A kind of polyester imitation cotton type differential shrinkage composite yarn and preparation method thereof
A technology of iso-shrinkage and composite yarn, applied in the direction of single-component polyester rayon, rayon manufacturing, filament/thread forming, etc., to achieve the effect of excellent performance
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Embodiment 1
[0084] A method for preparing polyester cotton-like heterogeneous shrinkage composite yarn, the specific steps are as follows:
[0085] (1) Spinning melt preparation;
[0086] (1.1) Preparation of modified polyester:
[0087] (a) Esterification reaction; mix terephthalic acid, ethylene glycol and 2-ethyl-2-methyl-1,3-propanediol with a molar ratio of 1:1.2:0.03 into a slurry, and add antimony trioxide , Titanium dioxide and triphenyl phosphate are mixed uniformly, pressurized in a nitrogen atmosphere to carry out the esterification reaction, the pressure is normal pressure, the temperature of the esterification reaction is 250 ℃, when the amount of water distilled in the esterification reaction reaches the theoretical 90% of the value is the end point of the esterification reaction, where the addition of antimony trioxide is 0.01% by weight of terephthalic acid, the addition of titanium dioxide is 0.20% by weight of terephthalic acid, and the addition of triphenyl phosphate It is 0...
Embodiment 2
[0097] A method for preparing polyester cotton-like heterogeneous shrinkage composite yarn, the specific steps are as follows:
[0098] (1) Spinning melt preparation;
[0099] (1.1) Preparation of modified polyester:
[0100] (a) Esterification reaction; mix terephthalic acid, ethylene glycol and 2,2-diethyl-1,3-propanediol with a molar ratio of 1:1.3:0.04 into a slurry, and add ethylene glycol antimony and titanium dioxide After mixing with trimethyl phosphate uniformly, the esterification reaction is carried out under pressure in a nitrogen atmosphere. The pressure is normal pressure, and the temperature of the esterification reaction is 260℃. When the amount of water distilled in the esterification reaction reaches the theoretical value 91% is the end point of the esterification reaction, where the addition of ethylene glycol antimony is 0.02% by weight of terephthalic acid, the addition of titanium dioxide is 0.21% by weight of terephthalic acid, and the addition of trimethyl ph...
Embodiment 3
[0110] A method for preparing polyester cotton-like heterogeneous shrinkage composite yarn, the specific steps are as follows:
[0111] (1) Spinning melt preparation;
[0112] (1.1) Preparation of modified polyester:
[0113] (a) Esterification reaction; mix terephthalic acid, ethylene glycol and 2-butyl-2-ethyl-1,3-propanediol with a molar ratio of 1:1.4:0.05 into a slurry, and add antimony acetate and titanium dioxide After mixing with trimethyl phosphite uniformly, the esterification reaction is carried out under pressure in a nitrogen atmosphere. The pressure is 0.1MPa and the temperature of the esterification reaction is 252°C. When the amount of water distilled in the esterification reaction reaches the theoretical value 92% is the end point of the esterification reaction. The addition of antimony acetate is 0.03% by weight of terephthalic acid, the addition of titanium dioxide is 0.23% by weight of terephthalic acid, and the addition of trimethyl phosphite is for 0.01% by we...
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