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Method for flocculating and removing blue algae through dual-polymer composition and application of dual-polymer composition

A dual polymer and polymer technology, applied in the field of environmental engineering, can solve the problems of easy operation by external conditions, short duration of action, long operation period, etc., and achieve the effects of easy subsequent separation, low price, and reduced processing costs.

Inactive Publication Date: 2017-02-01
TIANJIN ACADEMY OF ENVIRONMENTAL SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Common physical methods include mechanical salvage method, filtration method, aeration method, air flotation method, water replacement method, etc. Although these methods are effective and non-polluting, they have a large workload, long cycle, high cost of algae control, and can only cure the symptoms but not the root cause.
Chemical algae removal methods include chemical algae killing method, chemical coagulation and sedimentation method, etc. These methods have quick results and high efficiency, but the duration of action is short, and secondary pollution is easily generated
Common biological methods include microbial algae control method, plant algae suppression method, aquatic animal manipulation method, etc. Although these methods are not easy to produce secondary pollution, but the operation cycle is long, and the operation is easily affected by external conditions, making it difficult to control

Method used

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  • Method for flocculating and removing blue algae through dual-polymer composition and application of dual-polymer composition
  • Method for flocculating and removing blue algae through dual-polymer composition and application of dual-polymer composition
  • Method for flocculating and removing blue algae through dual-polymer composition and application of dual-polymer composition

Examples

Experimental program
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Effect test

Embodiment 1~6

[0025] Take 700-1000 mL of cyanobacteria water samples from the main stream of Haihe River, put them in a glass beaker, add polymer A with a final concentration of 2-10 mg / L, stir well, then add polymer B with a final concentration of 4-15 mg / L , control the pH between 5.0 and 7.0, stir at 300 rpm for 1 min, and let stand for 1 min. The concentration of cyanobacteria in water before and after flocculation was measured, and the removal rate of cyanobacteria of six kinds of dual polymer compositions with different components and ratios was calculated.

[0026] Determination of the concentration of cyanobacteria in water samples by counting method: add Luger reagent to cyanobacteria water samples, let it settle in the laboratory, siphon to concentrate to an appropriate ratio, take 0.1 mL dropwise onto a 20×20 mm glass slide, and in 10× The cyanobacteria were counted at 40 times the environment, and then the counting results were converted into the concentration of cyanobacteria i...

Embodiment 7

[0028] The comparison results of the double polymer flocculant composition and the traditional flocculant are shown in the table below:

[0029]

[0030] In comparison, the composition of the dual polymer flocculation composition is natural, non-toxic and harmless to the water ecological environment, and avoids secondary pollution; the algae removal rate and flocculation effect are better than traditional flocculants, the flocculation efficiency is higher, and the algae formed The coagulum is larger in size and stronger in cohesion, making it easier to separate later.

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Abstract

The invention discloses a method for flocculating and removing blue algae through a dual-polymer composition. The dual-polymer composition is prepared from a natural cationic polymer A and a natural anionic polymer B; the polymer A is a mixture formed by one or two of chitosan and chitin according to a mass ratio of (1 : 200) to (100 : 1); the polymer B is a mixture formed by one or two of xanthan gum and pullulan according to a mass ratio of (1 : 500) to (300 : 1). The method for flocculating and removing the algae through the dual-polymer composition is characterized by comprising the following steps: firstly adding the polymer A into blue algae water according to a final concentration ratio of 0.2mg / L to 10mg / L, uniformly mixing, then adding the polymer B into the blue algae water according to a final concentration ratio of 0.2mg / L to 30mg / L, the adding ratio range of the polymer A and the polymer B being (1 : 1) to (1 : 3), adjusting pH of the algae water to be 3-7, stirring for 0.5-5 minutes under 100-500 rpm, standing or stirring for 0.5-10 minutes at a low speed to form massive dense blue algae floccules, and removing the algae floccules via a filtering or fishing manner.

Description

technical field [0001] The invention belongs to the technical field of environmental engineering, and in particular relates to a method for flocculating and removing cyanobacteria in water by using a double polymer composition and an application thereof. Background technique [0002] Eutrophication is a phenomenon of water pollution caused by excessive plant nutrients such as nitrogen and phosphorus. One of the prominent problems it brings is the outbreak of blue-green algae. The outbreak of harmful cyanobacteria not only destroys the balance of the ecological composition of the water body, reduces the efficiency of water resource utilization, but also produces harmful microcystins and volatile odor metabolites in the process of growth and metabolism, and brings public safety and health risks. Great hidden danger. [0003] In recent years, scholars at home and abroad have developed a variety of cyanobacteria emergency treatment technologies, which can be divided into physic...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F1/52C02F1/56
CPCC02F1/5263C02F1/56C02F2103/007
Inventor 李艳英周滨李慧邵晓龙
Owner TIANJIN ACADEMY OF ENVIRONMENTAL SCI
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