Rubber composition and vulcanized rubber for shoe soles, preparation method and application thereof
A technology of vulcanized rubber and rubber matrix, which is applied in the application field of vulcanized rubber, preparation of vulcanized rubber, and preparation of shoe soles. It can solve the problems of poor dynamic flexural performance and low rubber strength, so as to improve wear resistance, strength and bending resistance. flexible effect
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[0055] In order to specifically illustrate the method for preparing vulcanized rubber of the present invention, a preferred embodiment is provided below for illustration:
[0056] (1) Put the rubber matrix in the internal mixer, the speed is 50-120rpm, the initial mixing temperature is 70-90°C, and the raw rubber mastication time is 0.1-1min; then the mixture containing the initiator and Component A of the rubber modifier is introduced into the above-mentioned internal mixer for the first mixing to obtain a section of masterbatch;
[0057] (2) Add the one-stage masterbatch and component B containing white carbon black, activator, anti-aging agent, carbonate and softener into the internal mixer for the second mixing, discharge and park for 3-5 hours , to obtain the second-stage masterbatch;
[0058] (3) Set the speed of the internal mixer to 50-100rpm, and the initial mixing temperature to 25-50°C. After masticating the second-stage masterbatch for 0.5-1.5 minutes, add compone...
Embodiment 1
[0088] Rubber composition formula: 100 parts by weight of butadiene rubber, 40 parts by weight of white carbon black, 0.2 parts by weight of DCP, 5 parts by weight of glycidyl methacrylate, 8 parts by weight of zinc carbonate, 10 parts by weight of 10# white oil, 5 parts by weight of stearic acid, 1 part by weight of sulfur, 3 parts by weight of accelerator DM, 1.5 parts by weight of accelerator TMTD, 1.5 parts by weight of accelerator D, and 0.5 parts by weight of anti-aging agent 264.
[0089] Preparation process of vulcanized rubber:
[0090] (1) Perform the first mixing of rubber matrix, initiator and rubber modifier to obtain a section of masterbatch; specifically, add butadiene rubber into the internal mixer, set the rotation speed to 80rpm, and the initial mixing temperature to 80°C , the raw rubber masticating time is 0.5min; add the initiator and rubber modifier to the above-mentioned internal mixer for mixing, the mixing temperature is 150°C, and the mixing time is 8...
Embodiment 2
[0096] Rubber composition formula: 100 parts by weight of butadiene rubber, 50 parts by weight of white carbon black, 0.6 parts by weight of BPO, 8 parts by weight of methyl methacrylate, 5 parts by weight of zinc carbonate, 18 parts by weight of 10# white oil, hard 3 parts by weight of fatty acid, 4 parts by weight of sulfur, 4 parts by weight of accelerator DM, and 2 parts by weight of antioxidant 264.
[0097] Preparation process of vulcanized rubber:
[0098] (1) Perform the first mixing of rubber matrix, initiator and rubber modifier to obtain a section of masterbatch; specifically, add butadiene rubber into the internal mixer, set the rotation speed to 80rpm, and the initial mixing temperature to 80°C , the raw rubber masticating time is 0.5min; add the initiator and rubber modifier to the above-mentioned internal mixer for mixing, the mixing temperature is 160°C, and the mixing time is 6min to obtain a masterbatch;
[0099] (2) Add the one-stage masterbatch and white c...
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