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Novel compound modified asphalt and preparing method thereof

A composite modified asphalt, a new type of technology, used in building components, building insulation materials, buildings, etc., can solve the problem of lack of modification function, inability to synergize modification effect of waste rubber powder, weakening the modification effect of rubber powder on asphalt, etc. problems, to achieve the effect of improving storage stability, avoiding performance decay, and good strength performance

Active Publication Date: 2017-01-04
HENAN NORMAL UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the use of these additives tends to bring some negative effects at the same time. The introduction of organic solvents or coupling agents can easily play a plasticizing role, weakening the effect of rubber powder on asphalt modification, and these added additives, It does not have the modification function itself, and cannot play a synergistic modification effect with waste rubber powder

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] First heat 790g of molten matrix pitch, keep the temperature at 130°C, add 10g of sulfur-doped graphene and perform mechanical stirring for 2h, then raise the temperature to 160°C, then add 150g of 80-mesh waste rubber powder under stirring, and then cool down to 120°C Keep it for 1h to make it fully swell, continue to shear on a high-speed shear for 0.5h, the shearing temperature is 120°C, then raise the temperature to 160°C, after the temperature is stable, add 50g of 2-mercaptobenzene while stirring After the addition of thiazole and 2-mercaptobenzothiazole is completed, the insulation and stirring are continued for 0.5 h, and finally a new type of composite modified asphalt is obtained.

[0022] The road performance test method of composite modified asphalt is carried out according to the "Experimental Regulations for Asphalt and Asphalt Mixtures in Highway Engineering" JTGE20-2011, and the test results are shown in Table 1.

Embodiment 2

[0024] First heat 700g of molten matrix pitch, keep the temperature at 140°C, add 50g of sulfur-doped graphene and perform mechanical stirring for 4 hours, then raise the temperature to 170°C, then add 220g of 60-mesh waste rubber powder under stirring, and then cool down to 145°C Keep it for 3 hours to make it fully swell, continue to shear on a high-speed shear for 0.8 hours, the shear temperature is 145°C, and then raise the temperature to 170°C, after the temperature is stable, add 45g of 4,4'-di After the addition of dimorpholine sulfide and 4,4'-dimorpholine disulfide is completed, the heat preservation and stirring are continued for 0.6 h to finally obtain a new type of composite modified asphalt.

[0025] The road performance test method of composite modified asphalt is carried out according to the "Experimental Regulations for Asphalt and Asphalt Mixtures in Highway Engineering" JTGE20-2011, and the test results are shown in Table 1.

Embodiment 3

[0027] First heat 590g of molten base asphalt, keep the temperature at 150°C, add 100g of sulfur-doped graphene and carry out mechanical stirring for 6h, then raise the temperature to 180°C, then add 300g of 40-mesh waste rubber powder under stirring, and then cool down to 150°C Keep it for 4 hours to make it fully swell, continue to shear on a high-speed shear for 1 hour, the shearing temperature is 150°C, and then heat up to 180°C, after the temperature is stable, add 60g of diphenylguanidine and diphenylguanidine while stirring After the addition is complete, continue to keep warm and stir for 1 hour, and finally obtain a new type of composite modified asphalt.

[0028] The road performance test method of composite modified asphalt is carried out according to the "Experimental Regulations for Asphalt and Asphalt Mixtures in Highway Engineering" JTGE20-2011, and the test results are shown in Table 1.

[0029] Table 1 Performance test results of composite modified asphalt

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Abstract

The invention discloses a novel compound modified asphalt and a preparing method thereof, and belongs to the technical field of road building materials. The invention is characterized in that the novel compound modified asphalt is prepared from, by weight, 1%-10% of sulfur doped graphene, 1%-5% of accelerant, 15%-30% of waste rubber powder and the balance matrix asphalt. The invention also discloses the preparing method of the compound modified asphalt. By using sulfur doped graphene as the cross-linking agent and the modifying agent, on one hand, the degree of association between the constituent materials of the modified asphalt is improved with the sulfur atom in the molecular structure of the sulfur doped graphene playing the role of crosslinking, and on the other hand, through the good physical properties of the sulfur doped grapheme, the asphalt is modified and the structural performance of the graphene is given to the modified asphalt, at last, the compound modified asphalt with excellent performance is prepared.

Description

technical field [0001] The invention belongs to the technical field of road building materials, and in particular relates to a novel composite modified asphalt and a preparation method thereof. Background technique [0002] With the development of the automobile industry, a large number of tires are discarded. Processing waste tires into waste rubber powder and applying them to asphalt modification not only greatly improves the high and low temperature performance of asphalt, but also reduces the cost of paving and realizes resource utilization. recycling. In the process of modifying asphalt with waste rubber powder, there are currently some key technical problems. For example, waste rubber powder and asphalt mainly exist in the form of physical blending. Due to the lack of compatibility between rubber polymers and matrix asphalt, the modified The storage stability of asphalt is insufficient, which seriously affects the performance of modified asphalt. If a large amount of...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L95/00C08L19/00C08K9/02C08K3/04
CPCC08L95/00C08L2312/00C08L2555/50C08L2555/54C08L2555/80C08L19/003C08K9/02C08K3/04
Inventor 张庆房立白正宇李珊珊黄茹梦衡金梦蒋凯宋世理
Owner HENAN NORMAL UNIV