Organic light-emitting compound, preparation method thereof and device
A technology of organic light-emitting devices and light-emitting compounds, applied in the fields of silicon organic compounds, organic chemistry, chemical instruments and methods, etc., can solve problems such as different performances
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
preparation example 1
[0075] Synthesis of Compound G-1 and Compound 1
[0076] 1) Synthesis of Compound G-1
[0077]
[0078]a) Material A-1 (14.0 g, 50 mmol) and material B (9.8 g, 50 mmol) were dissolved in 300 mL of dry toluene in a 500 mL round bottom flask under nitrogen atmosphere. Then sodium tert-butoxide (9.6g, 100mmol) and 2-dicyclohexylphosphine-2,4,6-triisopropylbiphenyl (4.76g, 10mmol) were added to the flask, followed by palladium acetate (0.56g, 2.5 mmol). The reaction was heated to 100°C and stirred for 10 hours. After the reaction, the temperature was lowered to room temperature, the salt and the catalyst were removed, the toluene was concentrated, and 200 mL of ethanol was used for recrystallization to obtain intermediate C-1 (16.83 g, yield: 85%).
[0079] b) Intermediate C-1 (15.0g, 37.88mmol) and Intermediate D-1 (7.42g, 37.88mmol) were completely dissolved in a mixed solution of 150mL toluene and 50mL tetrahydrofuran in a 500mL round bottom flask, and then added p-tolu...
preparation example 2
[0085] Synthesis of Compound 7
[0086]
[0087] 1) Prepare intermediate G-7 according to the synthesis method of intermediate G-1 in Preparation Example 1, except that intermediates A-7, C-7, and E-7 are used instead of A-1, C-1, and E -1.
[0088]
[0089] 2) Compound 7 was prepared according to the synthesis method of Compound 1 in Preparation Example 1, except that intermediates G-7 and H-7 were used instead of intermediates G-1 and H-1. Compound 7 (14.73 g, yield: 79%) was obtained. ESI-MS(m / z)(M+): theoretical value is 676.25, measured value is 676.55
preparation example 3
[0090] Synthesis of Compound 23
[0091]
[0092] Intermediate G-23 was prepared according to the synthesis method of intermediate G-1 in Preparation Example 1, except that intermediates A-23, C-23, E-23, and F-23 were used instead of A-1 and C-1 , E-1, F-1.
[0093]
[0094] 2) Compound 23 was prepared according to the synthesis method of Compound 1 in Preparation Example 1, except that intermediates G-23 and H-23 were used instead of intermediates G-1 and H-1. Compound 23 (16.22 g, yield: 83%) was obtained. ESI-MS (m / z) (M+): The theoretical value is 651.22, and the measured value is 651.37.
PUM
| Property | Measurement | Unit |
|---|---|---|
| thickness | aaaaa | aaaaa |
| thickness | aaaaa | aaaaa |
Abstract
Description
Claims
Application Information
Login to View More