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A kind of graphite composite material and preparation method thereof

A composite material and graphite technology, applied in metal material coating process, coating, liquid chemical plating and other directions, can solve the problems of poor discoloration resistance of coating layer, strong cohesion of graphite powder, and inability to guarantee process conditions, etc. To achieve the effect of low equipment requirements, strong anti-discoloration ability, and no radioactive pollution

Active Publication Date: 2020-11-06
CENT SOUTH UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, the powder metallurgy method has been applied in industry, because the density difference between graphite and metal powder is too large, and the graphite powder has strong cohesion, poor dispersion, uneven mixing, and easy segregation, which limits its large-scale production; arc spraying The technology is to spray a metal layer on the surface of graphite. The prepared coating layer has poor discoloration resistance, unevenness, weak bonding force and high cost, which limits its further application; the latest research direction also includes electroplating, but electroplating Changing the thickness of the powder coating during the process will lead to drastic fluctuations in the system resistance, which cannot guarantee fixed process conditions. The process control is more troublesome and the cost is higher.

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  • A kind of graphite composite material and preparation method thereof
  • A kind of graphite composite material and preparation method thereof
  • A kind of graphite composite material and preparation method thereof

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Effect test

Embodiment 1

[0039] A kind of preparation method of graphite composite material of the present invention, comprises the following steps:

[0040] (1) Acid treatment: use high-purity graphite rods as the substrate, and the size of the graphite rods is 50mm long, 5mm wide, and 5mm high. Put the graphite rods into a mixture of concentrated sulfuric acid and concentrated nitric acid (volume ratio: 3:1) and ultrasonically Treat for 10 minutes, clean up with a large amount of deionized water, and obtain the acid-treated graphite rod;

[0041](2) Sensitization treatment: take by weighing 2.5g tin protochloride and dissolve in 2.5ml concentrated hydrochloric acid (mass concentration is 36%), add water and dilute to 100ml, obtain sensitization solution, then with step (1) gained acid after treatment The graphite rod is added to the sensitization solution for ultrasonic treatment for 10 minutes, and cleaned with a large amount of deionized water to obtain a sensitized graphite rod;

[0042] (3) Act...

Embodiment 2

[0056] A kind of preparation method of graphite composite material of the present invention, comprises the following steps:

[0057] (1) Acid treatment: use high-purity graphite rods as the substrate, and the size of the graphite rods is 50mm long, 5mm wide, and 5mm high. Put the graphite rods into a mixture of concentrated sulfuric acid and concentrated nitric acid (volume ratio: 2:1) for ultrasonic Treat for 10 minutes, clean up with a large amount of deionized water, and obtain the acid-treated graphite rod;

[0058] (2) Sensitization treatment: take by weighing 2.5g tin protochloride and dissolve in 2.5ml concentrated hydrochloric acid (mass concentration is 36%), add water and dilute to 100ml, obtain sensitization solution, then with step (1) gained acid after treatment The graphite rod is added to the sensitization solution for ultrasonic treatment for 10 minutes, and cleaned with a large amount of deionized water to obtain a sensitized graphite rod;

[0059] (3) Activa...

Embodiment 3

[0070] A kind of preparation method of graphite composite material of the present invention, comprises the following steps:

[0071] (1) Acid treatment: use high-purity graphite rods as the substrate, and the size of the graphite rods is 50mm long, 5mm wide, and 5mm high. Put the graphite rods into a mixture of concentrated sulfuric acid and concentrated nitric acid (volume ratio: 2:1) for ultrasonic Treat for 10 minutes, clean up with a large amount of deionized water, and obtain the acid-treated graphite rod;

[0072] (2) Sensitization treatment: take by weighing 2.5g tin protochloride and dissolve in 2.5ml concentrated hydrochloric acid (mass concentration is 36%), add water and dilute to 100ml, obtain sensitization solution, then with step (1) gained acid after treatment The graphite rod is added to the sensitization solution for ultrasonic treatment for 10 minutes, and cleaned with a large amount of deionized water to obtain a sensitized graphite rod;

[0073] (3) Activa...

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Abstract

The invention discloses a graphite composite material. The graphite composite material is composed of a graphite matrix and a copper-gold-zinc alloy layer on the surface layer of the graphite matrix,wherein the copper-gold-zinc alloy layer is obtained by alloying a copper coating, a gold coating and a zinc coating, and the copper-gold-zinc alloy layer is composed of the following components of, in percentage by weight, 15%-78% of the copper, 2%-55% of the gold and 20%-30% of the zinc. The graphite composite material adopts graphite as a substrate, and has the characteristics of low density, chemical stability, high temperature resistance, thermal shock resistance, self-lubricating property, 3D printing easiness and the like, the surface of the graphite is coated with the copper-gold-zincalloy layer, so that high gold degree, conductivity, high strength and good ductility of the copper-gold-zinc alloy are achieved, a synergistic effect is further generated between the graphite and thecopper-zinc alloy layer, so that the graphite composite material has wide application prospects; by regulating and controlling process parameters, the copper-gold-zinc alloy layer with the high golddegree and strong anti-color-change capability can be obtained, interface bonding is good, the coatings are uniform, and the components are controllable; and the graphite composite material is simplein process and low in cost, and can be suitable for large-scale production.

Description

technical field [0001] The invention belongs to the field of composite material preparation, and in particular relates to a graphite composite material and a preparation method thereof. Background technique [0002] The crystal structure of graphite determines that it has many characteristics such as excellent high temperature resistance, thermal shock resistance, electrical conductivity, self-lubricating property, etc. In addition, graphite has good chemical stability at room temperature, is environmentally friendly and healthy, and has no radioactive pollution. Complicated handicrafts and artistic decorations are prepared by 3D printing technology, but the dark black surface color does not conform to the public's aesthetics, which limits its application in this field. In actual production, it is usually necessary to carry out surface treatment on the surface of graphite to improve the performance of graphite. Combining graphite with metal materials not only has the color o...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23C18/18C23C18/40C23C18/52C23C18/44
CPCC23C18/1889C23C18/40C23C18/44C23C18/52
Inventor 李周龚深肖柱王洋吴迪肖韬
Owner CENT SOUTH UNIV
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