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A kind of MBR plate type membrane cleaning agent and cleaning method

A technology for cleaning chemicals and plate membranes, applied in chemical instruments and methods, membrane technology, semi-permeable membrane separation, etc., can solve problems such as uneven chemical cleaning and unrecoverable chemicals, and achieve saving time for adding chemicals and stabilizing water flow. The effect of low quantity and production cost

Active Publication Date: 2022-07-12
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The cleaning agent provided by the present invention includes alkaline cleaning agent and / or acidic cleaning agent, which can efficiently remove various pollutants remaining on the surface of the ultrafiltration membrane and in the membrane pores; the online cleaning method of the present invention will The cleaning agent is injected into the interior of the plate membrane, and then the residual cleaning agent in the membrane is recovered after standing still for aeration and scrubbing. On the one hand, it can overcome the shortcomings of the existing plate membrane chemical cleaning that is not uniform and the agent cannot be recovered. On the other hand, it is effective Improve the chemical cleaning intensity and the recovery rate of the mold performance after chemical cleaning, prolong the chemical cleaning cycle and service life of the MBR plate membrane system

Method used

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  • A kind of MBR plate type membrane cleaning agent and cleaning method

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0069] Taking the domestic sewage processed by a certain company as the raw water of the present embodiment, the specific water quality data analysis is shown in Table 1:

[0070] Table 1

[0071] COD / ppm BOD / ppm Sludge concentration / ppm 2560 1480 4300

[0072] MBR plate membrane is used to treat the above-mentioned sewage, and after continuous operation for 2-5 days, the cleaning agent and the online cleaning method of the present application are used for cleaning.

[0073] S1, prepare an alkaline cleaning agent, which comprises the following components: sodium dodecyl benzene sulfonate 1wt%, sodium dodecyl sulfate 0.5wt%, sodium hypochlorite 0.5wt% and the water produced by MBR plate membrane treatment, and use Sodium hydroxide to adjust pH to 10.5;

[0074] S2, stop the water production of the MBR plate membrane module, stop the aeration, and let it stand for 10 minutes;

[0075] S3, open the dosing pipeline valve 11 and the return membrane tank p...

Embodiment 2

[0081] Taking Example 1 as the raw water of this example, the above sewage was treated with MBR plate membrane, and after continuous operation for 2 months, the cleaning agent and the online cleaning method of the present application were used for cleaning.

[0082] S1, an acidic cleaning agent is prepared, comprising the following components: the content of activated carbon is 0.1 wt%, the content of tetrasodium EDTA is 2 wt%; the content of sodium tripolyphosphate is 1 wt%; the content of sodium sulfite is 1 wt% , and the water produced by MBR plate membrane treatment, and adjust the pH value to 2 with citric acid;

[0083] S2, stop the water production of the MBR plate membrane module, stop the aeration, and let it stand for 10 minutes;

[0084] S3, open the dosing pipeline valve 11 and the return membrane tank pipeline valve 17, open the cleaning agent dosing pump 9 and the cleaning agent return pump 15, to replace the water in the MBR plate membrane module, and stop the p...

Embodiment 3

[0090] Taking Example 1 as the raw water of this example, the above sewage was treated with MBR plate membrane, and after continuous operation for 6 months, the cleaning agent and the online cleaning method of the present application were used for cleaning.

[0091] S1, prepare an alkaline cleaning agent, which comprises the following components: sodium dodecylbenzene sulfonate 2wt%, sodium dodecyl sulfate 1wt%, sodium hypochlorite 2wt% and MBR plate membrane treated water obtained, and hydrogenated Sodium adjusts the pH to 11;

[0092] S2, stop the water production of the MBR plate membrane module, stop the aeration, and let it stand for 10 minutes;

[0093] S3, open the dosing pipeline valve 11 and the return membrane tank pipeline valve 17, open the cleaning agent dosing pump 9 and the cleaning agent return pump 15, to replace the water in the MBR plate membrane module, and stop the pump after 20 seconds;

[0094] S4, open the return water pipeline valve 19, and close the ...

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Abstract

The invention discloses an MBR plate-type membrane cleaning agent, which includes an alkaline cleaning agent and / or an acid cleaning agent, and the cleaning agent can efficiently remove various pollutants remaining on the surface of an ultrafiltration membrane and in the membrane pores; the invention A method for cleaning MBR plate membrane is also provided. The cleaning agent is injected into the plate membrane by means of cross-flow circulation, and then the cleaning agent left in the membrane is recovered after standing for aeration and scrubbing. On the one hand, it can overcome the The existing plate membrane has the shortcomings of uneven chemical cleaning and unrecoverable chemicals. On the other hand, it effectively improves the chemical cleaning strength and the recovery rate of mold performance after chemical cleaning, and prolongs the chemical cleaning cycle and service life of the MBR plate membrane system.

Description

technical field [0001] The invention belongs to the technical field of organic ultrafiltration membrane treatment of sewage, in particular to an MBR plate-type membrane cleaning agent and an online circulating cleaning method. Background technique [0002] With the rapid development of social economy and the rapid increase of population, China's water resources problems are becoming more and more serious. Improving the quality of the water environment is our top priority. Membrane bioreactor (MBR) technology is generally used in sewage treatment in my country. Because of its high effluent quality, stable structure and easy operation, it is widely used in the reuse of municipal water and industrial wastewater, and is the most promising market. One of the wastewater treatment technologies, and the MBR plate membrane is one of the important ways of MBR technology, and the plate ultrafiltration membrane is the key to its use. [0003] However, during the use of ultrafiltration ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01D65/02B01D65/06C02F3/12
CPCB01D65/02C02F3/1268B01D2321/162B01D2321/164B01D2321/168C02F2303/16Y02W10/10
Inventor 任鹏飞奚振宇张新妙王玉杰彭海珠
Owner CHINA PETROLEUM & CHEM CORP