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A metal-organic coordination compound with reversible dielectric properties, preparation method and application

A technology of coordination compounds and dielectric properties, applied in the field of synthesis of reversible dielectric materials, to achieve high yield, simple preparation process, and stable polarization mode

Active Publication Date: 2017-05-10
JIANGSU UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] In recent years, there have been more and more studies on proton-conducting materials, but it is still quite challenging to develop a "proton source" that is stable to temperature, humidity, and acid and alkali environments

Method used

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  • A metal-organic coordination compound with reversible dielectric properties, preparation method and application
  • A metal-organic coordination compound with reversible dielectric properties, preparation method and application
  • A metal-organic coordination compound with reversible dielectric properties, preparation method and application

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Embodiment 1

[0023] 5mmol ZnCl 2 and 5mmol 2-methylimidazole were mixed in 50mL water, and at room temperature, a kind of coordination compound (2MI)[Zn(2MI)Cl with reversible dielectric properties was obtained by self-assembly by solution method and slow evaporation of solvent. 3 ]

[0024] The coordination compound crystals obtained in Example 1 were characterized. Select a single crystal of appropriate size under a microscope, and use graphite monochromatized Mo Kα rays at room temperature The X-ray diffraction structure of the single crystal was determined on a Bruker Apex II CCD diffractometer, and the results are shown in Table 1. The SADABS method was used for semi-empirical absorption correction, the unit cell parameters were determined by the least squares method, the data reduction and structure analysis were completed using the SAINT and SHELXL program packages, and all non-hydrogen atoms were anisotropically refined by the full matrix least squares method. The minimum asymm...

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Abstract

The invention discloses a metal-organic coordination compound with a reversible dielectric property, a preparation method and application.The coordination compound (2MI)[Zn(2MI)Cl3] with the reversible dielectric property is prepared by self-assembling a transition metal ion Zn<2+> and 2-methylimidazole through a solution method.The coordination compound is simple in preparation method, good in repeatability and high in yield, the good reversible dielectric property is achieved, and by means of the reversible dielectric property of the metal-organic coordination compound, potential application prospects in the aspects of data communications, signal processing, sensing, phase shifters, variable capacitors and the like are achieved.

Description

technical field [0001] The invention belongs to the technical field of synthesis of reversible dielectric materials, and specifically relates to a metal-organic coordination compound with reversible dielectric properties, a preparation method and an application. Background technique [0002] Dielectric materials can be used to control / storage charge and electrical energy, and have an important strategic position in modern electronic and power systems. People's research on dielectric materials started from inorganic piezoelectric ceramic materials. Inorganic piezoelectric ceramic materials have high dielectric constant and high thermoelectric stability, but they are brittle and have high processing temperature. With the rapid development of the information and microelectronics industry, the application requirements for miniaturization, integration, intelligence, high frequency and planarization of semiconductor devices have increased. More and more electronic components, such...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C07F3/06
CPCC07F3/003
Inventor 陈立庄孙俊潘其建
Owner JIANGSU UNIV OF SCI & TECH