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Insensitive primary explosive prepared by using electrostatic spraying process and preparation method thereof

A detonating and insensitivity technology, applied in explosives, offensive equipment, explosives processing equipment, etc., can solve the problem of not completely independent detonating explosives, etc., and achieve the effects of low static electricity and friction sensitivity, simple operation and uniform particles

Inactive Publication Date: 2018-04-20
NANJING UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This new type of explosive device uses less sensitive materials than previous ones but it's also lighter weight and easier for users to handle because they don’t have any harmful metals or other substances inside them that could be dangerous if used improperly. It can produce consistency from fine powders even at very small sizes without adding too much material into their structure.

Problems solved by technology

This patents discusses different ways to make certain chemical compounds called “nano” thermal agents safer and less expensive compared to existing ones like nitroglycerine and pentaerythritosanilane. However, there have been concerns about their potential health hazards due to residual amounts of metals contained within them. Therefore, some companies now focus on developing new sources of secondary explosives without relying heavily upon traditional raw ingredients.

Method used

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  • Insensitive primary explosive prepared by using electrostatic spraying process and preparation method thereof
  • Insensitive primary explosive prepared by using electrostatic spraying process and preparation method thereof
  • Insensitive primary explosive prepared by using electrostatic spraying process and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] Weigh 1.8mg and dissolve in 2ml of isopropanol, disperse 0.25g of copper sulfate pentahydrate and 0.108g of nano-aluminum powder in the nitrocellulose solution, and ultrasonically form a precursor solution. Add the precursor solution into the syringe of the electrostatic spray device, collect it with aluminum foil and dry it, its appearance is as follows figure 1 shown. The sample is placed in a closed explosive device and ignited to obtain a P-t curve such as figure 2 .

Embodiment 2

[0024] Weigh 2.0 mg and dissolve in 2 ml of isopropanol, disperse 0.25 g of copper sulfate pentahydrate and 0.135 g of nano-aluminum powder in the nitrocellulose solution, and ultrasonically form a precursor solution. Add the precursor solution into the syringe of the electrostatic spray device, collect it with aluminum foil and dry it. The sample is placed in a closed explosive device and ignited to obtain a P-t curve such as figure 2 .

Embodiment 3

[0026] Weigh 2.1 mg and dissolve in 2 ml of isopropanol, disperse 0.25 g of copper sulfate pentahydrate and 0.162 g of nano-aluminum powder in the nitrocellulose solution, and ultrasonically form a precursor solution. Add the precursor solution into the syringe of the electrostatic spray device, collect it with aluminum foil and dry it. The sample is placed in a closed explosive device and ignited to obtain a P-t curve such as figure 2 .

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Abstract

The invention discloses an insensitive primary explosive prepared by using an electrostatic spraying process and a preparation method thereof. The insensitive primary explosive is composed of 100 parts by weight of a nanometer thermite and 0.5 part by weight of nitrocellulose, wherein the nanometer thermite is composed of 54 to 57% by weight of copper sulfate pentahydrate and 43 to 46% by weight of nanometer aluminum powder. The preparation method comprises a step of, with copper sulphate pentahydrate as an oxidizing agent and nanometer aluminum powder as a reducing agent, preparing a coatingstructure at a microstructure level by using the electrostatic spraying process, wherein the coating structure uses sulfate as a core and the nanometer aluminum powder as a shell, and the unique microstructure enables the insensitive primary explosive to have higher heat release and higher peak pressure. The insensitive primary explosive of the invention has the advantages of high safety, no heavymetal ions and the like compared with traditional primary explosives, and overcomes safety problems in conventional primary explosives for detonators; and the electrostatic-spraying preparation method is simple in process and does not produce wastewater during production.

Description

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Claims

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Application Information

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Owner NANJING UNIV OF SCI & TECH
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