Antimicrobial moisturizing degradable porous gel preservative film and preparation method and application thereof

A fresh-keeping film and gel technology is applied in the field of antibacterial, moisturizing and degradable porous gel fresh-keeping film and its preparation field, which can solve the problems that chemical preservatives endanger human health, the fresh-keeping film is difficult, and endangers health, etc., and achieves good fresh-keeping effect. Highly effective antibacterial properties, the effect of slowing down the rate of decay

Active Publication Date: 2016-09-28
TIANJIN POLYTECHNIC UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] Traditional preservative film preparation methods are generally difficult and costly, and some chemical preservatives may even endanger human health
Some PVC cling film wraps a plate of raw or cooked food, and a large area of ​​the food will be close to the soft plastic cling film. The content of vinyl chloride monomer in the cling film is relati...

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] 1) Preparation of bentonite and zinc oxide dispersion: Weigh 0.2kg of bentonite and 10g of zinc oxide respectively, add them to 20L of deionized aqueous solution at 25°C, stir and disperse for 30 minutes until a uniform bentonite and zinc oxide dispersion is formed , and then mix the two dispersions together and continue to stir for 30 minutes;

[0033] 2) Dissolution of sodium acrylate and starch: Weigh 0.2kg sodium acrylate and 0.1kg starch respectively, add them into deionized water at 25°C, and disperse with magnetic stirring for 30min until a uniform and stable mixed solution is formed;

[0034] 3) Preparation of gel prepolymerization solution: pour the mixed solution containing sodium acrylate and starch prepared in step 2) into the mixed solution of bentonite and zinc oxide in step 1), stir for 30 minutes, add 10 g of supernatant under ice-water bath Ammonium sulfate and sodium bisulfite were stirred evenly for 10 minutes to obtain the pre-polymerization liquid o...

Embodiment 2

[0038] 1) Preparation of talc powder and silver oxide dispersion: Weigh 0.18kg talc powder and 12g zinc hydroxide respectively, add them into 18L deionized aqueous solution at 25°C, stir and disperse for 25min until uniform talc powder and Zinc hydroxide dispersion liquid, then two kinds of dispersion liquids are mixed together, continue to stir 30min;

[0039] 2) Dissolution of N-methylolacrylamide and polylactic acid: Weigh 0.18kg N-methylolacrylamide and 0.1kg polylactic acid respectively, add them to deionized water at 25°C, stir and disperse for 25min , until a uniform and stable mixed solution is formed;

[0040] 3) Preparation of gel prepolymer solution: pour the mixed solution containing N-methylolacrylamide and polylactic acid prepared in step 2) into the mixed solution of talcum powder and zinc hydroxide in step 1), and stir After 25 minutes, add 12 g of ammonium persulfate and tetramethylethylenediamine under ice-water bath, and stir evenly for 10 minutes to obtain...

Embodiment 3

[0044] 1) Preparation of graphene oxide and copper silicate dispersions: Weigh 0.25kg graphene oxide and 8g copper silicate respectively, add them to 22L deionized aqueous solution at 25°C, and mechanically stir and disperse for 40min until a uniform Graphene oxide and copper silicate dispersion liquid, then two kinds of dispersion liquids are mixed together, continue to stir 30min;

[0045] 2) Dissolution of dimethylaminoethyl methacrylate and polyvinyl alcohol: Weigh 0.22kg dimethylaminoethyl methacrylate and 0.1kg polyvinyl alcohol respectively, add them to deionized water successively at 30°C, and manually Stir and disperse for 40 minutes until a uniform and stable mixed solution is formed;

[0046] 3) Preparation of gel prepolymer solution: pour the mixed solution containing dimethylaminoethyl methacrylate and polyvinyl alcohol prepared in step 2) into the mixed solution of graphene oxide and copper silicate in step 1) , stirring for 40 minutes, adding 15 g of potassium ...

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PUM

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Abstract

The invention relates to an antimicrobial moisturizing degradable porous gel preservative film and a preparation method and application thereof. The gel preservative film is formed by polymerizing a carboxyl or amido contained functional monomer, an inorganic nano-powder, biodegradable natural polymer, calcium-ion-contained salt, an inorganic antimicrobial agent and a reductant-oxidant in a water solution. A gel three-dimensional network porous structure is used for spontaneously adjusting gas components inside the film, and the natural polymer is adopted, so that the antimicrobial moisturizing degradable porous gel preservative film has the advantages of being wide in source, biologically degradable, good in film forming property and the like; due to the high antimicrobial property of the inorganic antimicrobial agent, the defects that a traditional preservative film is high in pollution, short in storage period, high in cost, hard to recycle, complex in technology and the like are avoided, and the antimicrobial moisturizing degradable porous gel preservative film can partially replace cardboards, water absorption sponges, ice blocks or plastics and other preservative materials. The preparation method is easy and convenient to implement, capable of promoting large-scale production, long in preservation time, good in permeability, and capable of effectively slowing down the food rotting speed, thereby being applied to food, fruit, vegetable transportation, storage, delivery, assembling, disassembling, storage and preservation in the edible process.

Description

technical field [0001] The invention relates to the fields of food safety and preservation, polymer materials and environmental protection, in particular to an antibacterial, moisturizing and degradable porous gel preservation film, a preparation method and application thereof. Background technique [0002] With the improvement of people's living standards, food safety and food preservation issues are getting more and more attention. In the process of food production, the performance of packaging materials or supporting materials often has a great influence on the shelf life of food. Among the existing packaging films in our country, the vast majority are processed from polyethylene (PE), polypropylene (PP), polyvinyl chloride (PVC) and polyester. These products are of high quality, light in weight and easy to process. , low cost, but because it contains chemical substances such as phthalates and di(2-ethyl)hexyl adipate (DEHA) that may cause cancer, and cannot be degraded ...

Claims

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Application Information

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IPC IPC(8): C08J9/40C08J5/18C08J3/075C08F251/00C08F220/06C08K3/34C08K3/22C08F283/02C08F220/28C08K9/00C08K3/04C08F261/04C08F220/34C08K3/28C08F283/04C08F216/14
CPCC08F251/00C08F261/04C08F283/02C08F283/04C08J3/075C08J5/18C08J9/40C08J2351/00C08J2351/02C08J2351/08C08K3/04C08K3/22C08K3/28C08K3/34C08K3/346C08K9/00C08K2003/2241C08K2003/2296C08K2201/011C08F220/34C08F216/1475C08F220/281
Inventor 张青松高文军兴丽娟刘亚龙杨超超刘鹏飞陈莉
Owner TIANJIN POLYTECHNIC UNIV
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