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Method for decreasing sensitivity by coating single-compound explosive with norepinephrine

A technology of norepinephrine and elemental explosives, which is applied in the directions of explosives, non-explosive/non-thermal agent components, non-explosive desensitizers/passivators, etc., can solve the problem of high mechanical sensitivity, and achieve reduced mechanical sensitivity and reaction conditions Mild, friction-reducing effect

Active Publication Date: 2019-09-27
INST OF CHEM MATERIAL CHINA ACADEMY OF ENG PHYSICS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Commonly used high-energy single-substance explosives have high mechanical sensitivity, and their applications are limited, so they need to be desensitized

Method used

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  • Method for decreasing sensitivity by coating single-compound explosive with norepinephrine
  • Method for decreasing sensitivity by coating single-compound explosive with norepinephrine

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] (1) Weigh 0.12g Tris (trishydroxymethylaminomethane), measure 100ml water, stir and mix thoroughly, so that Tris is completely dissolved in water, and prepare a solution with a Tris concentration of 10mmol / L and a pH value of 8.5.

[0018] (2) Take 0.5g norepinephrine and add it to the Tris solution prepared in step (1) to prepare a solution with a norepinephrine concentration of 5 mg / ml;

[0019] (3) Add 5.0 g of HMX granules to the norepinephrine solution in step (2), and let stand for 24 hours;

[0020] (4) Washing with water, filtering, separating and drying the HMX particles at a drying temperature of 50° C. to obtain HMX particles coated with desensitization on the surface. like figure 1 and figure 2 as shown, figure 1 Scanning electron micrographs of the surface of uncoated HMX particles, figure 2 It is a scanning electron micrograph of the coated HMX particle surface, which shows a uniform norepinephrine film on the surface. The characteristic drop height...

Embodiment 2

[0022] (1) Weigh 0.24g Tris, measure 100ml water, stir and mix thoroughly, so that Tris is completely dissolved in water, and prepare a solution with a Tris concentration of 20mmol / L and a pH value of 8.9.

[0023] (2) Take 0.5g norepinephrine and add it to the Tris solution prepared in step (1) to prepare a solution with a norepinephrine concentration of 5 mg / ml;

[0024] (3) Add 5.0 g of HMX granules to the norepinephrine solution in step (2), and let stand for 24 hours;

[0025] (4) Washing with water, filtering, separating and drying the HMX particles at a drying temperature of 50° C. to obtain HMX particles coated with desensitization on the surface. The characteristic drop height of HMX is increased from 32.0cm to 48.0cm; the friction sensitivity is reduced from 100% to 30%.

Embodiment 3

[0027] (1) Weigh 0.12g Tris, measure 100ml water, stir and mix thoroughly, so that Tris is completely dissolved in water, and prepare a solution with a Tris concentration of 10mmol / L and a pH value of 8.5.

[0028] (2) Weigh 1.0 g of norepinephrine, add it into the Tris solution prepared in step (1), and prepare a solution whose norepinephrine concentration is 10 mg / ml;

[0029] (3) Add 5.0 g of HMX granules to the norepinephrine solution in step (2), and let stand for 24 hours;

[0030] (4) Washing with water, filtering, separating and drying the HMX particles at a drying temperature of 50° C. to obtain HMX particles coated with desensitization on the surface. The characteristic drop height of HMX is increased from 32.2cm to 46.0cm; the friction sensitivity is reduced from 100% to 30%.

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Abstract

The invention discloses a method for decreasing sensitivity by coating single-compound explosive with norepinephrine, including the following steps: (1) adding a certain amount of trishydroxymethylaminomethane to water to completely dissolve to obtain a trishydroxymethylaminomethane solution; (2) weighing a certain amount of norepinephrine, and adding the same to the trishydroxymethylaminomethane solution to obtain a solution with the norepinephrine concentration of 1 to 100 mg / ml; (3) adding single-compound explosive to the solution obtain in step (2), standing or stirring for a period of time to complete the surface coating; (4) washing with water, filtering, separating single-compound explosive particles out and drying at a certain temperature to obtain the single-compound explosive with a norepinephrine polymer-coated surface. The method can reduce the mechanical sensitivity of the single-compound explosive, and the coating step and the post-treatment process are simple.

Description

technical field [0001] The invention relates to the technical field of energetic materials, in particular to a method for reducing the sensitivity of a norepinephrine-coated elemental explosive. Background technique [0002] The development and application of insensitive explosives is a necessary condition for improving the safety of weapons and ammunition itself, and reducing the mechanical sensitivity of high-energy single-substance explosives is a key technology for realizing high-energy insensitive explosives. Commonly used high-energy single-substance explosives have high mechanical sensitivity, and their applications are limited, so they need to be desensitized. Among the existing desensitization methods for explosives, surface coating has attracted the attention of researchers at home and abroad as a method with a relatively simple process, a wide range of applications, and a method that can be used comprehensively with other types of desensitization methods. Conten...

Claims

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Application Information

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IPC IPC(8): C06B23/00C06B45/22
CPCC06B23/005C06B45/22
Inventor 谢虓林国忠柴志宇黄川郑保辉祝青肖春刘涛
Owner INST OF CHEM MATERIAL CHINA ACADEMY OF ENG PHYSICS