Composition for forming cured film, orientation material, and retardation material
A curing film and composition technology, applied in the direction of instruments, polarizing elements, optical elements, etc., can solve the problems of low display contrast ratio, difficulty in improving contrast ratio and brightness, response speed, brightness change/color change, etc., Achieve the effects of efficient formation, high transparency, high solvent resistance, and excellent vertical alignment
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[0164] Hereinafter, examples are given and the present invention will be described in more detail, but the present invention is not limited by these examples.
[0165] [Abbreviated symbols used in Examples]
[0166] The meanings of the abbreviations used in the following examples are as follows.
[0167]
[0168] LAA: lauryl acrylate
[0169] EHA: 2-ethylhexyl acrylate
[0170] HEMA: 2-Hydroxyethyl methacrylate
[0171] HEA: 2-Hydroxyethyl Acrylate
[0172] MAA: methacrylic acid
[0173] MMA: methyl methacrylate
[0174] BMAA: N-Butoxymethacrylamide
[0175] AIBN: α,α'-Azobisisobutyronitrile
[0176]
[0177] CYM303: Hexamethoxymethylmelamine
[0178]
[0179] PTSA: p-toluenesulfonic acid monohydrate
[0180]
[0181] PM: Propylene Glycol Monomethyl Ether
[0182] MIBK: Isobutyl methyl ketone
[0183] The number-average molecular weight and weight-average molecular weight of the acrylic copolymer obtained according to the following synthesis examples were de...
Synthetic example 1
[0185] By dissolving 13.8 g of MAA, 14.1 g of LAA, 7.2 g of HEMA, and 0.68 g of AIBN as a polymerization catalyst in 107.0 g of PM, it was reacted at 80° C. for 16 hours to obtain an acrylic copolymer solution (solid content concentration 25 mass %) (P1). Mn of the obtained acrylic copolymer was 13,300, and Mw was 27,800.
Synthetic example 2
[0187] 8.8 g of MAA, 14.0 g of LAA, 5.2 g of HEMA, and 0.53 g of AIBN as a polymerization catalyst were dissolved in 85.5 g of PM, and reacted at 80° C. for 16 hours to obtain an acrylic copolymer solution (solid content concentration: 25 mass %) (P2). Mn of the obtained acrylic copolymer was 11,900, and Mw was 28,800.
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