third graphite material; and c1+ c2 +c3is equal to 1, and c1+c2 is less than or equal to c3. The material mixing method comprises the following steps of carrying out mixing on the first graphite material, the second graphite material andthe third graphite material to obtain three slurry materials respectively, and then enabling the three slurry materials to be mixed according to a specific sequence to obtain the graphite negative electrode slurry with high dispersion degree. The graphite negative electrode slurry disclosed by the invention is high in graphite dispersion degree, free of agglomeration, free of sedimentation, high in storage stability, high in energy density and high in rate performance.
Owner:山东中信迪生电源有限公司

Method and computer system for quantum chemical modelling of molecules under non-equilibrium conditions

The invention relates to a method an computer system for using extrapolation analysis to express an approximate self-consistent solution or a change in a self-consistent solution based on a change in the value of one or more external parameters, said self-consistent solution being used in a model of a system having at least two probes or electrodes, which model is based on an electronic structure calculation comprising a self-consistent determination of an effective one-electron potential energy function and / or an effective one-electron Hamiltonian. The method of the invention comprises the steps of: determining a first self-consistent solution to a selected function for a first value of a first external parameter by use of self-consistent loop calculation; determining a second self-consistent solution to the selected function for a second value of the first selected external parameter by use of self-consistent loop calculation, said second value of the first selected external parameter being different to the first value of the first selected external parameter; and expressing an approximate self-consistent solution or a change in the self-consistent solution for the selected function for at least one selected value of the first selected external parameter by use of extrapolation based on at least the determined first and second self-consistent solutions and the first and second values of the first selected external parameter.
Owner:ATOMISTIX

Method for measuring diffusion coefficient and equilibrium concentration of CO2 in process of diffusion from water phase to oil phase

The invention relates to a method for measuring the diffusion coefficient and the equilibrium concentration of CO2 in the process of diffusion from a water phase to an oil phase. According to the method, the water-phase saturated CO2 at the bottom of a U-shaped pipe is formed into saturated carbonated water; CO2 is injected into the end a of the U-shaped pipe, and crude oil is injected into the end b of the U-shaped pipe; as CO2 in the water phase diffuses to the oil phase, CO2 in the saturated carbonated water is not saturated again, and therefore, the gaseous-phase CO2 is dissolved in the carbonated water. Pressure change due to the diffusion of the CO2 to the carbonated water is measured, and then the diffusion coefficient of the CO2 during diffusion from the water phase to the oil phase and the equilibrium concentration of the CO2 in the crude oil after equilibrium can be obtained in combination with a pressure drop formula. According to the method, the method for measuring the diffusion coefficient of the CO2 in the process of diffusion from the water phase to the oil phase by use of an improved PVT pressure drop method is provided for the first time, and the method is simple to operate and clear in principle; the diffusion coefficient can be obtained without directly measuring the concentration change of CO2 in the process of diffusion from the water phase to the oil phase; the method is significant for studying the migration and distribution of CO2 between the water phase and the oil phase and guiding oil-gas field development.
Owner:CHINA UNIV OF PETROLEUM (EAST CHINA)

Preparation method for monoclonal antibody specifically binding vardenafil and analog thereof

The invention relates to a preparation method for a monoclonal antibody specifically binding vardenafil and an analog thereof. The preparation method comprises the steps of: synthesizing artificial immunizing antigens and artificial testing antigens, screening mice under immune state and the monoclonal antibody, and conducting structural specificity identification of the monoclonal antibody, specifically, mixing M-BSA with the vardenafil, regulating pH, adding a glutaraldehyde coupling agent, slowly stirring with a magnetic stirrer for reaction, dialyzing with distilled water, freezing and drying under vacuum condition, and synthesizing the artificial immunizing antigens; mixing M-OVA with the vardenafil, regulating pH, adding a glutaraldehyde coupling agent, slowly stirring with a magnetic stirrer for reaction, dialyzing with distilled water, freezing and drying under vacuum condition, and synthesizing the artificial testing antigens; and using a competitive inhibition ELISA method to detect the coasensual reaction between the monoclonal antibody and the vardenafil and piperidenafil and identifying the monoclonal antibody which has high coasensual reaction rate and can specifically bind the vardenafil and the analog thereof. The affinity equilibrium constant of the monoclonal antibody prepared by the method on the vardenafil and the analog thereof is higher than 10M.
Owner:NANCHANG UNIV

Refined heavy-hydrocarbon removal system for recovering LNG/LPG/NGL from petroleum associated gas

The invention provides a refined heavy-hydrocarbon removal system for recovering LNG/LPG/NGL from petroleum associated gas, which comprises a raw material associated gas inlet pipeline, an LPG cold box, a low-temperature separator and a refined removed heavy hydrocarbon absorption tower, wherein an outlet of a lower box of the LPG cold box is connected with the refined removed heavy hydrocarbon absorption tower by a pipeline, an outlet at the bottom of the refined removed heavy hydrocarbon absorption tower is connected with a tower-bottom liquid phase pipeline, an outlet at the top of the refined removed heavy hydrocarbon absorption tower is connected with a lower middle box of the LPG cold box by a pipeline, the lower middle box is connected with the low-temperature separator by a pipeline, the bottom of the low-temperature separator is connected with an absorbent booster pump by a pipeline, and the absorbent booster pump is connected with the refined removed heavy hydrocarbon absorption tower by a pipeline. By using the characteristic that the equilibrium constants of hydrocarbon substances at different temperatures and consisting of different components are different, the system dilutes the heavy hydrocarbon content of associated gas, thereby achieving the purpose of reducing the heavy hydrocarbon content of dry gas; the temperature of associated gas is reduced two times by using the cold box so as to meet different temperature requirements of absorption and separation; and due to the adoption of the absorption tower, the precision of heavy hydrocarbon removal is improved.
Owner:XIAN CHANGQING TECH ENG

VPCE (vapor phase catalytic exchange) static performance testing method

ActiveCN106841447AAppropriate treatment method planComponent separationSeparation factorWater vapor
The invention discloses a VPCE (vapor phase catalytic exchange) static performance testing method. The method comprises the following steps: S1, putting a catalyst to be detected and analyzed in a reaction tank, and closing; S2, vacuumizing a reaction vessel: washing several times, and then vacuumizing the reaction vessel; S3, separating a mixing tank and the reaction tank to form independent spaces; and introducing pure hydrogen into the mixing tank, and injecting deuterium-containing water into the mixing tank; S4, regulating a temperature control device, so that the temperature of the reaction vessel reaches a preset temperature value; monitoring a pressure sensor and a temperature sensor of the mixing tank and the reaction tank; when the temperature and pressure from the both reach preset requirements, enabling the mixing tank to communicate with the reaction tank; and reacting deuterium-containing vapor and hydrogen gas in the presence of a hydrophilic catalyst; and S5, sampling and detecting: sampling from the reaction tank at set intervals, detecting and analyzing. The VPCE static performance testing method disclosed by the invention can accurately acquire the kinetic curve, equilibrium constant, separation factor and other parameters of hydrogen-water isotope catalytic exchange reaction.
Owner:MATERIAL INST OF CHINA ACADEMY OF ENG PHYSICS
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