A kind of polyester wool-like different shrinkage composite yarn and its preparation method
A technology of different shrinkage and composite yarn, which is applied in the direction of single-component polyester rayon, rayon manufacturing, melt spinning, etc., to achieve the effect of excellent performance
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Embodiment 1
[0083] A preparation method of polyester wool-like different shrinkage composite yarn, the specific steps are as follows:
[0084] (1) spinning melt preparation;
[0085] (1.1) Preparation of modified polyester:
[0086] (a) Esterification reaction: terephthalic acid, ethylene glycol and 2-ethyl-2-methyl-1,3-propanediol in a molar ratio of 1:1.2:0.03 are made into a slurry, and antimony trioxide is added , titanium dioxide and triphenyl phosphate are mixed evenly, and the esterification reaction is carried out under pressure in a nitrogen atmosphere. The pressurized pressure is normal pressure, and the temperature of the esterification reaction is 250°C. 90% of the value is the end point of the esterification reaction, wherein the addition of antimony trioxide is 0.01% of the weight of terephthalic acid, the addition of titanium dioxide is 0.20% of the weight of terephthalic acid, and the addition of triphenyl phosphate It is 0.05% of the weight of terephthalic acid, wherein...
Embodiment 2
[0096] A preparation method of polyester wool-like different shrinkage composite yarn, the specific steps are as follows:
[0097] (1) spinning melt preparation;
[0098] (1.1) Preparation of modified polyester:
[0099] (a) Esterification reaction; prepare terephthalic acid, ethylene glycol and 2,2-diethyl-1,3-propanediol in a molar ratio of 1:1.3:0.04 into a slurry, add ethylene glycol antimony, titanium dioxide After mixing evenly with trimethyl phosphate, carry out the esterification reaction under pressure in a nitrogen atmosphere. The pressurized pressure is normal pressure, and the temperature of the esterification reaction is 260°C. 91% is the end point of the esterification reaction, wherein the addition of ethylene glycol antimony is 0.02% of the weight of terephthalic acid, the addition of titanium dioxide is 0.21% of the weight of terephthalic acid, and the addition of trimethyl phosphate is 0.02% of the weight of terephthalic acid. 0.03% by weight of phthalic ac...
Embodiment 3
[0109] A preparation method of polyester wool-like different shrinkage composite yarn, the specific steps are as follows:
[0110] (1) spinning melt preparation;
[0111] (1.1) Preparation of modified polyester:
[0112] (a) Esterification reaction: terephthalic acid, ethylene glycol, and 2-butyl-2-ethyl-1,3-propanediol in a molar ratio of 1:1.4:0.05 are made into a slurry, and antimony acetate and titanium dioxide are added After mixing evenly with trimethyl phosphite, carry out esterification reaction under pressure in a nitrogen atmosphere. 92% is the end point of the esterification reaction, wherein the addition of antimony acetate is 0.03% of the weight of terephthalic acid, the addition of titanium dioxide is 0.23% of the weight of terephthalic acid, and the addition of trimethyl phosphite is 0.03% of the weight of terephthalic acid. 0.01% by weight of phthalic acid, wherein the structural formula of 2-butyl-2-ethyl-1,3-propanediol is as follows:
[0113]
[0114] ...
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