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A kind of preparation method of reinforced silicon carbide-alumina composite foam ceramics

A composite foam and silicon carbide technology, which is applied to ceramic products, other household appliances, household appliances, etc., can solve the problems of high sintering temperature and poor toughness of structural ceramics, achieve good economic and environmental benefits, reduce sintering temperature, and reduce costs. not high effect

Active Publication Date: 2021-01-01
NORTHEASTERN UNIV LIAONING
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The invention aims to solve the defects of high sintering temperature and poor toughness of structural ceramics, and provides a preparation method for in-situ formation of ceramic crystallite reinforced silicon carbide-alumina composite foam ceramics by introducing low-melting point oxides

Method used

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  • A kind of preparation method of reinforced silicon carbide-alumina composite foam ceramics

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] (1) The mass fraction is 60% industrial silicon carbide powder, 30% fused corundum powder, 5% kaolin, and 2% V 2 o 5 , use deionized water as the ball milling medium and mix well. After mixing, add appropriate amount of deionized water, in the planetary ball mill, at 300r·min -1 Ball milled for 6 hours to make a ceramic slurry with a solid phase mass fraction of 60% for later use. In addition, the slurry rheology agent sodium carboxymethyl cellulose, as well as the antifoaming agent tributyl phosphate and dispersing agent sodium polyacrylate are added in an amount of 1% by mass fraction;

[0025] (2) Make the polyurethane porous sponge into the size of diameter (25±1mm) and height (11±1mm), put it into NaOH solution (6.0mol·L -1 ) at 60°C for 10 hours, rinsed with deionized water and dried in air;

[0026] (3) immerse the polyurethane porous sponge after the hydrolysis treatment in the ceramic slurry and start slurrying, and the slurry is evenly attached to the surf...

Embodiment 2

[0031] (1) The mass fraction is 50% industrial silicon carbide powder, 35% fused corundum powder, 8% kaolin, and 4% Na 2O, use deionized water as the ball milling medium and mix well. After mixing, add appropriate amount of deionized water, in the planetary ball mill, at 300r·min -1 Ball milled for 6 hours to make a ceramic slurry with a solid phase mass fraction of 60% for later use. In addition, the slurry rheology agent sodium carboxymethyl cellulose, as well as the antifoaming agent tributyl phosphate and dispersing agent sodium polyacrylate are added in an amount of 1% by mass fraction;

[0032] (2) Make the polyurethane porous sponge into the size of diameter (25±1mm) and height (11±1mm), put it into NaOH solution (6.0mol·L -1 ) at 60°C for 10 hours, rinsed with deionized water and dried in air;

[0033] (3) immerse the polyurethane porous sponge after the hydrolysis treatment in the ceramic slurry and start slurrying, and the slurry is evenly attached to the surface ...

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Abstract

The invention discloses a method for preparing an enhanced silicon carbide-aluminum oxide composite foamed ceramic, and belongs to the field of porous materials and ceramic materials. The method is characterized by comprising the following steps: mixing silicon carbide, aluminum oxide, kaolin and the like according to a preset ratio, and performing ball-milling with a deionized ball-milling medium so as to obtain ceramic slurry; performing hydrolysis treatment on organic foamed sponge in an NaOH solution, and starting slurry coating after treatment is completed; after slurry coating is completed, drying at room temperature and constant temperature so as to obtain a ceramic biscuit; and finally sintering the ceramic biscuit in a high-temperature furnace, thereby obtaining the silicon carbide-aluminum oxide composite foamed ceramic. By adopting the silicon carbide-aluminum oxide composite foamed ceramic prepared by using the method, problems that a conventional foamed ceramic is high in sintering temperature, high in porosity, low in strength and the like are overcome, in addition the method has the advantages of being simple in process, low in energy consumption, good in environment friendliness, low in cost and the like, and industrial production can be easily achieved.

Description

technical field [0001] The invention belongs to the technical field of preparation of foam ceramic materials, and relates to a method for preparing reinforced silicon carbide-alumina composite foam ceramics, in particular to a method for introducing low-melting point oxides to form ceramic crystallite-reinforced silicon carbide-alumina composite foam ceramics in situ method of preparation. Background technique [0002] Foamed ceramics have excellent properties such as high specific surface area, strong adsorption and low electrical conductivity due to the existence of a special three-dimensional pore structure. Therefore, foamed ceramics are often used as sound insulation, filtration, adsorption and biological materials. Secondly, ceramic foam also has some unique properties of ceramic materials, such as good corrosion resistance, high temperature resistance, thermal shock resistance and structural stability. With the rapid development of science and technology, all walks ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B38/06C04B35/56C04B35/622C04B35/64
CPCC04B35/5611C04B35/622C04B35/64C04B38/067C04B2235/3201C04B2235/3217C04B2235/3239C04B2235/349C04B2235/6562C04B2235/6567C04B2235/77C04B2235/96C04B2235/9607C04B38/0067
Inventor 马北越任鑫明张亚然李世明于景坤
Owner NORTHEASTERN UNIV LIAONING