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Composition for forming cured film, orientation material, and retardation material

A curing film and composition technology, applied in the direction of instruments, polarizing elements, optical elements, etc., can solve the problems of low display contrast ratio, difficulty in improving contrast ratio and brightness, response speed, brightness change/color change, etc., Achieve the effects of efficient formation, high transparency, high solvent resistance, and excellent vertical alignment

Active Publication Date: 2021-07-13
NISSAN CHEM CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] The characteristic of IPS-LCD is that since there is no inclination in the vertical direction of the liquid crystal molecules, there is little brightness change / color change due to the viewing angle; however, as disadvantages, it is difficult to improve the contrast ratio, brightness, and response speed
For example, as disclosed in Patent Document 1, the viewing angle compensation film was not used in the IPS-LCD at the initial stage of proposal. , so there is a disadvantage that the value of the display contrast ratio is low

Method used

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  • Composition for forming cured film, orientation material, and retardation material
  • Composition for forming cured film, orientation material, and retardation material
  • Composition for forming cured film, orientation material, and retardation material

Examples

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Effect test

Embodiment

[0164] Hereinafter, examples are given and the present invention will be described in more detail, but the present invention is not limited by these examples.

[0165] [Abbreviated symbols used in Examples]

[0166] The meanings of the abbreviations used in the following examples are as follows.

[0167]

[0168] LAA: lauryl acrylate

[0169] EHA: 2-ethylhexyl acrylate

[0170] HEMA: 2-Hydroxyethyl methacrylate

[0171] HEA: 2-Hydroxyethyl Acrylate

[0172] MAA: methacrylic acid

[0173] MMA: methyl methacrylate

[0174] BMAA: N-Butoxymethacrylamide

[0175] AIBN: α,α'-Azobisisobutyronitrile

[0176]

[0177] CYM303: Hexamethoxymethylmelamine

[0178]

[0179] PTSA: p-toluenesulfonic acid monohydrate

[0180]

[0181] PM: Propylene Glycol Monomethyl Ether

[0182] MIBK: Isobutyl methyl ketone

[0183] The number-average molecular weight and weight-average molecular weight of the acrylic copolymer obtained according to the following synthesis examples were de...

Synthetic example 1

[0185] By dissolving 13.8 g of MAA, 14.1 g of LAA, 7.2 g of HEMA, and 0.68 g of AIBN as a polymerization catalyst in 107.0 g of PM, it was reacted at 80° C. for 16 hours to obtain an acrylic copolymer solution (solid content concentration 25 mass %) (P1). Mn of the obtained acrylic copolymer was 13,300, and Mw was 27,800.

Synthetic example 2

[0187] 8.8 g of MAA, 14.0 g of LAA, 5.2 g of HEMA, and 0.53 g of AIBN as a polymerization catalyst were dissolved in 85.5 g of PM, and reacted at 80° C. for 16 hours to obtain an acrylic copolymer solution (solid content concentration: 25 mass %) (P2). Mn of the obtained acrylic copolymer was 11,900, and Mw was 28,800.

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Abstract

The object of the present invention is to provide an alignment material having excellent vertical alignment and capable of highly sensitive alignment even on a resin film, and a composition for forming a cured film for providing a retardation material using the alignment material. The polymerizable liquid crystal is aligned vertically. The solution of the present invention is a composition for forming a cured film, an orientation material, and a retardation material, wherein the composition for forming a cured film is characterized in that it contains (A) a compound having a vertical alignment group and a functional group capable of thermal crosslinking. A polymer and (B) a crosslinking agent; the orientation material is obtained using the composition; and the phase difference material is obtained using the composition.

Description

technical field [0001] The present invention relates to a cured film-forming composition suitable for a vertical alignment material that orients liquid crystal molecules vertically. In particular, the present invention relates to improving viewing angle characteristics of a liquid crystal display (liquid crystal display; LCD), specifically for improving IPS liquid crystals filled with liquid crystals having positive dielectric anisotropy (Δε>0). Cured film-forming composition, orientation material, and retardation material useful for producing a +C plate (positive C plate) for viewing angle characteristics of a liquid crystal display of a display device (In-plane Switching LCD; in-plane orientation switching LCD). Background technique [0002] IPS-LCD is characterized in that since there is no vertical inclination of liquid crystal molecules, there is little brightness change / color change due to viewing angle; however, as disadvantages, it is difficult to improve contrast...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D201/00C09D133/14G02B5/30G02F1/13363G02F1/1337
CPCC08F120/58C09D133/066C09D133/24G02B5/3016G02F1/13363G02F1/133635G02F1/133742C08F220/1812C08F220/06C08F220/20
Inventor 大村浩之后藤耕平畑中真
Owner NISSAN CHEM CORP