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Permanent antistatic natural-color polyurethane rubber roller

An antistatic and polyurethane technology, applied in the field of polyurethane rubber rollers, can solve the problems of no antistatic, easy precipitation and falling off of antistatic, and poor antistatic effect.

Inactive Publication Date: 2019-12-20
KUNSHAN BYE MACROMOLECULE MATERIAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The existing method of anti-static polyurethane rubber rollers is to add conductive particles such as carbon black metal oxides, but it will make the rubber rollers have a specific color; another method is to add surfactant antistatic agents, but this type of antistatic The antistatic agent has poor effect in low humidity environment, and the antistatic agent is easy to precipitate and fall off, resulting in poor antistatic effect or no antistatic effect at the end of the service life of the rubber roller

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] The invention provides the following technical solutions: a permanent antistatic natural color polyurethane rubber roller, the rubber is made of the following raw materials in parts by weight: 50 parts of polyethylene glycol, 2 parts of wear-resistant agent, 5 parts of antistatic agent, and 5 parts of glycerin 5 parts, 5 parts of lithium nitrate, 10 parts of lithium oxalate, 5 parts of ethanol, 5 parts of butanediol, 5 parts of lithium formate, 5 parts of diaminodiphenylmethane.

[0023] According to the manufacture method of a kind of permanent antistatic natural color polyurethane rubber roller of said scheme, comprises the following steps:

[0024] S1. First, add glycerin to polyethylene glycol and heat to 130°C;

[0025] S2. Dehydration under vacuum for 1.5 hours, then heated to 130°C, dehydration under vacuum, and repeated three times;

[0026] S3. When the temperature drops to 50°C, add anti-wear agent, antistatic agent, ethanol, butanediol and diaminodiphenylmet...

Embodiment 2

[0036] The invention provides the following technical solutions: a permanent antistatic natural color polyurethane rubber roller, the rubber is made of the following raw materials in parts by weight: 50 parts of polyethylene glycol, 3 parts of wear-resistant agent, 7 parts of antistatic agent, and 7 parts of glycerin 13 parts of lithium nitrate, 15 parts of lithium oxalate, 7 parts of ethanol, 12 parts of butanediol, 7 parts of lithium formate, 12 parts of diaminodiphenylmethane.

[0037] According to the manufacture method of a kind of permanent antistatic natural color polyurethane rubber roller of said scheme, comprises the following steps:

[0038] S1. First, add glycerin to polyethylene glycol and heat to 135°C;

[0039] S2. Dehydration under vacuum for 1.5 hours, then heated to 135°C, dehydration under vacuum, and repeated three times;

[0040] S3. When the temperature drops to 55°C, add anti-wear agent, antistatic agent, ethanol, butanediol and diaminodiphenylmethane, ...

Embodiment 3

[0050] The invention provides the following technical solutions: a permanent antistatic natural color polyurethane rubber roller, the rubber is made of the following raw materials in parts by weight: 50 parts of polyethylene glycol, 5 parts of wear-resistant agent, 10 parts of antistatic agent, and 10 parts of glycerin 20 parts of lithium nitrate, 20 parts of lithium oxalate, 10 parts of ethanol, 15 parts of butanediol, 10 parts of lithium formate, 15 parts of diaminodiphenylmethane.

[0051] According to the manufacture method of a kind of permanent antistatic natural color polyurethane rubber roller of said scheme, comprises the following steps:

[0052] S1. First, add glycerin to polyethylene glycol and heat to 140°C;

[0053] S2. Dehydration under vacuum for 1.5 hours, then heated to 140°C, dehydration under vacuum, and repeated three times;

[0054] S3. When the temperature drops to 60°C, add anti-wear agent, antistatic agent, ethanol, butanediol and diaminodiphenylmetha...

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PUM

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Abstract

The invention belongs to the technical field of polyurethane rubber rollers, and particularly relates to a permanent antistatic natural-color polyurethane rubber roller, wherein the rubber is preparedfrom the following raw materials by weight: 2-5 parts of a wear-resistant agent, 5-10 parts of an antistatic agent, 5-10 parts of glycerol, 5-20 parts of lithium nitrate, 10-20 parts of lithium oxalate, 5-10 parts of ethanol, 5-15 parts of butanediol, 5-10 parts of lithium formate and 5-15 parts of diaminodiphenyl methane. The production method of the permanent antistatic natural-color polyurethane rubber roller comprises: adding glycerol into polyethylene glycol, heating to a temperature of 130-140 DEG C, dehydrating for 1.5 h under vacuum, heating to a temperature of 130-140 DEG C, dehydrating under vacuum, repeating the steps three times, and carrying out other steps after the temperature is reduced to 50-60 DEG C. According to the invention, the reactive antistatic agent is prepared by compounding the polyethylene glycol and the organic lithium salt, the polyurethane synthesized by the reactive antistatic agent is essentially an ionic electrolyte, and the polyurethane rubber roller prepared from the reactive antistatic agent has non-permanent antistatic property, cannot change the primary color of polyurethane, and can be used for preparing a transparent rubber roller.

Description

technical field [0001] The invention belongs to the technical field of polyurethane rubber rollers, and in particular relates to a permanent antistatic natural color polyurethane rubber roller. Background technique [0002] Polyurethane rubber is a kind of rubber with excellent tensile strength, elasticity and elongation at break. It is often used to prepare special rubber rollers and wear-resistant products used in various papermaking and smelting industries. [0003] The existing method of anti-static polyurethane rubber rollers is to add conductive particles such as carbon black metal oxides, but it will make the rubber rollers have a specific color; another method is to add surfactant antistatic agents, but this type of antistatic The antistatic agent has poor effect in low humidity environment, and the antistatic is easy to precipitate and fall off, resulting in poor antistatic effect or no antistatic effect at the end of the service life of the rubber roller. Content...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G18/66C08G18/48C08G18/32C08K3/28C08K5/098
CPCC08G18/4833C08G18/6674C08G18/6677C08G18/6685C08K3/28C08K5/098
Inventor 喻四海车荣升宁永宏施法宽
Owner KUNSHAN BYE MACROMOLECULE MATERIAL CO LTD