Upconversion crystal nano-material for infrared ray excited red-green-blue three-color orthogonal fluorescence transmission and preparation method thereof

A technology of nano-crystals and fluorescence emission, applied in the field of nano-fluorescent materials, can solve the problems of limited material size, limited resolution, local unevenness, etc., and achieve the effect of improving resolution and broad application prospects

Active Publication Date: 2017-10-24
FUDAN UNIV
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Problems solved by technology

However, this method has many limitations so far. On the one hand, in order to solve many problems in the mixing of rare earth elements, a large number of thin layers are doped and bonded layer by layer with optical adhesives. The material manufacturing is very complicated and the size of the material is limited.
At the same time, it shows that the red, green and blue voxels in the body are separated from each other, and the local unevenness is controlled by the thickness of the thin layer. The resolution of the focus is limited by the scale of

Method used

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  • Upconversion crystal nano-material for infrared ray excited red-green-blue three-color orthogonal fluorescence transmission and preparation method thereof
  • Upconversion crystal nano-material for infrared ray excited red-green-blue three-color orthogonal fluorescence transmission and preparation method thereof
  • Upconversion crystal nano-material for infrared ray excited red-green-blue three-color orthogonal fluorescence transmission and preparation method thereof

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Embodiment Construction

[0025] (1) Preparation of rare earth precursors for shell growth.

[0026] Preparation of Y-OA (0.1 M) precursor: add 5 mmol YCl sequentially to a 250 mL three-neck flask 3 , 20 mL oleic acid (OA), 30 mL octadecene (ODE). Under the conditions of vacuum and magnetic stirring, the reaction was heated to 140 degrees Celsius for 1 hour to remove crystal water and low-boiling solvent molecules, and a clear and transparent oleic acid complex Y-OA (0.1 M) precursor was obtained.

[0027] Preparation of Gd, Yb, Er-OA (0.1M) precursor: The preparation of Gd, Yb, Er-OA (0.1M) precursor is similar to the preparation method of the above-mentioned Y-OA (0.1 M) precursor. 5 mmol YCl in 3 , replaced by 3.9 mmol GdCl 3 , 1 mmol YbCl 3 , 0.1 mmol ErCl 3 , the synthesis method is the same.

[0028] Preparation of Gd, Yb-OA (0.1M) precursor: The preparation of Gd, Yb-OA (0.1M) precursor is similar to the preparation method of Y-OA (0.1 M) precursor mentioned above. YCl 3 , replaced by 4....

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Abstract

The invention belongs to the technical field of fluorescence nano-materials, and particularly relates to an upconversion crystal nano-material for infrared ray excited red-green-blue three-color orthogonal fluorescence transmission and a preparation method thereof. The nano-material comprises five types of shells, including an upconversion luminous center core, two upconversion luminous shells, an inert isolation layer, an energy transfer layer and an energy absorption layer, wherein the upconversion luminous center core and the energy absorption layers are used for absorbing exciting lights having specific wavelengths; the energy transfer layer is used for transferring energy between the energy absorption layer and a visible light luminous layer; the inert isolation layer is used for isolating each luminous center through an inert material inhibiting energy transfer, so that the fluorescence process of the luminous centers are not impacted one another; and the thickness of each energy absorption layer is adjusted to filter infrared exciting light strengths, so that each energy absorption layer can be used for absorbing energy of infrared exciting lights having different wavelengths respectively, and the energy can be finally transferred to corresponding unused luminous centers. The upconversion crystal nano-material realizes independent fluorescence transmission of red-green-blue three-primary colors, and can be used in the field of volumetric three-dimensional colorful display.

Description

technical field [0001] The invention belongs to the technical field of nano fluorescent materials, and in particular relates to an up-conversion nano crystal material for independent orthogonal fluorescent emission of red, green and blue in the visible light band and a preparation method thereof. Background technique [0002] In the modern information society, the importance of visual information transmission and performance is gradually increasing. Among them, the three-dimensional color display can instantly display the dynamic information of all angles, and is not affected by the viewing angle compared with the plane display. Three-dimensional display technology has broad application prospects in optical information, medical treatment, national defense and other fields. At present, the common virtual three-dimensional display is mainly through the parallax of the human eyes, and the pseudo three-dimensional display is generated by receiving the image difference between t...

Claims

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Application Information

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IPC IPC(8): C09K11/02C09K11/85B82Y20/00B82Y30/00B82Y40/00
CPCB82Y20/00B82Y30/00B82Y40/00C09K11/02C09K11/7773
Inventor 张凡刘玄
Owner FUDAN UNIV
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