Polyolefin resin foam sheet and adhesive tape
A polyolefin-based resin and foam sheet technology, applied in adhesives, pressure-sensitive films/sheets, film/sheet-shaped adhesives, etc., can solve the problem of reducing the foaming ratio of foam sheets The softness of the bubble sheet, the inability to use small electronic devices and other problems, achieve the effect of excellent flexibility and excellent light-shielding properties
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Embodiment 1
[0145] Linear low-density polyethylene ("Exact3027" manufactured by Exon Chemical Co., Ltd., density: 0.900 g / cm2) was used as a polyolefin resin. 3 ) 100 parts by mass, 1.13 parts by mass of a pigment (manufactured by Dainichi Seika Co., Ltd., AP-09979), 2.1 parts by mass of azodicarbonamide as a thermally decomposable foaming agent, 1 mass part of zinc oxide as a decomposition temperature regulator parts, and 0.5 parts by mass of 2,6-di-tert-butyl-p-cresol as an antioxidant are supplied to the extruder, melted and kneaded at 130°C, and then the polyolefin resin composition is extruded into a length of about 0.3 mm in thickness. Strip flaky.
[0146] Next, irradiate the above-mentioned long sheet-shaped polyolefin-based resin composition with an electron beam of 70 kGy at an accelerating voltage of 500 kV to cross-link it, and then continuously send it through hot air and infrared heaters and keep it at 250 ° C. It was heated in a foaming furnace for foaming, and stretched w...
Embodiment 2~8、 example 1~8
[0148] The compounding of the polyolefin resin composition was changed as shown in Table 1 and Table 2, and the amount of thread at the time of crosslinking was adjusted to the gel ratio in Tables 1 and 2, and the draw ratio of MD and TD was adjusted to 1.2 times -4.0 times, except these, it carried out similarly to Example 1.
[0149] Table 1
[0150]
[0151] Table 2
[0152]
[0153] From the results of the above examples, it can be seen that the present invention can provide a polyolefin-based resin foam sheet having excellent light-shielding properties and excellent flexibility, and an adhesive tape using the polyolefin-based resin foam sheet. On the other hand, in Comparative Examples 1 and 2, the gel ratio was out of the predetermined range, the bubble diameter was large, and the light-shielding property was insufficient. In Comparative Examples 3 and 4, the 25% compressive stress was out of the prescribed range, and the compounding amounts of the pigments in Co...
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Abstract
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