Halogen-containing alumina shaped body and catalyst, preparation method and application, and hydrogenation treatment method

Abstract

The invention discloses a halogen-containing alumina molded body and a preparation method and application thereof. The preparation method comprises optionally drying a molded body of a hydrated alumina composition containing hydrated alumina, a compound containing at least two proton acceptor sites and a halogen-containing compound and having the phi value of 5 or less shown in the description, and roasting the molded body in an oxygen-containing atmosphere in the presence of vapor. The invention also discloses a catalyst using the alumina molded body as a carrier and having hydrogenation catalysis effects, a preparation method thereof and a hydrogenation treatment method. The high strength molded body is prepared from hydrated alumina wet gel as a starting raw material so that the hydrated alumina wet gel drying process is avoided. The overall processes are reduced, overall operation energy consumption is reduced, the dust pollution is avoided and the working environment is greatly improved. The catalyst using the alumina molded body as a carrier has high catalytic activity in the hydrotreatment on hydrocarbon oil.

Description

Technical field [0001] The present invention relates to the technical field of alumina molding. Specifically, the present invention relates to a halogen-containing alumina molded body and a preparation method and application thereof. The present invention also relates to a catalyst and a catalyst using the halogen-containing alumina molded body as a carrier. For its preparation method, the present invention further relates to a hydrotreating method using the catalyst. Background technique [0002] In traditional methods, alumina shaped bodies, especially γ-alumina shaped bodies, are often used as adsorbents or supported catalysts because of their better pore structure, suitable specific surface area and higher heat resistance. Carrier use. This kind of alumina is usually obtained from dried hydrated alumina, such as pseudo-boehmite, which is formed, dried, and calcined at high temperature. [0003] Based on the above understanding, such as figure 1 As shown, the prepared hydrated...

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Problems solved by technology

[0014] (1) Pseudo-boehmite that has not been completely dried has strong viscosity, is difficult to transfer, and easily causes secondary dust pollution;

[0015] (2) Drying starts from the surface. The drying of the wet solid product separated from the mixture obtained from the gelling reaction is incomplete drying, so there is a sandwich biscuit phenomenon, that is, the surface of part of the pseudo-boehmite is dried (that is, the dried surface is substantially free of free water), while the interior is still wet (that is, for the non-dried interior, the content of free water is basically maintained at the level before drying), since the surface is dried, Therefore, hard particles are formed. When peptizing agent and / or binder are added to this incompletely dried pseudo-boehmite and kneaded, the hard particles formed during the drying process are in the process of extrusion. It is easy to cause blockage and affect production efficiency;

[0016] (3) It is difficult to stably control the dry base of pseudo-boehmite. The instability of the dry base will cause great interference to the molding process, making the molding process very unstable, resulting in an increase in the amount of unqualified products and low production efficiency;

[0017] (4) CN103769118A adopts a conventional molding process when molding, yet because the dry basis (35%-50%) of the pseudo-boehmite it adopts is far lower than the conventional dry basis content (about 70%), that is The water content is high, and there is basically no extrusion pressure during the extrusion molding process. Therefore, the carrier obtained after the extrudate is dried and roasted has basically no mechanical strength. As long as a little external force is applied, it will be pulverized, which is not suitable for industrial applications. possibility, which is the biggest problem facing the technology

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