Upconversion crystal nano-material for infrared ray excited red-green-blue three-color orthogonal fluorescence transmission and preparation method thereof
A technology of nano-crystals and fluorescence emission, applied in the field of nano-fluorescent materials, can solve the problems of limited material size, limited resolution, local unevenness, etc., and achieve the effect of improving resolution and broad application prospects
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[0025] (1) Preparation of rare earth precursors for shell growth.
[0026] Preparation of Y-OA (0.1 M) precursor: add 5 mmol YCl sequentially to a 250 mL three-neck flask 3 , 20 mL oleic acid (OA), 30 mL octadecene (ODE). Under the conditions of vacuum and magnetic stirring, the reaction was heated to 140 degrees Celsius for 1 hour to remove crystal water and low-boiling solvent molecules, and a clear and transparent oleic acid complex Y-OA (0.1 M) precursor was obtained.
[0027] Preparation of Gd, Yb, Er-OA (0.1M) precursor: The preparation of Gd, Yb, Er-OA (0.1M) precursor is similar to the preparation method of the above-mentioned Y-OA (0.1 M) precursor. 5 mmol YCl in 3 , replaced by 3.9 mmol GdCl 3 , 1 mmol YbCl 3 , 0.1 mmol ErCl 3 , the synthesis method is the same.
[0028] Preparation of Gd, Yb-OA (0.1M) precursor: The preparation of Gd, Yb-OA (0.1M) precursor is similar to the preparation method of Y-OA (0.1 M) precursor mentioned above. YCl 3 , replaced by 4....
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