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Flexible stretchable temperature control conductor insulator reversible transformation material and application thereof

An insulator, reverse transformation technology, used in the direction of insulating conductors/cables, manufacturing extensible conductors/cables, etc., can solve the problems of inability to withstand stretching, bending, deformation, small resistance change range, poor stretchability, etc. Achieve the effect of good reversibility and repeatability of resistance change, large resistance change range, and fast temperature control response speed.

Active Publication Date: 2019-12-10
TSINGHUA UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Traditional temperature-controlling conductor-insulator transition materials include Mott insulators, metal oxides, perovskites, organic diaphragms, etc., which are basically composed of solid rigid materials, without flexibility and stretchability, and cannot withstand stretching and bending , deformation, thus limiting its application in flexible electronics, wearable electronics that directly interact with people, etc.
[0003] In order to improve the flexible and stretchable properties of traditional temperature-controlled conductor-insulator transition materials, researchers have mixed some filler materials with flexible silica gel and other materials; the filler materials mainly include carbon nanotubes, graphene, and solid metal particles, etc., but the composite materials obtained There are the following disadvantages: the range of resistance change is small, the resistance change can only be stimulated by pressure, the stretchability is poor, and the manufacturing process is complicated, etc.

Method used

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  • Flexible stretchable temperature control conductor insulator reversible transformation material and application thereof
  • Flexible stretchable temperature control conductor insulator reversible transformation material and application thereof
  • Flexible stretchable temperature control conductor insulator reversible transformation material and application thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0031] This embodiment provides a flexible and stretchable material, and the stretchable temperature control switch made of the same can be used in the field of outer space exploration, such as on Mars or the moon.

[0032] The flexible and stretchable material consists of liquid metal for GaIn 24.5 , AB glue is mixed at a volume ratio of 2:3, and stirred at 600r / min for 2 minutes to obtain;

[0033] The obtained flexible and stretchable material is poured into a section of disconnected circuit of the control system to obtain a stretchable temperature control switch.

[0034] After testing, the obtained stretchable temperature control switch can withstand temperatures between -196°C and 200°C. The conductor-insulator transition temperature is -50°C.

[0035] On the moon and other uninhabited areas, the environment is very harsh, the extreme low temperature can reach -180°C, and the extreme high temperature can reach 126°C. Such an environment brings great challenges to the ...

Embodiment 2

[0038] This embodiment provides a flexible and stretchable material, and a low-temperature and high-temperature alarm device made thereof.

[0039] The flexible and stretchable material is made of liquid metal GaIn 24.5 , polymethylvinylsiloxane and polymethylhydrogensiloxane mixed at a volume ratio of 2:3, and stirred at 600r / min for 2 minutes to obtain.

[0040] The obtained flexible and stretchable material is poured into a certain circuit of the alarm system to obtain a low temperature and high temperature alarm device.

[0041] After testing, the low temperature and high temperature alarm device can automatically connect the circuit and activate the alarm when the temperature is lower than minus 50°C.

[0042]Low temperature will cause some damage to certain instruments, making them unable to work. When the ambient temperature reaches a dangerous temperature, the above materials will automatically conduct electricity, and an alarm can be issued, and the heating device ca...

Embodiment 3

[0044] This embodiment provides a flexible and stretchable material, and a failure alarm device made of the same for a low-temperature refrigerator.

[0045] The flexible stretchable material is obtained by mixing liquid metal Ga and AB glue at a volume ratio of 2:3; and stirring at 600r / min for 2 minutes;

[0046] The failure alarm device is obtained by pouring the flexible stretchable material into a certain section of the circuit of the temperature control detection system of the low-temperature refrigerator.

[0047] After testing, when the ambient temperature of the failure alarm device is higher than minus 40°C, the circuit will be automatically disconnected and an alarm will be issued; the transition temperature from the conductor to the insulator is minus 40°C.

[0048] The low-temperature refrigerator needs to maintain a low-temperature environment at all times. When the instrument fails or the power is cut off, the temperature of the refrigerator rises. At this time,...

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Abstract

The invention relates to a flexible stretchable temperature control conductor insulator reversible transformation material and an application thereof. The flexible stretchable temperature control conductor insulator reversible transformation material comprises liquid metal and a flexible base material, wherein a volume ratio of the liquid metal to the flexible base material is 1: (0.15-10). The material is advantaged in that the preparation method is simple, the resistance change range is large, the response speed is high, repeatability is good, the stretchability is high (780%), and 3D printing can be achieved. The material can be widely applied to various fields, for example, the material is further made into a flexible temperature switch, a temperature sensor, a stretchable semiconductor, a resistive random access memory and a low-temperature automatic protection device.

Description

technical field [0001] The invention belongs to the field of conductor-insulator conversion materials, and in particular relates to a flexible and stretchable temperature-controlled conductor-insulator reversible conversion material and its application. Background technique [0002] Materials that change conductivity through temperature are widely used in many fields, such as smart switches, sensors, semiconductors, and resistive memory. Traditional temperature-controlling conductor-insulator transition materials include Mott insulators, metal oxides, perovskites, organic diaphragms, etc., which are basically composed of solid rigid materials, without flexibility and stretchability, and cannot withstand stretching and bending , deformation, thus limiting its application in flexible electronics, wearable electronics that directly interact with people, etc. [0003] In order to improve the flexible and stretchable properties of traditional temperature-controlled conductor-ins...

Claims

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Application Information

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IPC IPC(8): H01B13/06H01B13/008C22C12/00C22C28/00
CPCC22C12/00C22C28/00H01B13/008H01B13/06
Inventor 汪鸿章刘静
Owner TSINGHUA UNIV
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