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A kind of melamine resin, preparation method and melamine foaming liquid

A technology of melamine and foaming liquid, applied in the field of preparation, melamine resin and melamine foamed plastic foaming liquid, can solve the problems of slow release of formaldehyde, limitation, insufficient application, etc., and achieve the effect of saving resources

Active Publication Date: 2019-08-30
CHENGDU ORGANIC CHEM CO LTD CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] But the melamine foamed plastics in the prior art is all at 4~12kg / m because of its density 3 (density > 12kg / m 3 The foams are all prepared by secondary processing such as hot pressing), the residual free formaldehyde is at least 10ppm (10mg / l), and the rationality of the molecular structure design in the melamine foam production process is insufficient, so that some ether bonds in the melamine foam etc. may degrade under long-term environmental factors or heating conditions, and slowly release formaldehyde, resulting in serious shortage or even restricted

Method used

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  • A kind of melamine resin, preparation method and melamine foaming liquid
  • A kind of melamine resin, preparation method and melamine foaming liquid
  • A kind of melamine resin, preparation method and melamine foaming liquid

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0050] Synthesis of Melamine Resin Ⅱ

[0051] Raw material ratio:

[0052]

[0053] 0.5 parts by weight of imidazolone alkoxy polyacrylate (functional compound)

[0054] React at 85-90°C. According to the density and mechanical properties of the prepared foam plastics, control the viscosity to 5000-40000mpa.s, terminate the reaction, and cool the resin storage tank for use.

Embodiment 2

[0056] Synthesis of Melamine Resin

[0057] Raw material ratio:

[0058]

[0059]

[0060] React at 85-90°C. According to the density and mechanical properties of the prepared foam plastics, control the viscosity to 5000-40000mpa.s, terminate the reaction, and cool the resin storage tank for use.

Embodiment 3

[0062] Synthesis of Melamine Resin

[0063] Raw material ratio:

[0064]

[0065] React at 85-90°C. According to the density and mechanical properties of the prepared foam plastics, control the viscosity to 5000-40000mpa.s, terminate the reaction, and cool the resin storage tank for use.

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Abstract

The invention discloses a melamine resin, a preparation method and a melamine foaming liquid. The resin is polymerized from raw materials including the following components: 100 parts by weight of melamine; 30-120 parts by weight of formaldehyde; 2-50 parts by weight of modified monomer; 0.5-5 parts by weight of functional compound; 1-3 parts by weight of catalyst . The melamine foaming solution comprises: 100 parts by weight of melamine resin; 1-10 parts by weight of surfactant; 1-15 parts by weight of foaming agent; 0-8 parts by weight of foam stabilizer; The present invention can make the density of foamed plastics in the range of 6-60kg / m 3 Controllable adjustment; the functional compound, especially the functional compound synthesized by the present invention can efficiently reduce the formaldehyde emission of the foamed plastics, making the formaldehyde emission of the foamed plastics <0.2mg / l (0.2ppm).

Description

technical field [0001] The invention relates to the field of melamine foamed plastics, and furthermore, relates to a melamine resin, a preparation method, and a melamine foamed plastic foaming liquid containing the melamine resin. Background technique [0002] Melamine foam is an intrinsically high flame-retardant foam material, because of its excellent sound absorption, noise reduction, heat insulation, high temperature resistance, low smoke rate, chemical corrosion resistance, convenient post-processing, etc. Its performance makes it widely used in more and more fields such as architectural decoration, public places, electromechanical equipment, and transportation vehicles. [0003] At present, the commonly used foam materials (such as polyurethane, polystyrene, etc.) not only have poor flame retardancy, but also produce a lot of smoke and toxic gases in a fire. According to statistics, more than 80% of fire deaths are related to inhalation of toxic fumes. Melamine foam ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08G12/32C08G12/40C08L61/32C08L83/12C08L71/02C08K5/42C08K5/09C08K3/32C08J9/14
Inventor 刘绍英王公应李子健
Owner CHENGDU ORGANIC CHEM CO LTD CHINESE ACAD OF SCI