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Preparation method and application of water hyacinth-magnesium oxide composite biochar

A technology of magnesium oxide and water hyacinth, applied in chemical instruments and methods, water pollutants, biofuels, etc., can solve the problems of low adsorption capacity, and achieve the effects of low cost of materials, increased yield, and realization of resource utilization value.

Inactive Publication Date: 2017-05-17
GUANGDONG UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In order to overcome the insufficiency and shortcoming of biochar existing in the prior art that the adsorption capacity of heavy metal pollution is low, the primary purpose of the present invention is to provide a kind of preparation method of water hyacinth-magnesia composite biochar

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] (1) Take freshly picked water hyacinth, wash it with clean water, dry it in an oven at 80°C for 16 hours, and pass it through a 0.1mm sieve after crushing to obtain fine water hyacinth powder; similarly, dry the magnesium oxide in an oven at 80°C for 16 hours, Pass through a 0.1mm sieve to obtain magnesium oxide fine powder; fully mix the water hyacinth fine powder and magnesium oxide fine powder according to the mass ratio of 19:1, so that the magnesium oxide content is 5% of the mixed material.

[0022] (2) with step (1) gained mixed homogeneous raw material, in logical N 2 Under anaerobic conditions, the temperature was raised to 500°C at a rate of 8°C / min, thermally cracked for 2 hours, and naturally cooled to room temperature to obtain water hyacinth-magnesia composite biochar A.

[0023] (3) Take 100mL of wastewater with Pb and Cd concentrations of 150 and 50mg / L respectively, adjust the pH value to 5.0, add 0.2g of the water hyacinth-magnesia composite biochar A,...

Embodiment 2

[0026] (1) Take freshly picked water hyacinth, wash it with clean water, dry it in an oven at 90°C for 10 hours, and pass it through a 0.3mm sieve after crushing to obtain fine water hyacinth powder; similarly, dry the magnesium oxide in an oven at 90°C for 10 hours, Pass through a 0.3mm sieve to obtain magnesium oxide fine powder; fully mix the water hyacinth fine powder and magnesium oxide fine powder according to the mass ratio of 9:1, so that the magnesium oxide content is 10% of the mixed material.

[0027] (2) with step (1) gained mixed homogeneous raw material, in logical N 2 Under anaerobic conditions, the temperature was raised to 400°C at a rate of 3°C / min, thermally cracked for 4 hours, and naturally cooled to room temperature to obtain water hyacinth-magnesia composite biochar B.

[0028] (3) Take 100mL of waste water with Pb and Cd concentrations of 150 and 50mg / L respectively, adjust the pH value to 7.0, add 0.2g of the water hyacinth-magnesia composite biochar B...

Embodiment 3

[0031] (1) Take freshly picked water hyacinth, wash it with water, dry it in an oven at 90°C for 12 hours, and pass it through a 0.1mm sieve after crushing to obtain fine water hyacinth powder; similarly, dry the magnesium oxide in an oven at 90°C for 12 hours, Pass through a 0.1mm sieve to obtain magnesium oxide fine powder; fully mix water hyacinth fine powder and magnesium oxide fine powder according to the mass ratio of 4:1, so that the content of magnesium oxide is 20% of the mixed material.

[0032] (2) with step (1) gained mixed homogeneous raw material, in logical N 2 Under anaerobic conditions, the temperature was raised to 500°C at a rate of 5°C / min, thermally cracked for 3 hours, and cooled to room temperature naturally to obtain water hyacinth-magnesia composite biochar C.

[0033] (3) Take 100mL of waste water with Pb and Cd concentrations of 200 and 50mg / L respectively, adjust the pH value to 6.0, add 0.2g of the water hyacinth-magnesia composite biochar C, and o...

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Abstract

The invention belongs to the technical field of solid waste resource utilization and the field of heavy metal pollution water treatment, and discloses a water hyacinth-magnesium oxide composite biochar and a preparation method and application thereof. The preparation method comprises the following steps: taking magnesium oxide and water hyacinth and drying for 10 to 16 hours at a temperature of 80 to 90 DEG C, grinding and then passing through a 0.1-0.3mm sieve, and fully and evenly mixing so that the content of magnesium oxide is 5 to 20%; heating the mixed material to 400 to 500 DEG C at a rate of 3 to 8 DEG C / min under N2 anaerobic condition, maintaining the temperature, thermally cracking for 2 to 4h, and naturally cooling to a room temperature to obtain the water hyacinth-magnesium oxide composite biochar. The pH value of heavy metal wastewater is adjusted to 5.0 to 7.0, and the water hyacinth-magnesium oxide composite biochar is added according to the dosage of 1 to 5g / L, and the shock adsorption is carried out at a rotational speed of 100 to 200r / min for 20 to 24h. The removal rates of Pb and Cd are more than 99.5%.

Description

technical field [0001] The invention belongs to the technical field of utilization of solid waste resources and the field of treatment of heavy metal polluted water bodies, in particular to a preparation method and application of water hyacinth-magnesia composite biochar. Background technique [0002] The results of the first national survey on pollution sources show that in 2007, the discharge of five heavy metals including lead, cadmium, mercury, chromium and arsenic in national wastewater reached 897.3 tons. Heavy metals entering the environment cannot be degraded by microorganisms, and easily pass through soil, water, air, especially the food chain, posing a serious threat to the ecological environment and public health. Heavy metal pollution in water has become one of the major environmental problems today, and how to effectively treat heavy metal wastewater has become an environmental problem that needs to be solved urgently. [0003] The treatment methods of heavy me...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10B53/02C10B57/06B01J20/20B01J20/30C02F1/28C02F101/20C02F101/22
CPCB01J20/041B01J20/20C02F1/28C02F1/281C02F1/283C02F2101/20C02F2101/22C10B53/02C10B57/06Y02E50/10
Inventor 林亲铁项江欣陈志良莫海文郭见龙
Owner GUANGDONG UNIV OF TECH