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Metal base waterborne graphene modified long-lasting anticorrosive paint and preparation method thereof

A water-based graphene and metal substrate technology, applied in the direction of anti-corrosion coatings, coatings, etc., can solve the problems of loss of anti-corrosion function, short anti-corrosion period, chemical bond breakage, etc., achieve unique anti-corrosion performance, strong complexation ability, and improve cross-linking degree of effect

Active Publication Date: 2019-01-08
广东绿色大地化工有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the current anti-corrosion coatings, because the main chain in the film-forming material is composed of C-C bonds, are prone to breakage of chemical bonds under the irradiation of ultraviolet light, thus losing the anti-corrosion function, resulting in a short anti-corrosion life; therefore, the development of long-term Efficient anti-corrosion coatings have become an important direction of current coatings research

Method used

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  • Metal base waterborne graphene modified long-lasting anticorrosive paint and preparation method thereof
  • Metal base waterborne graphene modified long-lasting anticorrosive paint and preparation method thereof
  • Metal base waterborne graphene modified long-lasting anticorrosive paint and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] A kind of metal substrate water-based graphene modified long-term anti-corrosion paint, is made up of the raw material of following parts by weight:

[0038] Silicone modified styrene-acrylic emulsion (selected from Xinde XD-510) and epoxy resin modified styrene-acrylic emulsion (selected from model SY8914) 45 parts of composite modified styrene-acrylic emulsion composed of mass ratio 1:4, modified 5 parts of graphene, 20 parts of rutile titanium dioxide with a fineness of 50nm, 0.8 part of defoamer BYK066N selected from BYK Chemicals, 0.8 part of leveling agent EFKA3777 selected from Ciba, 1 part of cobalt organic acid soap , selected from Wuxi Deyu Chemical Industry, wetting agent BYK-333 0.8 parts, selected from BYK Chemicals, anti-settling agent BYK-420 1 part, selected from BYK Chemicals, dispersant BYK-2022 0.3 parts, selected from BYK 30 parts of chemical and deionized water;

[0039] A kind of preparation method of waterborne graphene modified long-acting antic...

Embodiment 2

[0051] A kind of metal substrate water-based graphene modified long-term anti-corrosion paint, is made up of the raw material of following parts by weight:

[0052] Silicone modified styrene-acrylic emulsion (selected from Xinde XD-510) and epoxy resin modified styrene-acrylic emulsion (selected from model SY8914) 40 parts of composite modified styrene-acrylic emulsion composed of mass ratio 1:5, modified 10 parts of graphene, 25 parts of phthalocyanine blue with a fineness of 100nm, 0.5 part of defoamer BYK066N selected from BYK, 0.5 part of leveling agent EFKA3777 selected from Ciba, 0.8 part of cobalt organic acid soap, selected from From Wuxi Deyu Chemical Industry, wetting agent BYK-333 0.5 parts, selected from BYK Chemicals, anti-settling agent BYK-420 0.8 parts, selected from BYK Chemicals, dispersant BYK-2022 0.1 parts, selected from BYK Chemicals, 20 parts of deionized water;

[0053] A kind of preparation method of waterborne graphene modified long-acting anticorros...

Embodiment 3

[0065] A kind of metal substrate water-based graphene modified long-term anti-corrosion paint, is made up of the raw material of following parts by weight:

[0066] Silicone modified styrene-acrylic emulsion (selected from Xinde XD-510) and epoxy resin modified styrene-acrylic emulsion (selected from model SY8914) 50 parts of composite modified styrene-acrylic emulsion composed of mass ratio 1:3, modified 20 parts of graphene, 15 parts of high-pigment carbon black with a fineness of 200nm, 1 part of defoamer BYK066N, selected from BYK, 0.3 part of leveling agent EFKA3777, 0.5 part of Ciba, cobalt organic acid soap, Selected from Wuxi Deyu Chemical Industry, wetting agent BYK-333 1 part, selected from BYK Chemicals, anti-settling agent BYK-420 1.2 parts, selected from BYK Chemicals, dispersant BYK-2022 0.5 parts, selected from BYK Chemicals , 25 parts of deionized water;

[0067] A kind of preparation method of waterborne graphene modified long-acting anticorrosion paint of me...

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Abstract

The invention belongs to the technical field of anticorrosive coatings, and specifically relates to a metal base waterborne graphene modified long-acting anticorrosive paint and a preparation method thereof. The metal base waterborne long-lasting anticorrosive paint comprises the following raw materials in parts by weight: 40-50 parts of composite modified styrene-acrylic emulsion, 10-20 parts ofmodified graphene, 15-25 parts of pigment, 0.5-1 part of an antifoaming agent, 0.3-0.8 part of a leveling agent, 0.5-1 part of a waterborne drier, 0.5-1 part of a wetting agent, 0.8-1.2 parts of an anti-settling agent, 0.1-0.5 part of a dispersant, and 20-35 parts of deionized water. The preparation method comprises: (1) preparation of modified graphene; (2) pigment surface modification; and (3) preparation of the waterborne paint. The metal base waterborne graphene modified long-acting anticorrosive paint has the advantages of long-lasting excellent anticorrosive performance, strong base adhesion, high mechanical strength, excellent friction resistance, excellent solvent resistance and weather resistance, strong construction adaptability and the like; the preparation method is simple, easy to operate, low in raw material and energy consumption costs, environmentally-friendly and pollution-free; the coating is quickly dried, and the construction period is short.

Description

technical field [0001] The invention belongs to the technical field of anti-corrosion coatings, in particular to a water-based graphene-modified long-acting anti-corrosion coating for metal substrates and a preparation method thereof. Background technique [0002] Corrosion of metal is a phenomenon in which metal is destroyed by chemical or electrochemical action of environmental medium. The corrosion of metals spreads all over the national economy and brings huge losses to the national economy. In industrially developed countries, the direct economic loss caused by corrosion accounts for 1% to 4% of the total output value of the national economy, the annual corroded and rusted steel accounts for about 20% of the output, and about 30% of the equipment is scrapped due to corrosion. In China, the economic loss caused by metal corrosion is as high as 30 billion yuan per year, accounting for 4% of the gross national product. For a long time, people have used a variety of techn...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D125/14C09D5/08C09D7/62C09D7/41
CPCC08K2003/2241C09D5/08C09D7/41C09D7/62C09D125/14C08L25/14C08K9/06C08K9/02C08K3/042C08K9/04C08K3/22C08K9/08C08K3/04
Inventor 肖洪健谢秋梅
Owner 广东绿色大地化工有限公司
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