Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Eucryptite microcrystal glass and preparation method thereof

A technology of glass-ceramics and eucryptite, which is applied in the field of eucryptite glass-ceramics and its preparation, can solve the problems of low utilization rate of eucryptite and high production cost of eucryptite glass-ceramics, and achieve good environmental resistance , Promote further development, excellent performance effect

Inactive Publication Date: 2019-05-10
WUHAN UNIV OF TECH
View PDF2 Cites 5 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] In view of this, the present invention aims to propose a kind of eucryptite glass-ceramics, to solve the existing domestic eucryptite utilization rate is low, the problem of high production cost of eucryptite glass-ceramics

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Eucryptite microcrystal glass and preparation method thereof
  • Eucryptite microcrystal glass and preparation method thereof
  • Eucryptite microcrystal glass and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] A kind of eucryptite glass-ceramic, by weight, the raw material of eucryptite glass-ceramic comprises: eucryptite: 67 parts, lepidolite: 2 parts, quartz sand: 20 parts, alumina: 2 parts, oxide Zirconium: 1.98 parts, titanium oxide: 2.75 parts, talc: 0.3 parts, barium carbonate: 1.91 parts, antimony trioxide: 0.50 parts, zinc oxide: 1 part.

[0030] Wherein, by weight percentage, the chemical composition of eucryptite includes: Li 2 O: 6.14%, Al 2 o 3 : 25.73%, SiO 2 : 63.74%, Na 2 O and K 2 Total O: 2.2%, TiO 2 , CaO, MnO and Fe 2 o 3 The total ≤ 2%, the loss on ignition and the remaining trace elements ≤ 1.5%; by weight percentage, the chemical composition of lepidolite includes: Li 2 O: 2.78%, Al 2 o 3 : 24.94%, SiO 2 : 54.41%, Na 2 O: 1.69%, K 2 O: 6.21%, F: 1.92%, TiO 2 , CaO, MnO and Fe 2 o 3 Total ≤ 2%, loss on ignition and residual trace elements ≤ 1.5%.

[0031] In terms of weight percentage, the corresponding oxide composition in the glass batc...

Embodiment 2

[0045] The difference between this embodiment and Embodiment 1 is that, in parts by weight, the raw materials of eutcryptite glass-ceramic include: eutcryptite: 62.61 parts, lepidolite: 3.25 parts, quartz sand: 23.65 parts, alumina: 3.36 parts , soda ash: 0.12 parts, zirconia: 1.98 parts, titanium oxide: 2.75 parts, talc: 0.5 parts, barium carbonate: 1.92 parts, antimony trioxide: 0.50 parts, zinc oxide: 1 part.

[0046] In terms of weight percentage, the corresponding oxide composition in the glass batch prepared from the above raw materials is: Li 2 O: 3.85%, Na 2 O: 1.22%, Al 2 o 3 : 0.25%, SiO 2 : 64.64%, K 2 O: 0.28%, TiO 2 : 2.78%, BaO: 1.49%, Sb 2 o 3 : 0.5%, ZnO: 1.00%, Zr 2 O: 2.00%, P 2 o 5 , MgO, and F total: 0.8%, other oxides with less content (Fe 2 o 3 +MnO+CaO) total: 0.65%.

[0047] The difference between the preparation method of the above-mentioned eucryptite glass-ceramic and that of Example 1 is that when the raw materials in step 1) are mixed,...

Embodiment 3

[0057] The difference between this embodiment and Embodiment 1 is that, in parts by weight, the raw materials of eutcryptite glass-ceramic include: eutcryptite: 57.01 parts, lepidolite: 6.23 parts, quartz sand: 28.42 parts, alumina: 5.26 parts , soda ash: 0.25 parts, zirconia: 1.98 parts, titanium oxide: 2.77 parts, talc: 0.45 parts, barium carbonate: 1.92 parts, antimony trioxide: 0.50 parts, zinc oxide: 1 part.

[0058] In terms of weight percentage, the corresponding oxide composition in the glass batch prepared from the above raw materials is:

[0059] Li 2 O: 3.51%, Na 2 O: 1.23%, Al 2 o 3 : 20.11%, SiO 2 : 64.96%, K 2 O: 0.28%, TiO 2 : 2.80%, BaO: 1.50%, Sb 2 o 3 : 0.50%, ZnO: 1.00%, Zr 2 O: 2.00%, P 2 o 5 , F and MgO total: 0.78%, other less oxides (Fe 2 o 3 , MnO and CaO) a total of 0.65%

[0060] The difference between the preparation method of the above-mentioned eucryptite glass-ceramics and that of Example 1 is that when the raw materials in step 1) a...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
sizeaaaaaaaaaa
flexural strengthaaaaaaaaaa
densityaaaaaaaaaa
Login to View More

Abstract

The invention provides eucryptite microcrystal glass and a preparation method thereof. The eucryptite microcrystal glass is prepared from, by weight, 45-70% of eucryptite, 1-5% of lepidolite, 20-38% of quartz sand, 2-8% of aluminum oxide, 3-5% of zirconium oxide and titanium oxide, 0.2-0.8% of talcum, 1-3% of barium carbonate, 0.2-0.7% of antimony trioxide and 0-1.5% of zinc oxide. The Sinkiang eucryptite is used as a main material, and the transparent eucryptite microcrystal glass with low expansion is prepared through synergistic effects of raw materials while indexes of strength, hardness,wear resistance and the like reach utilization standards; on the one hand, the resource utilization rate of domestic eucryptite is increased; on the other hand, microcrystal glass production cost is sharply reduced, getting rid of limitation of foreign imported resources on the industry of lithium-aluminum-silicon microcrystal glass is realized, and accordingly further development of the domesticindustry of lithium-aluminum-silicon microcrystal glass is effectively promoted.

Description

technical field [0001] The invention relates to the technical field of glass-ceramics, in particular to a eucryptite glass-ceramics and a preparation method thereof. Background technique [0002] Glass-ceramics can also be called glass-ceramics, which means that the basic glass is obtained by firing a specific composition formula, and then it is subjected to a certain heat treatment process under a certain temperature system, so that the crystal nucleating agent in the basic glass passes through various The effect is to precipitate a large number of tiny crystalline phases that are evenly distributed with the glass phase in the glass, thereby obtaining a polycrystalline composite solid material with a special structure. [0003] Among them, the expansion coefficient of lithium aluminum silicon (LAS) glass-ceramics is very low, which belongs to the category of low expansion and ultra-low expansion, and can be used in (-5×10 -7 / °C)—(+80×10 -7 / °C) can be adjusted arbitraril...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): C03C10/14C03C6/04C03C6/02C03B32/02
Inventor 何峰陈美桃施江谢峻林
Owner WUHAN UNIV OF TECH
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products