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Flexible polymer-based PTC material for normal-temperature thermal control, and preparation method thereof

A flexible polymer and warming technology, applied in the direction of film/sheet adhesives, adhesives, etc., can solve the problems that PTC materials cannot be flexible, cannot be thinned, and cannot be practically applied to high-precision temperature control at room temperature. , to achieve the effects of making up for the flexibility and inability to be thinned, good PTC characteristics and flexibility, and simple and feasible preparation methods

Active Publication Date: 2019-02-01
合肥低碳研究院
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This patented technology allows for creation of thermally controlled switches that have improved performance compared with existing ones due to its ability to change their resistance based on changes made within certain temperatures (T). These switches also allow for easier manufacturing process than previous designs because they only require two components - one being an organic compound called poly(styrene)-grafted polystyreneglycerate) resin mixed into another type of plastic known as liquid crystal elastomer), which makes it easy to mold them around tiny particles inside. By adding these blockscopopolymers along with other supporting materials like paraffine wax/graphite powders or conductivity carbon Black, this new composition becomes more flexible but still maintains excellent properties over time when heated above 100 degrees Celsius.

Problems solved by technology

This patented technical solution described by Cathayne et al describes how certain types of plastic called thermally sensitive semiconducers made up of crystal particles that expand upon exposure to specific temperatures show negative values indicating their ability to absorb energy during expansion. These plates may then undergo transformation back again after they reach these conditions - causing another increase in electrical resistance over time. By measuring both voltage levels and ambient air temperatures accurately, we found out what caused instabilities and leaks within the device' s circuitry. Additionally, there was no way to use existing methods like liquid nitrogen injection inside the devices without affecting their properties.

Method used

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  • Flexible polymer-based PTC material for normal-temperature thermal control, and preparation method thereof
  • Flexible polymer-based PTC material for normal-temperature thermal control, and preparation method thereof
  • Flexible polymer-based PTC material for normal-temperature thermal control, and preparation method thereof

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Effect test

Embodiment 1

[0026] The specific preparation steps of a flexible polymer-based PTC material for thermal control at room temperature are as follows:

[0027] (1) Add 45g of ethylene octene block copolymer (OBC) and 105g of paraffin into the stainless steel kettle body, cover the sealing cover tightly, then put the stainless steel kettle body into a constant temperature oil bath, and connect the vacuum pump through a rubber tube The exhaust port of the stainless steel kettle body is used to evacuate the inside of the kettle body, and stir and mix evenly with a digital constant speed mixer at a temperature of 150-170°C and a speed of 300 rpm;

[0028] (2) Add 100g of graphite powder (GP) again, stir at a speed of 300 rpm at a temperature of 150-170°C under vacuum conditions, stir and mix evenly to obtain a mixture;

[0029] (3) Press the mixed material into a disc sample with a diameter of 30mm and a thickness of 5mm by a hot press, cool to room temperature and set it, and let it stand for 3-...

Embodiment 2

[0035] The specific preparation steps of a flexible polymer-based PTC material for thermal control at room temperature are as follows:

[0036] (1) Add 45g of ethylene octene block copolymer (OBC) and 105g of n-octadecane into the stainless steel kettle body, cover and seal it tightly, then put the stainless steel kettle body into a constant temperature oil bath, and put the vacuum pump through the rubber The pipe is connected to the exhaust port of the stainless steel kettle body, and the inside of the kettle body is vacuumed. Under the conditions of temperature 150-170°C and speed 300 rpm, stir and mix evenly with a digital constant speed mixer;

[0037] (2) Add 100g of graphite powder (GP) again, stir at a speed of 300 rpm at a temperature of 150-170°C under vacuum conditions, stir and mix evenly to obtain a mixture;

[0038] (3) Press the mixed material into a film of 140mm*70mm*0.8mm by a hot press, cool to room temperature and shape it, let it stand for 6-8 hours, and wa...

Embodiment 3

[0041] The specific preparation steps of a flexible polymer-based PTC material for thermal control at room temperature are as follows:

[0042](1) Add 45g of ethylene octene block copolymer (OBC) and 135g of paraffin into the stainless steel kettle body, cover the sealing cover tightly, then put the stainless steel kettle body into a constant temperature oil bath, and connect the vacuum pump through a rubber tube The exhaust port of the stainless steel kettle body is used to evacuate the inside of the kettle body, and stir and mix evenly with a digital constant speed mixer at a temperature of 150-170°C and a speed of 300 rpm;

[0043] (2) Add 20 g of conductive carbon black (CB), and stir at a speed of 300 rpm at a temperature of 150-170° C. under a vacuum condition, and stir and mix evenly to obtain a mixture;

[0044] (3) Press the mixed material into a disc sample with a diameter of 30mm and a thickness of 5mm by a hot press, cool to room temperature and set it, and let it ...

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Abstract

The invention discloses a flexible polymer-based PTC material for normal-temperature thermal control, and a preparation method thereof. The material comprises a block copolymer, a phase change matrixand a conductive filler, wherein a mass of the block copolymer to the phase change matrix is (20:80) to (40:60), and the mass proportion of the conductive filler is less than 80%. The block copolymeris added to a composite material of paraffin and graphite powder or conductive carbon black as a as a supporting material, and the formula of all components is adjusted to make the prepared material have a PTC effect generating Curie temperature of -10-40 DEG C, have good flexibility and realize film formation, so the material can be applied to the fields of active temperature control and other normal-temperature thermal controls of electronic devices, and makes up for a main deficiency that existing normal-temperature thermal control PTC materials are not flexible and cannot be processed intofilms.

Description

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Claims

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Application Information

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Owner 合肥低碳研究院
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