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A kind of universal black masterbatch and preparation method thereof

A black masterbatch, a general-purpose technology, applied in the field of general-purpose black masterbatch and its preparation, can solve the problems of low carrier resin content, heavy odor, high production cost, reduce crushing shear friction, and simple preparation process , good dispersion effect

Active Publication Date: 2020-04-21
江苏永彩新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Because of the use of low molecular wax, on the one hand, it is easy to precipitate during processing and products, which directly affects the performance of plastic products. On the other hand, the price of low molecular wax is relatively high, which increases the manufacturing cost of masterbatch
Therefore, there are many shortcomings in the universal black masterbatch made in this way: the predictability of the coloring effect is poor, the strength of the plastic product is affected, the product is easily deformed and twisted, and it is more obvious for engineering plastics; moreover, due to the high price of polyethylene wax, production The cost is high. If you want to reduce the cost, you must use low-cost recycled materials such as polyethylene wax. In the post-processing process, the smell is heavy, and it also affects the performance of plastic products.
The content of carrier resin in the patented black masterbatch is very low, while the content of inorganic particles is quite high, especially the high content of carbon black is seriously agglomerated during processing, which has a very adverse effect on the performance of modified plastics
Therefore, the "universality" of universal color masterbatches is greatly limited

Method used

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  • A kind of universal black masterbatch and preparation method thereof
  • A kind of universal black masterbatch and preparation method thereof
  • A kind of universal black masterbatch and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] 46.0g of carbon black (average primary particle size of 21nm, oil absorption value of 55mL / 100g), 50.0g of linear low density polyethylene powder (melt index of 50g / 10min, recorded as MI50), 2.0g of vinyl Bis stearamide (EBS) and 2.0g of zinc stearate were added to a heating kneader, and mixed for 40 minutes at a heating temperature of 130°C and a rotating speed of 30r / min, and then entered into a double kneader with an aspect ratio of 48:1. Screw extruder, extrusion temperature: 150°C, 160°C, 170°C, 180°C, 190°C, head temperature 180°C, host speed 260r / min, cooled, dried, pelletized and packaged after extrusion Odorless black masterbatch.

[0040] The obtained black masterbatch is added into the polyamide, the amount of the black masterbatch is 3% of the weight of the polyamide, mixed and then extruded to obtain the black polyamide.

[0041] According to ISO527, ISO180, ISO178 standards, the test results show that compared with the original polyamide, the tensile stre...

Embodiment 2

[0043] 40.0g of carbon black (average primary particle size is 21nm, oil absorption value is 55mL / 100g), 56.0g of linear low density polyethylene powder (MI50), 1.0g of EBS and 3.0g of zinc stearate are added to heat Type kneader, at a heating temperature of 130°C and a speed of 40r / min, mix for 30 minutes, and then enter a twin-screw extruder with a length-to-diameter ratio of 48:1, extrusion temperature: 150°C, 160°C, 170°C , 180°C, 190°C, head temperature 180°C, host speed 260r / min, after extrusion, cooling, drying, pelletizing, and packaging into odorless black masterbatch.

[0044] Add the obtained black masterbatch into ABS, the consumption of black masterbatch is 3% of ABS weight, mix and extrude to obtain black ABS.

[0045] Tested according to ISO527, ISO180, ISO178, ISO75 standards, the test results show that compared with the original ABS, the tensile strength of the obtained black ABS is reduced by 10%, the elongation at break is increased by 5%, the impact strengt...

Embodiment 3

[0047] 50.0g of carbon black (average primary particle diameter is 21nm, oil absorption value is 55mL / 100g), 46.0g of linear low density polyethylene powder (MI50), 3.0g of EBS and 1.0g of zinc stearate are added to heat Type kneader, at a heating temperature of 130°C and a rotating speed of 20r / min, mix for 50 minutes, and then enter a twin-screw extruder with a length-to-diameter ratio of 48:1, extrusion temperature: 150°C, 160°C, 170°C , 180 ℃, 190 ℃, head temperature 180 ℃, host speed 260r / min, after cooling, drying, dicing, packaging into odorless black masterbatch.

[0048] Add the obtained black masterbatch into polycarbonate (PC), the consumption of the black masterbatch is 3% of PC weight, mix and extrude to obtain black PC.

[0049] Tested according to ISO527, ISO180, ISO178 standards, the test results show that compared with the original PC, the tensile strength of the obtained black PC is reduced by 2%, the elongation at break is reduced by 36%, the impact strength...

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Abstract

The invention discloses universal black masterbatch and a preparation method thereof. The black masterbatch comprises the following components in percentage by weight: 40 to 50 percent of carbon black, 46 to 56 percent of linear low-density polyethylene power, 1 to 3 percent of vinyl distearamide and 1 to 3 percent of zinc stearate, wherein the average primary particle size of the carbon black is19 to 23 nm and the oil absorbing value is 45 to 60 mL / 100 g; the melt index of the linear low-density polyethylene power is 20 to 50 g / 10 minute. The black masterbatch is prepared according to the steps of adding the components into a heating type kneading machine, kneading at a low speed, entering a double-screw extrusion machine to perform extrusion, and cooling, drying and pelletizing to prepare the black masterbatch. The black masterbatch provided by the invention is environmentally friendly, odorless and free of wax, has high color blackness and dispersibility, has little influence on the mechanical property of various plastic products and has high universality; the preparation method is low in production cost, simple and stable in process, simple and practical to operate and particularly suitable for industrialized large-scale production.

Description

technical field [0001] The invention belongs to the field of polymer materials, and in particular relates to a universal black masterbatch and a preparation method thereof. Background technique [0002] Synthetic resin and plastic are indispensable and important materials in various fields of production and life. Plastic coloring is an indispensable part of plastic production. It not only adds harmonious colors to plastic products, but also makes the world around us colorful. It can also endow plastics with multiple functions, improve some application properties of plastics and endow them with new characteristics. The traditional methods of plastic coloring include dry (floating dyeing) coloring, paste colorant coloring, liquid colorant coloring, etc. Pigments are generally powdery, with poor dispersibility, difficult control of metering, poor coloring effect, and high cost. In products with a very small amount of pigment, it will cause color difference; for products with h...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L77/00C08L55/02C08L69/00C08L23/12C08L23/06C08L23/08C08K5/098C08K3/04C08K5/20C08J3/22B29B7/00B29B9/06B29C48/60B29C48/92
CPCB29B7/002B29B9/06B29C48/625B29C48/92B29C2948/9259B29C2948/92704C08J3/226C08J2323/06C08J2323/12C08J2355/02C08J2369/00C08J2377/00C08J2423/08C08K3/04C08K5/098C08K5/20C08K2201/011
Inventor 袁峰
Owner 江苏永彩新材料科技有限公司
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